N-naphthalen-2-yl-N-phenyl-N-(4-vinylphenyl)amine | 943784-71-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-naphthalen-2-yl-N-phenyl-N-(4-vinylphenyl)amine
• 英文别名: N-(4-ethenylphenyl)-N-phenylnaphthalen-2-amine
• CAS: 943784-71-2
• 化学式: C₂₄H₁₉N
• 分子量: 321.422
• InChiKey: OWLBYJGSTFQLBD-UHFFFAOYSA-N

物化性质

• 沸点：
  499.8±24.0 °C(Predicted)
• 密度：
  1.145±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-naphthalen-2-yl-N-phenyl-N-(4-vinylphenyl)amine 、 10-bromo-N,N,15-triphenyl-15-azatetracyclo[10.2.1.05,14.08,13]pentadeca-1(14),2,4,6,8,10,12-heptaen-3-amine 在 palladium diacetate 、 三乙胺 、 三对苯甲基膦 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 12.0h， 以56%的产率得到10-[2-[4-(N-naphthalen-2-ylanilino)phenyl]ethenyl]-N,N,15-triphenyl-15-azatetracyclo[10.2.1.05,14.08,13]pentadeca-1(14),2,4,6,8,10,12-heptaen-3-amine
  参考文献：
  名称：

  헤테로고리 화합물 및 이를 포함한 유기 발광 소자

  摘要：

  所公开的是下式 1 的杂环化合物以及由其组成的有机发光器件。<方案 1>关于式 1 的取代基，请参阅详细说明。

  公开号：

  KR20150019721A
• 作为产物：
  描述：

  N-苯基-2-萘胺 在 18-冠醚-6 、 potassium tert-butylate 、 铜 、 potassium carbonate 作用下， 以 四氢呋喃 、 邻二氯苯 为溶剂， 生成 N-naphthalen-2-yl-N-phenyl-N-(4-vinylphenyl)amine
  参考文献：
  名称：

  The synthesis of robust, polymeric hole-transport materials from oligoarylamine substituted styrenes

  摘要：

  报道了一系列新型苯乙烯基低聚芳胺单体，这些单体适用于制备具有极高玻璃化转变温度的聚合物空穴传输材料。这些单体是通过Wittig反应从适当的醛前体合成得到的，而该醛前体则是通过经典的Ullmann反应组装而成的。其中多种单体生成了高质量的晶体，这有助于利用X射线进行表征。通过溶液自由基引发或通过缩聚相热自聚合可以实现聚合。后者提示了一种无需引发剂的聚合方法，该方法可能在多层器件制造中具有潜在应用价值。

  DOI：

  10.1039/b614235d

文献信息

• CONDENSED-CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20140027721A1

  公开（公告）日：2014-01-30

  Embodiments of the invention are directed to a condensed-cyclic compound represented by Formula 1, and to an organic light-emitting device including the condensed-cyclic compound. The organic light-emitting device may include an organic layer containing the condensed-cyclic compound.

  本发明的实施例涉及一种由式1表示的紧凑环状化合物，以及包括该紧凑环状化合物的有机发光器件。该有机发光器件可能包括含有该紧凑环状化合物的有机层。
• 헤테로고리 화합물 및 이를 포함한 유기 발광 소자
  申请人：Samsung Display Co., Ltd. 삼성디스플레이 주식회사(120120164552) Corp. No ▼ 134511-0187812

  公开号：KR20150019721A

  公开（公告）日：2015-02-25

  하기 화학식 1의 헤테로고리 화합물 및 이를 포함한 유기 발광 소자가 개시된다. <화학식 1> 상기 화학식 1의 치환기에 대한 내용은 상세한 설명을 참고한다.

  所公开的是下式 1 的杂环化合物以及由其组成的有机发光器件。<方案 1>关于式 1 的取代基，请参阅详细说明。
• Doping methods for hole injection and transport layers
  申请人：Plextronics, Inc.

  公开号：US20130092887A1

  公开（公告）日：2013-04-18

  A method including combining at least one first compound in a neutral form with at least one ionic dopant in a first solvent system to provide a first doped reaction product, isolating the first doped reaction product in solid form, and combining the isolated first doped reaction product with at least one conjugated polymer in neutral form in a second solvent system to form a second doped reaction product including an oxidized form of the conjugated polymer a neutral form of the first compound. Advantages include better stability, ease of use, and lower metal content. Applications include organic electronic devices including OLEDs.

  一种方法包括将至少一种第一化合物以中性形式与至少一种离子掺杂剂在第一溶剂体系中结合以提供第一掺杂反应产物，将第一掺杂反应产物以固体形式分离，并将分离的第一掺杂反应产物以中性形式与至少一种共轭聚合物在第二溶剂体系中结合以形成第二掺杂反应产物，其中包括共轭聚合物的氧化形式和第一化合物的中性形式。优点包括更好的稳定性、易于使用和较低的金属含量。应用包括有机电子器件，包括OLED。
• Organic light emitting device and method of manufacturing the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10553796B2

  公开（公告）日：2020-02-04

  An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the emission layer and the second electrode, the electron transport region including an electron auxiliary layer, wherein the hole transport region includes at least one copolymer selected from i) a first copolymer of a first compound and a second compound and ii) a second copolymer of a third compound and a fourth compound, wherein the first compound and the second compound are each independently selected from compounds represented by Formula 1, and the third compound and the fourth compound are each independently selected from compounds represented by Formula 2, and wherein the electron auxiliary layer includes a metal oxide.

  一种有机发光器件包括第一电极； 面向第一电极的第二电极； 位于第一电极和第二电极之间的发射层； 位于第一电极和发射层之间的空穴传输区域；和发射层与第二电极之间的电子传输区域，电子传输区域包括电子辅助层，其中空穴传输区域包括至少一种选自 i) 第一化合物和第二化合物的第一共聚物和 ii) 第三化合物和第四化合物的第二共聚物的共聚物，其中第一化合物和第二化合物各自独立地选自式 1 所代表的化合物，第三化合物和第四化合物各自独立地选自式 2 所代表的化合物，电子辅助层包括金属氧化物。
• ORGANIC LIGHT EMITTING DEVICE AND METHOD OF MANUFACTURING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170125682A1

  公开（公告）日：2017-05-04

  An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the emission layer and the second electrode, the electron transport region including an electron auxiliary layer, wherein the hole transport region includes at least one copolymer selected from i) a first copolymer of a first compound and a second compound and ii) a second copolymer of a third compound and a fourth compound, wherein the first compound and the second compound are each independently selected from compounds represented by Formula 1, and the third compound and the fourth compound are each independently selected from compounds represented by Formula 2, and wherein the electron auxiliary layer includes a metal oxide.