1,1'-Bi(bicyclo<1.1.1>pentan) | 115092-74-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: 1,1'-Bi(bicyclo<1.1.1>pentan)
• 英文别名: Bi(bicyclo-<1.1.1>pentyl)；<2>staffane；1,1'-Bi(bicyclo[1.1.1]pentan)；1,1'-Bi(bicyclo[1.1.1]pentane)；1-(1-bicyclo[1.1.1]pentanyl)bicyclo[1.1.1]pentane
• CAS: 115092-74-5
• 化学式: C₁₀H₁₄
• 分子量: 134.221
• InChiKey: ANXNFNXJUGPIGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,3'-diiodobis(1,1'-bicyclo[1.1.1]pentane) 在 三正丁基氢锡 作用下， 以 乙醚 为溶剂， 反应 3.0h， 以70%的产率得到1,1'-Bi(bicyclo<1.1.1>pentan)
  参考文献：
  名称：

  Reductive dehalogenation of halo derivatives of bis(1,1?-bicyclo[1.1.1]pentane)

  摘要：

  DOI：

  10.1007/bf00959608

文献信息

• [n]Staffanes: the parent hydrocarbons
  作者：Gudipati S. Murthy、Karin Hassenruck、Vincent M. Lynch、Josef Michl

  DOI：10.1021/ja00200a057

  日期：1989.8

  Synthese d'oligomere [n] staffanes (n=1 a 6) a partir de [1,1,1] propellane et d'argon ou d'hydrogene ou d'ammoniac

  合成这些 d'oligomere [n] 工作人员 (n=1 a 6) a partir de [1,1,1] propellane et d'argon ou d'hydrogene ou d'ammoniac
• Synthesis of doubly bridgehead substituted bicyclo[1.1.1]pentanes. Radical transformations of bridgehead halides and carboxylic acids
  作者：Piotr Kaszynski、Neil D. McMurdie、Josef Michl

  DOI：10.1021/jo00001a058

  日期：1991.1

  Synthetic transformations of the 1-bicyclo[1.1.1]pentyl bridgehead radicals 11 generated from the corresponding bridgehead iodides 3 and carboxylic acids 5 are described. The relatively high nucleophilicity of these radicals was utilized in reactions with carbonyl compounds. In the reaction sequence of preparation of the iodides 3 and their further transformations, [1.1.1]propellane (2) is a synthetic equivalent of the recently described bicyclo[1.1.1]penta-1,3-dienyl dianion (8).
• Infrared spectra of [n]staffanes
  作者：Murthy S. Gudipati、Steven J. Hamrock、V. Balaji、Josef Michl

  DOI：10.1021/j100204a016

  日期：1992.12

  The IR spectra of the rust five oligomers of [1.1.1]propellane ([n]staffanes, n = 1-5), and some of their bridgehead-deuteriated derivatives, have been measured in argon matrix isolation. IR transition moment directions were obtained using stretched polyethylene as solvent. Assignments were based on a simple model of interacting subunits and on comparison with 3-21G HF calculations. IR peaks particularly suitable for use in the determination of orientation of the staffane moieties in supramolecular assemblies have been identified.
• MURTHY, GUDIPATI S.;HASSENRUCK, KARIN;LYNCH, VINCENT M.;MICHL, JOSEF, J. AMER. CHEM. SOC., 111,(1989) N18, C. 7262-7264
  作者：MURTHY, GUDIPATI S.、HASSENRUCK, KARIN、LYNCH, VINCENT M.、MICHL, JOSEF

  DOI：——

  日期：——
• SADOVAYA, N. K.;BLOXIN, A. V.;TYUREXODZHAEVA, M. A.;GRISHIN, YU. K.;SURMI+, IZV. AN CCCP. CEP. XIM.,(1990) N, S. 716-717
  作者：SADOVAYA, N. K.、BLOXIN, A. V.、TYUREXODZHAEVA, M. A.、GRISHIN, YU. K.、SURMI+

  DOI：——

  日期：——