bis(4-(n-butyl)phenyl)-(4-vinylphenyl)amine | 247074-96-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(4-(n-butyl)phenyl)-(4-vinylphenyl)amine
• 英文别名: N,N-di(4-n-butylphenyl)-4-vinylaniline；N,N-bis-(4-n-butylphenyl)-4-styrylamine；4-butyl-N-(4-butylphenyl)-N-(4-ethenylphenyl)aniline
• CAS: 247074-96-0
• 化学式: C₂₈H₃₃N
• 分子量: 383.577
• InChiKey: WLFDUMJHMVIJGQ-UHFFFAOYSA-N

物化性质

• 沸点：
  521.7±49.0 °C(Predicted)
• 密度：
  1.014±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(4-(n-butyl)phenyl)-(4-vinylphenyl)amine 、 在 palladium diacetate 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以41%的产率得到7-[6-[2,7-bis[(E)-2-[4-(4-butyl-N-(4-butylphenyl)anilino)phenyl]ethenyl]carbazol-9-yl]hexyl]-18-tricosan-12-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
  参考文献：
  名称：

  Photo-induced charge transfer and nonlinear absorption in dyads composed of a two-photon-absorbing donor and a perylene diimide acceptor

  摘要：

  本文报告了由 2,7-双(4-(二芳基氨基)苯乙烯基)咔唑双光子吸收供体发色团组成的两个分子二元组（Dyad 1 和 Dyad 2）的合成、电化学和光学特性，这两个分子二元组由不同的连接体与过二亚胺（PDI）受体连接而成。利用瞬态吸收测量法对这些化合物中的光诱导电荷转移进行了表征。由于供体的双光子吸收带与 PDI 自由基阴离子的单光子吸收带之间存在光谱重叠，与双光子吸收的供体发色团相比，二元化合物在 700 纳米到 800 纳米波长处表现出更强的非线性吸收。Dyad 1 与 Dyad 2 相比，非线性吸收更强，这是因为供体和受体之间的连接体不同，光生自由基离子的产量更高，电荷分离状态的寿命更长。

  DOI：

  10.1039/c1jm12566d
• 作为产物：
  描述：

  对丁基溴苯 、 4-乙烯苯胺 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 16.0h， 以27%的产率得到bis(4-(n-butyl)phenyl)-(4-vinylphenyl)amine
  参考文献：
  名称：

  Block Copolymers for Directional Charge Transfer: Synthesis, Characterization, and Electrochemical Properties of Redox-Active Triarylamines

  摘要：

  A series of styrenic triarylamines bearing electron-withdrawing or electron-donating substituents were synthesized and readily polymerized by nitroxide-mediated polymerization (NMP). The utility of the homopolymers as macroinitiators for the preparation of defined block copolymers is demonstrated. All redox-active polymers were characterized in detail by NMR, MS, and SEC measurements; in addition, their electrochemical properties were studied. The homopolymers undergo reversible oxidation, whereby the redox potential is modulated by the substitution pattern. In the case of the copolymers, the sequential oxidation of the individual blocks is observed and corroborated by (spectro)electrochemical measurements. The ratio of transferred charges per redox-active block agreed with the stoichiometric composition, as readily quantified by the semi-integral analysis of the electrochemical data. In addition, redox-titration experiments revealed effective electron transfer between the redox-active polymers following the order of their redox potentials. These results demonstrate the potential to achieve directional charge transfer in hierarchically defined block copolymers.

  DOI：

  10.1021/acs.macromol.5b00449

文献信息

• Two-photon or higher-order absorbing optical materials for generation of reactive species
  申请人：California Institute of Technology

  公开号：US20040110984A1

  公开（公告）日：2004-06-10

  Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

  所公开的是高效多光子吸收化合物及其使用方法。这些化合物通常包括连接电子供体或电子受体的π-共轭键桥。该桥也可被各种取代基取代。化合物的溶解度、亲油性、吸收最大值和其他特性可通过改变电子供体或电子受体基团、π-共轭桥所连接的取代基或其长度来调整。在同时吸收至少两束光子辐射时，这些化合物会转化为电子激发态，从而实现多种光物理和光化学方法。这些化合物具有较大的双光子或高阶吸收率，因此在吸收时会形成一种或多种路易斯酸性物质、路易斯碱性物质、自由基物质或离子物质。
• TWO-PHOTON OR HIGHER-ORDER ABSORBING OPTICAL MATERIALS
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：EP1071909A1

  公开（公告）日：2001-01-31
• EP1071909A4
  申请人：——

  公开号：EP1071909A4

  公开（公告）日：2005-02-02
• TWO-PHOTON OR HIGHER-ORDER ABSORBING OPTICAL MATERIALS FOR GENERATION OF REACTIVE SPECIES
  申请人：Cumpston Brian

  公开号：US20080283804A1

  公开（公告）日：2008-11-20

  Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.
• US6608228B1
  申请人：——

  公开号：US6608228B1

  公开（公告）日：2003-08-19