(2,4-di-(tert-butyl)-6-methylphenyl)dithiophosphorane | 136910-29-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,4-di-(tert-butyl)-6-methylphenyl)dithiophosphorane
• 英文别名: [2,4-di-(tert-butyl)-6-methylphenyl]dithiophosphorane
• CAS: 136910-29-7
• 化学式: C₁₅H₂₃PS₂
• 分子量: 298.453
• InChiKey: JOUBHSYUBBIQAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  64.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (2,4-di-(tert-butyl)-6-methylphenyl)phosphine 在 sulfur 作用下， 以 甲苯 为溶剂， 反应 0.67h， 以94%的产率得到(2,4-di-(tert-butyl)-6-methylphenyl)dithiophosphorane
  参考文献：
  名称：

  (2,4-Di-(tert-butyl)-6-methylphenyl)dithiophosphorane

  摘要：

  Use of the 2,4-di-(tert-butyl)-6-methylphenyl radical permits stabilization of the corresponding dithiophosphorane (I). The analogous diselenophosphorane could not be detected as the monomer. This compound undergoes intramolecular addition of the C-H bond of the ortho-tert-butyl group at the P = Se bond with formation of the corresponding diselenophosphonic acid (III). Intermediate selenophosphine oxide (IV) was trapped as its salt with triethylamine (V).

  DOI：

  10.1007/bf00961254

文献信息

• IONKIN, A. S.;NEXOROSHKOV, V. M.;EFREMOV, YU. YA., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1654-1656
  作者：IONKIN, A. S.、NEXOROSHKOV, V. M.、EFREMOV, YU. YA.

  DOI：——

  日期：——
• (2,4-Di-(tert-butyl)-6-methylphenyl)dithiophosphorane
  作者：A. S. Ionkin、V. M. Nekhoroshkov、Yu. Ya. Efremov

  DOI：10.1007/bf00961254

  日期：1991.7

  Use of the 2,4-di-(tert-butyl)-6-methylphenyl radical permits stabilization of the corresponding dithiophosphorane (I). The analogous diselenophosphorane could not be detected as the monomer. This compound undergoes intramolecular addition of the C-H bond of the ortho-tert-butyl group at the P = Se bond with formation of the corresponding diselenophosphonic acid (III). Intermediate selenophosphine oxide (IV) was trapped as its salt with triethylamine (V).