diphenylethyl-N-phenylphosphinoselenoic amide | 1299597-56-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenylethyl-N-phenylphosphinoselenoic amide
• 英文别名: Anilino-bis(2-phenylethyl)-selenidophosphanium；anilino-bis(2-phenylethyl)-selenidophosphanium
• CAS: 1299597-56-0
• 化学式: C₂₂H₂₄NPSe
• 分子量: 412.373
• InChiKey: ZKQJFXSDDBHKHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  bis(2-phenylethyl)phosphine selenide 、 苯胺 在 三乙胺 作用下， 以 四氯化碳 为溶剂， 反应 1.0h， 以86%的产率得到diphenylethyl-N-phenylphosphinoselenoic amide
  参考文献：
  名称：

  A simple one-pot synthesis of phosphinoselenoic amides and diamides from secondary phosphine selenides and amines using Et3N-CCl4

  摘要：

  The multi-component reaction between secondary phosphine selenides and amines (primary, secondary, and primary diamines) proceeds using the Et3N-CCl4 system under mild conditions to give phosphinoselenoic amides or diamides in 81-89% isolated yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.02.095

文献信息

• A simple one-pot synthesis of phosphinoselenoic amides and diamides from secondary phosphine selenides and amines using Et3N-CCl4
  作者：Nina K. Gusarova、Pavel A. Volkov、Nina I. Ivanova、Ludmila I. Larina、Boris A. Trofimov

  DOI：10.1016/j.tetlet.2011.02.095

  日期：2011.5

  The multi-component reaction between secondary phosphine selenides and amines (primary, secondary, and primary diamines) proceeds using the Et3N-CCl4 system under mild conditions to give phosphinoselenoic amides or diamides in 81-89% isolated yields. (C) 2011 Elsevier Ltd. All rights reserved.
• Chemoselective Cross-Coupling of Secondary Phosphine Chalcogenides with Aminophenols: Synthesis of Aminophenylchalcogenophosphinic Acids O-Esters
  作者：K. O. Khrapova、P. A. Volkov、N. I. Ivanova、A. A. Telezhkin、N. K. Gusarova、B. A. Trofimov

  DOI：10.1134/s1070363218100341

  日期：2018.10

  Chemoselective reaction of secondary phosphine chalcogenides with 2-aminophenol under mild conditions (room temperature, 2-4 h, CCl4-Et3N) led to the formation of aminophenylchalcogenophosphinic acids O-esters in a yield of up to 80%.