3,5-diphenylbicyclo[3,1,0]hex-2-ene | 94995-15-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-diphenylbicyclo[3,1,0]hex-2-ene
• 英文别名: 3,5-diphenylbicyclo[3.1.0]hex-2-ene；1,3-Diphenyl-bicyclo<3,1,0>hexen-(3)；1,3-Diphenyl-bicyclo[3,1,0]hexen-(3)；Bicyclo[3.1.0]hex-2-ene, 3,5-diphenyl-
• CAS: 94995-15-0
• 化学式: C₁₈H₁₆
• 分子量: 232.325
• InChiKey: MFPWIRCJXAWZHA-UHFFFAOYSA-N

物化性质

• 沸点：
  335.9±27.0 °C(Predicted)
• 密度：
  1.150±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  cis-3-Hydroxy-1,5-diphenyl-bicyclo<3.1.0>hexan 生成 3,5-diphenylbicyclo[3,1,0]hex-2-ene
  参考文献：
  名称：

  The Acetolysis of 1,5-Diphenyl-cis-3-bicyclo [3.1.0]hexyl p-Toluenesulfonate

  摘要：

  DOI：

  10.1021/ja00895a021

文献信息

• Fukamizu, Koji; Miyake, Yoshihiro; Nishibayashi, Yoshiaki, Angewandte Chemie - International Edition, 2009, vol. 48, p. 2534 - 2537
  作者：Fukamizu, Koji、Miyake, Yoshihiro、Nishibayashi, Yoshiaki

  DOI：——

  日期：——
• Ruthenium- and Platinum-Catalyzed Sequential Reactions:  Selective Synthesis of Fused Polycyclic Compounds from Propargylic Alcohols and Alkenes
  作者：Yoshiaki Nishibayashi、Masato Yoshikawa、Youichi Inada、Masanobu Hidai、Sakae Uemura

  DOI：10.1021/ja045532k

  日期：2004.12.1

  A simple method for the preparation of fused polycyclic compounds by an intramolecular cyclization of propargylic alcohols bearing an alkene moiety at a suitable position has been developed, where the presence of both Ru and Pt catalysts promotes a sequence of catalytic cycles in the same medium. This sequential system can be applied to an intermolecular reaction between a propargylic alcohol and an alkene to obtain the corresponding bicyclo[3,1,0]hex-2-ene derivative. These sequential reactions provide a conceptually new type of cycloaddition system between propargylic alcohols and alkenes.
• <b>The Acetolysis of 1,5-Diphenyl-<b><i>cis</i></b>-3-bicyclo [3.1.0]hexyl <b><i>p</i></b>-Toluenesulfonate</b>
  作者：E. J. Corey、Hisashi. Uda

  DOI：10.1021/ja00895a021

  日期：1963.6