α,α'-bis(methylene chloride) β-phenyl ethene | 172607-41-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α,α'-bis(methylene chloride) β-phenyl ethene
• 英文别名: 1,1-bis(chloromethyl)-2-phenylethene；2-Benzylidene-1,3-dichloropropane；[3-Chloro-2-(chloromethyl)prop-1-en-1-yl]benzene；[3-chloro-2-(chloromethyl)prop-1-enyl]benzene
• CAS: 172607-41-9
• 化学式: C₁₀H₁₀Cl₂
• 分子量: 201.095
• InChiKey: ALOXCDWHUMEDFU-UHFFFAOYSA-N

物化性质

• 沸点：
  308.7±32.0 °C(Predicted)
• 密度：
  1.186±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三乙胺 、 α,α'-bis(methylene chloride) β-phenyl ethene 以 乙腈 为溶剂， 反应 5.0h， 以95%的产率得到α,α'-bis(triethyl ammonium methylene chloride) β-phenyl ethene
  参考文献：
  名称：

  Balakrishnan, Thayilekannu; Jayachandran, J. Paul, Journal of the Chemical Society. Perkin transactions II, 1995, # 11, p. 2081 - 2086

  摘要：

  DOI：
• 作为产物：
  描述：

  1-phenyl-2,4,8,10 tetra oxaspiro<5.5> undecane 在 盐酸 、 zinc(II) chloride 作用下， 以48%的产率得到α,α'-bis(methylene chloride) β-phenyl ethene
  参考文献：
  名称：

  Balakrishnan, Thayilekannu; Jayachandran, J. Paul, Journal of the Chemical Society. Perkin transactions II, 1995, # 11, p. 2081 - 2086

  摘要：

  DOI：

文献信息

• Synthesis of [1.1.1]Propellanes by Bridging of Bicyclo[1.1.0]butanes
  作者：Markus Werner、David S. Stephenson、Günter Szeimies

  DOI：10.1002/jlac.199619961103

  日期：1996.11

  Several [1.1.1]propellanes were synthesized by bridging the 1,3-positions of the corresponding bicyclo[1.1.0]butane. The synthesis of 1-bromo-3-(chloromethyl)bicyclobutanes and the bridging were carried out in a one-pot reaction by addition of 2.0 equiv. of MeLi to 1,1-dibromo-2,2-bis(chlormethyl)-cyclopropanes 10. Three routes to 10 were investigated: Firstly, the Wittig reaction of 1,3-dichloroacetone

  通过桥接相应的双环[1.1.0]丁烷的1,3-位，合成了几种[1.1.1]丙炔。1-溴-3-（氯甲基）双环丁烷的合成和桥连通过添加2.0当量的一锅法进行。MeLi合成1,1-二溴-2,2-双（氯甲基）-环丙烷10。研究了10种方法的三种途径：首先，除6m外，1,3-二氯丙酮的Wittig反应成功生成（氯甲基）烯丙基氯6，仅用衍生自伯烷基卤化物的Wittig试剂成功，其次，还原二乙基与苯中的LiAlH 4的亚烷基丙二酸酯，得到甲醇12，将其转化为6通过与N-氯代琥珀酰亚胺/二甲基硫醚反应。的环丙烷化6至10是通过相转移催化的条件下与溴仿/ NaOH调节反应来实现的。最后，根据顺序11 13 14 10，从亚烷基丙二酸二乙酯开始，还原和环丙烷化的顺序可以互换。丙烷5b和3用LiAlH 4还原为双环[1.1.1]戊烷15b和e。5d和5p的二维INADEQUATE NMR光谱表明耦合常数J（13
• 2-Alkoxycarbonylamino benzimidazoles having a halogen-containing substituent, their preparation and their use as parasiticides
  申请人：Merck & Co., Inc.

  公开号：EP0009361A1

  公开（公告）日：1980-04-02

  The invention provides novel benzimidazole compounds having the formuia: in which R. is lower alkoxy and R2 is halogenated lower alkenyl, halogenated lower alkoxy, halogenated lower alkylthio, halogenated lower alkylsulfinyl, or halogenated lower alkylsulfonyl. Processes for the preparation of such compounds are also disclosed. The compounds are active anthelmintic. antifungal, bactericidal and nematocidal agents and compositions containing the novel compounds for such use are also disclosed.

  本发明提供了具有以下结构的新型苯并咪唑化合物： 其中R.为低级烷氧基，R2为卤代低级烯基、卤代低级烷氧基、卤代低级烷硫基、卤代低级烷基亚磺酰基或卤代低级烷基磺酰基。还公开了制备此类化合物的工艺。这些化合物是活性驱虫药、抗真菌药、杀菌药和杀线虫药，含有这些新型化合物的用于此类用途的组合物也已公开。
• Acrylic rubber composition
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0811659A2

  公开（公告）日：1997-12-10

  A crosslinkable acrylic rubber composition exhibiting superior balance between the storage stability and cure rate, and having only minimal risk of corroding metals or being contaminated by metals. The cured products made from the composition have excellent tensile strength, permanent compression set, and water resistance. The composition which comprises (1) a halogen-containing acrylic rubber, (2) a triazine thiol compound, (3) a dithiocarbamine acid derivative or a thiuram sulfide compound, or both, (4) a hydrotalcite compound or an organotin compound, or both, (5) an aromatic carboxylic acid compound or an acid anhydride thereof, or both, (6) a white filler with a pH of 2-10, and (7) a silane coupling agent.

  一种可交联丙烯酸橡胶组合物，在贮存稳定性和固化速度之间表现出极佳的平衡，而且腐蚀金属或被金属污染的风险极低。由该组合物制成的固化产品具有优异的拉伸强度、永久压缩永久变形和防水性能。该组合物包括：(1) 含卤素丙烯酸橡胶；(2) 三嗪硫醇化合物；(3) 二硫代氨基甲酸衍生物或硫化秋兰姆化合物，或两者兼有；(4) 滑石粉化合物或有机锡化合物，或两者兼有；(5) 芳香族羧酸化合物或其酸酐，或两者兼有；(6) pH 值为 2-10 的白色填料；以及 (7) 硅烷偶联剂。
• Synthesis And Utility Of α,α'-bis (Triethyl Ammonium Methylene Chloride) β-Phenyl Ethene in Hydroxide Ion Initiated Reactions—A New Multi-Site Phase Transfer Catalyst
  作者：T. Balakrishnan、J. Paul Jayachandran

  DOI：10.1080/00397919508011456

  日期：1995.12

  A three step synthesis of novel 'multi-site' water soluble phase transfer catalyst viz., alpha,alpha'-bis(triethyl ammonium methylene chloride) beta-phenyl ethene and its utility in various organic biphase reactions are described.
• US4093567A
  申请人：——

  公开号：US4093567A

  公开（公告）日：1978-06-06