tricyclohexylphosphonium p-toluenesulfonate | 1106696-21-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tricyclohexylphosphonium p-toluenesulfonate
• 英文别名: tricyclohexylphosphonium-p-toluenesulfonate；Tricyclohexyl phosphonium p-toluene sulfonate；4-methylbenzenesulfonate;tricyclohexylphosphanium
• CAS: 1106696-21-2
• 化学式: C₇H₈O₃S*C₁₈H₃₃P
• 分子量: 452.639
• InChiKey: LFGTVHJQKMCIST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  65.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  对甲苯磺酸 、 三环己基膦 以 乙醚 为溶剂， 以77%的产率得到tricyclohexylphosphonium p-toluenesulfonate
  参考文献：
  名称：

  Use of phosphonium salts in coupling reactions and process for their manufacture

  摘要：

  本发明的对象是磷铵盐在偶联反应中的使用，以及它们的制备方法。

  公开号：

  EP2019107A1

文献信息

• USE OF PHOSPHONIUM SALTS IN COUPLING REACTIONS AND PROCESS FOR THEIR MANUFACTURE
  申请人：Kromm Klemenz

  公开号：US20100197969A1

  公开（公告）日：2010-08-05

  The object of the present invention is the use of phosphonium salts in coupling reactions, and a method for their preparation.

  本发明的对象是在偶联反应中使用磷酸铵盐以及它们的制备方法。
• PROCESS FOR PRODUCING CYCLOOLEFIN ADDITION POLYMER
  申请人：JSR Corporation

  公开号：EP1657259A1

  公开（公告）日：2006-05-17

  A process for producing a cycloolefin addition polymer in which one or more cycloolefin monomers can be (co)polymerized by addition polymerization with a small palladium catalyst amount to produce a cycloolefin addition (co)polymer while attaining high catalytic activity. The process for cycloolefin addition polymer production is characterized by addition-polymerizing one or more cycloolefin monomers comprising a cycloolefin compound represented by a specific formula in the presence of a multi-component catalyst comprising (a) a palladium compound and (b) a specific phosphorus compound.

  一种环烯烃加成聚合物的生产工艺，在该工艺中，一种或多种环烯烃单体可在少量钯催化剂的作用下通过加成聚合反应进行（共）聚合，从而生产出环烯烃加成（共）聚合物，同时获得较高的催化活性。 环烯烃加成聚合物生产工艺的特点是，在由(a)钯化合物和(b)特定磷化合物组成的多组分催化剂存在下，加成聚合一种或多种环烯烃单体，这些单体包括由特定式表示的环烯烃化合物。
• Process for producing cycloolefin addition polymer
  申请人：Oshima Noboru

  公开号：US20060217505A1

  公开（公告）日：2006-09-28

  A process for producing a cycloolefin addition polymer in which one or more cycloolefin monomers can be (co)polymerized by addition polymerization with a small palladium catalyst amount to produce a cycloolefin addition (co)polymer while attaining high catalytic activity. The process for cycloolefin addition polymer production is characterized by addition-polymerizing one or more cycloolefin monomers comprising a cycloolefin compound represented by a specific formula in the presence of a multi-component catalyst comprising (a) a palladium compound and (b) a specific phosphorus compound.

  一种环烯烃加成聚合物的生产工艺，在该工艺中，一种或多种环烯烃单体可在少量钯催化剂的作用下通过加成聚合反应进行（共）聚合，从而生产出环烯烃加成（共）聚合物，同时获得较高的催化活性。环烯烃加成聚合物生产工艺的特点是，在由(a)钯化合物和(b)特定磷化合物组成的多组分催化剂存在下，加成聚合一种或多种环烯烃单体，这些单体包括由特定式表示的环烯烃化合物。
• Method For Producing Cyclic Olefin Addition Copolymer, Cyclic Olefin Addition Copolymer And Use Thereof
  申请人：Ohkita Kenzo

  公开号：US20080125556A1

  公开（公告）日：2008-05-29

  The present invention provides a method for producing a cyclic olefin addition copolymer wherein a monomer composition containing 5 to 80 mol % of a cyclic olefin having a substituent selected from alkyl groups, alkylsilyl group, and alkylsilylmethyl group represented by formula (1) below and 20 to 95 mol % of a cyclic olefin represented by formula (2) below is addition-copolymerized in the presence of a palladium-based multicomponent catalyst containing a specific palladium compound (i), a specific phosphorus compound (ii), and an ionic boron compound or an ionic aluminum compound (iii): (one of A 1 to A 4 is a C 4-5 alkyl group, trimethylsilyl group, or trimethylsilylmethyl group, and the others each independently are a hydrogen atom, halogen atom, or methyl group) (B 1 to B 4 are each independently a hydrogen atom, methyl group, or halogen atom.)
• US7241847B2
  申请人：——

  公开号：US7241847B2

  公开（公告）日：2007-07-10