1,1'-{Oxybis[(4,1-phenylene)sulfonyl]}bis(4-methylbenzene) | 30752-92-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1'-{Oxybis[(4,1-phenylene)sulfonyl]}bis(4-methylbenzene)
• 英文别名: 1-methyl-4-[4-[4-(4-methylphenyl)sulfonylphenoxy]phenyl]sulfonylbenzene
• CAS: 30752-92-2
• 化学式: C₂₆H₂₂O₅S₂
• 分子量: 478.6
• InChiKey: FUSVECBSEMSWPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  94.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,1'-{Oxybis[(4,1-phenylene)sulfonyl]}bis(4-methylbenzene) 生成 4-[4-[4-(4-Carboxyphenyl)sulfonylphenoxy]phenyl]sulfonylbenzoic acid
  参考文献：
  名称：

  TAGUTI, JOSIO;IMAI, JOITI;NIVA, MASASI;KATO, MASAYUKI;IMAI, TIXIRO

  摘要：

  DOI：
• 作为产物：
  描述：

  对甲苯磺酰氯 、 二苯醚 生成 1,1'-{Oxybis[(4,1-phenylene)sulfonyl]}bis(4-methylbenzene)
  参考文献：
  名称：

  TAGUTI, JOSIO;IMAI, JOITI;NIVA, MASASI;KATO, MASAYUKI;IMAI, TIXIRO

  摘要：

  DOI：

文献信息

• METHOD FOR MANUFACTURING CONJUGATED AROMATIC COMPOUND
  申请人：Oda Seiji

  公开号：US20110275859A1

  公开（公告）日：2011-11-10

  A method for manufacturing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (A) does not have (c1) a group represented by the following formula (10): wherein A 1 represents a C1-C20 alkoxy group etc.; (g1) a C1-C20 alkyl group which may be substituted with a fluorine atom etc.; and (h1) a C2-C20 acyl group which may be substituted with a fluorine atom etc., at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) wherein the aromatic compound (B) is structurally different from the above-mentioned aromatic compound (A), one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (B) does not have the above-mentioned (c1), (g1) and (h1) at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, in the presence of (i) a nickel compound, (ii) a metal reducing agent, (iii) at least one ligand (L1) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-withdrawing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-withdrawing group and having no substituent at 2- and 9-positions, and (iv) at least one ligand (L2) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-releasing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-releasing group and having no substituent at 2- and 9-positions.

  一种制备共轭芳香化合物的方法，包括将含有一个或两个离去基团的芳香化合物（A）与含有相同结构的上述芳香化合物（A）或结构不同的芳香化合物（B）反应，其中这些离去基团选自碘原子、溴原子和氯原子，与芳香环结合，而芳香化合物（A）没有以下式（10）所代表的基团：其中A1代表C1-C20烷氧基等；（g1）代表C1-C20烷基基团，可能被氟原子等取代；以及（h1）代表C2-C20酰基基团，可能被氟原子等取代，与离去基团结合的碳原子的相邻碳原子处没有上述（c1）、（g1）和（h1），在（i）镍化合物、（ii）金属还原剂、（iii）从2,2′-联吡啶化合物和1,10-邻菲啰啉化合物中选择的至少一种配体（L1），具有至少一个吸电子基团且在3-、6-、3′-和6′-位置没有取代基，以及（iv）从2,2′-联吡啶化合物和1,10-邻菲啰啉化合物中选择的至少一种配体（L2），具有至少一个释电子基团且在3-、6-、3′-和6′-位置没有取代基团的情况下，在上述离去基团结合的碳原子的相邻碳原子处进行反应。
• BIPYRIDINE COMPOUND, TRANSITION METAL COMPLEX, AND METHOD FOR PRODUCTION OF CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX
  申请人：Asaumi Taku

  公开号：US20100184978A1

  公开（公告）日：2010-07-22

  A bipyridine compound represented by the formula (1): wherein R 1 , R 2 and R 3 each independently represent a C1-C10 alkyl group which may be substituted etc., and R 4 , R 5 , R 6 , R 7 and R 8 each independently represent a hydrogen atom etc., a transition metal complex obtained by contacting a bipyridine compound represented by the formula (1) with a compound of a transition metal belonging to Group 9, 10 or 11, and a method for production of a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of the transition metal complex.

  一种以式(1)表示的联吡啶化合物：其中R1、R2和R3各自独立地表示可以被取代的C1-C10烷基等，而R4、R5、R6、R7和R8各自独立地表示氢原子等，通过将式(1)表示的联吡啶化合物与属于9、10或11族过渡金属的化合物接触而获得的过渡金属配合物，以及一种制备共轭芳香化合物的方法，包括在过渡金属配合物的存在下，将一个或两个离去基团与芳环结合的芳香化合物（A）与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或结构不同于上述芳香化合物（A）且具有一个或两个离去基团与芳环结合的芳香化合物（B）反应。
• POLYMER, POLYMER ELECTROLYTE AND USE OF SAME
  申请人：Yashiro Arihiro

  公开号：US20110151355A1

  公开（公告）日：2011-06-23

  The present invention provides a polymer, a polymer electrolyte and the use thereof. The polymer has, as a structural unit, a phenylene group in which two or three hydrogen atoms each have been substituted with a group represented by the following formula (A), and is insoluble in water: wherein A 1 represents a group represented by formula (1a), formula (1b) or formula (1c) below, and the two or three A 1 groups may be the same as or different from each other, wherein R 10 and R 11 each independently represents a hydrogen atom, an alkyl group of 1 to 20 carbon atoms, or an aryl group of 6 to 20 carbon atoms, R 12 represents a hydrogen atom, an alkyl group of 1 to 20 carbon atoms, or an aryl group of 6 to 20 carbon atoms, M represents a metal ion or an ammonium ion, and in a case where M represents a divalent or higher-valent metal ion, M may be further bonded to another substituent.

  本发明提供了一种聚合物、聚合物电解质及其使用方法。该聚合物具有苯基结构单元，其中每个苯环上的两个或三个氢原子分别被下式（A）所代表的基团所取代，且聚合物不溶于水：其中A1代表以下式（1a）、式（1b）或式（1c）所代表的基团，两个或三个A1基团可以相同或不同，其中R10和R11各自独立地代表氢原子、1至20个碳原子的烷基或6至20个碳原子的芳基，R12代表氢原子、1至20个碳原子的烷基或6至20个碳原子的芳基，M代表金属离子或铵离子，当M代表二价或更高价的金属离子时，M可以进一步与另一个取代基连接。
• TRANSITION METAL COMPLEX AND PROCESS FOR PRODUCING CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX
  申请人：Asaumi Taku

  公开号：US20110046336A1

  公开（公告）日：2011-02-24

  A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R 1 , R 2 and R 3 represent a C1-C10 alkyl group which may be substituted, etc., and R 4 and R 5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.

  通过将式（1）所表示的联吡啶化合物与属于9、10或11族的过渡金属化合物接触而获得的过渡金属配合物，其中R1、R2和R3代表C1-C10烷基，可以被取代等，而R4和R5代表氢原子等。制备共轭芳香化合物的方法包括，在所述过渡金属配合物的存在下，将一个芳香化合物（A），其中一个或两个离去基团与芳香环相键合，与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或在结构上不同于上述芳香化合物（A）并且具有一个或两个离去基团与芳香环相键合的芳香化合物（B）反应。
• POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE ASSEMBLY AND SOLID POLYMER FUEL CELL EACH USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20140377686A1

  公开（公告）日：2014-12-25

  Provided are: a practically excellent polymer electrolyte composition having excellent chemical stability of being resistant to strong oxidizing atmosphere during operation of fuel cell, and achieving excellent proton conductivity under low-humidification conditions, excellent mechanical strength and physical durability; a polymer electrolyte membrane, a membrane electrode assembly, and a polymer electrolyte fuel cell each using the same. The polymer electrolyte composition of the present invention comprises at least an ionic group-containing polymer (A) and a phosphorus-containing additive (B), the phosphorus-containing additive (B) being at least one of a phosphine compound and a phosphinite compound. The polymer electrolyte membrane, the membrane electrode assembly, and the polymer electrolyte fuel cell of the present invention are structured by the polymer electrolyte composition.

  提供了一种具有优异化学稳定性，在燃料电池操作期间对强氧化气氛具有抗性，并在低加湿条件下实现优异的质子传导性、优异的机械强度和物理耐久性的实用优良聚合物电解质组成物；以及使用相同组成物的聚合物电解质膜、膜电极组件和聚合物电解质燃料电池。本发明的聚合物电解质组成物包括至少一种离子基团含有的聚合物（A）和一种含磷添加剂（B），该含磷添加剂（B）至少为膦化合物和膦酸酯化合物中的一种。本发明的聚合物电解质膜、膜电极组件和聚合物电解质燃料电池由聚合物电解质组成物构成。