N,N'-bis-p-chlorobenzenesulfonyl-2-chloro-1,4-benzoquinone diimine | 98763-13-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis-p-chlorobenzenesulfonyl-2-chloro-1,4-benzoquinone diimine
• 英文别名: N,N′-(2-chlorocyclohexa-2,5-diene-1,4-diylidene)bis(4-chlorobenzenesulfonamide)；2-Chlor-p-chinon-bis-；4-chloro-N-[3-chloro-4-(4-chlorophenyl)sulfonyliminocyclohexa-2,5-dien-1-ylidene]benzenesulfonamide
• CAS: 98763-13-4
• 化学式: C₁₈H₁₁Cl₃N₂O₄S₂
• 分子量: 489.787
• InChiKey: BPXFEYZEPIFXQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-氯-4-氨基苯胺 在 吡啶 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 N,N'-bis-p-chlorobenzenesulfonyl-2-chloro-1,4-benzoquinone diimine
  参考文献：
  名称：

  Synthesis of N,N′-Bis(arylsulfanyl)cyclohexa-2,5-diene-1,4-diimines and N,N′-(Cyclohexa-2,5-diene-1,4-diylidene)bis(arenesulfinamides)

  摘要：

  Reactions of (chlorosulfanyl)benzenes with benzene-1,4-diamines afforded new N,N′-bis(arylsulfanyl)cyclohexa-2,5-diene-1,4-diimines which were oxidized to N,N′-(cyclohexa-2,5-diene-1,4-diylidene)bis(arenesulfinamides) with 2 equiv of m-chloroperoxybenzoic acid. When the oxidation was carried out using 4 equiv of m-chloroperoxybenzoic acid, the corresponding bis-sulfonamides were obtained. The synthesized

  DOI：

  10.1134/s1070428021040084

文献信息

• Avdeenko, A. P.; Velichko, N. V.; Tolmachev, A. A., Russian Journal of Organic Chemistry, 1994, vol. 30, # 1, p. 146 - 154
  作者：Avdeenko, A. P.、Velichko, N. V.、Tolmachev, A. A.、Pirozhenko, V. V.、Romanenko, E. A.

  DOI：——

  日期：——
• Synthesis of N,N′-Bis(arylsulfanyl)cyclohexa-2,5-diene-1,4-diimines and N,N′-(Cyclohexa-2,5-diene-1,4-diylidene)bis(arenesulfinamides)
  作者：S. A. Konovalova、A. P. Avdeenko、A. A. Santalova

  DOI：10.1134/s1070428021040084

  日期：2021.4

  Reactions of (chlorosulfanyl)benzenes with benzene-1,4-diamines afforded new N,N′-bis(arylsulfanyl)cyclohexa-2,5-diene-1,4-diimines which were oxidized to N,N′-(cyclohexa-2,5-diene-1,4-diylidene)bis(arenesulfinamides) with 2 equiv of m-chloroperoxybenzoic acid. When the oxidation was carried out using 4 equiv of m-chloroperoxybenzoic acid, the corresponding bis-sulfonamides were obtained. The synthesized