4-chloro-N,N,N-trimethylbenzenemethanaminium chloride | 6320-45-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-chloro-N,N,N-trimethylbenzenemethanaminium chloride
• 英文别名: Trimethyl-<4-chlorbenzyl>-ammoniumhydroxid；(4-chloro-benzyl)-trimethyl-ammonium; chloride；(4-Chlor-benzyl)-trimethyl-ammonium; Chlorid；(4-Chlorophenyl)-N,N,N-trimethylmethanaminium chloride；(4-chlorophenyl)methyl-trimethylazanium;chloride
• CAS: 6320-45-2
• 化学式: C₁₀H₁₅ClN*Cl
• 分子量: 220.142
• InChiKey: JCNRICBAKSSBCP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.45
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-chloro-N,N,N-trimethylbenzenemethanaminium chloride 在 sodium hydroxide 、 potassium permanganate 、 氨 、 sodium amide 作用下， 生成 4-氯邻苯二酸
  参考文献：
  名称：

  Consecutive Ortho Substitution Rearrangements Starting with 2- and 4- Substituted Benzyltrimethylammonium Ions¹

  摘要：

  DOI：

  10.1021/jo01073a007
• 作为产物：
  描述：

  N-(3-chloro-benzyl)-N-(4-chloro-benzyl)-benzamide 在 五氯化磷 作用下， 生成 4-chloro-N,N,N-trimethylbenzenemethanaminium chloride
  参考文献：
  名称：

  v.Braun; Kuehn; Weismantel, Justus Liebigs Annalen der Chemie, 1926, vol. 449, p. 264

  摘要：

  DOI：

文献信息

• Shape-Selective Recognition of Quaternary Ammonium Chloride Ion Pairs
  作者：Dong-Hao Li、Bradley D. Smith

  DOI：10.1021/acs.joc.8b03197

  日期：2019.3.1

  Synthetic receptors that recognize ion pairs are potentially useful for many technical applications, but to date there has been little work on selective recognition of quaternary ammonium (Q+) ion pairs. This study measured the affinity of a tetralactam macrocycle for 11 different Q+·Cl– salts in chloroform solution. In each case, NMR spectroscopy was used to determine the association constant (Ka) and

  承认离子对合成的受体是许多技术应用可能有用，但到目前为止还没有关于季铵盐（Q的选择性识别一些工作+）离子对。这项研究测量了四内酰胺大环化合物对氯仿溶液中11种不同的Q + ·Cl –盐的亲和力。在每种情况下，都使用NMR光谱法确定缔合常数（K a）和缔合配合物的结构。发现K a强烈依赖于Q +的分子形状，当Q +时K a增强。可以穿透大环腔并与大环的NH残基和芳族侧壁发生吸引人的非共价相互作用。当Q +为对-CN取代的苄基三甲基铵时，测得的最高K a为7.9×10 3 M –1。这种高亲和力的Q + ·Cl –离子对被用作模板，以提高产生四内酰胺受体或结构相关衍生物的大环化反应的合成产率。另外，通过将由被反应性苄基阳离子穿线的四内酰胺大环组成的非共价络合物的末端加帽，制备了永久性联锁的轮烷。合成方法提供了一个新的轮烷化离子对家族的途径，这些家族可能充当阴离子传感器，分子穿梭分子或转运分子。
• Multicolor coating system, process for producing it, process using it to achieve a multicolor pattern on a surface, and articles having such multicolor patterns
  申请人：CELANESE CORPORATION

  公开号：EP0025679A2

  公开（公告）日：1981-03-25

  A multicolor coating system involves an aqueous gel composition which is adapted for application on the surface of articles to achieve a sharply defined multicolor pattern effect. The aqueous gel composition consists of an aqueous gel matrix which has dispersed therein one or more immiscible colorant gel phases. The matrix may itself be colored.

  一种多色涂层系统包括一种水性凝胶组合物，该组合物适用于涂抹在物品表面，以达到鲜明的多色图案效果。水性凝胶组合物由水性凝胶基质组成，基质中分散有一个或多个不相溶的着色凝胶相。基质本身可以着色。
• Anionic sulfonated thickening compositions
  申请人：RHONE-POULENC SPECIALTY CHEMICALS CO.

  公开号：EP0632057A1

  公开（公告）日：1995-01-04

  A novel composition suitable for use as a thickener comprising an anionic hydroxy containing polymer which is partially or completely substituted by one or more sulfonate groups derived from an ethylenically unsaturated monomer is provided. The composition is capable of producing enhanced viscosities either when used alone, or when combined with a cationic polymer and distributed in a solvent. The composition is suitable for use in foods, explosives, oil field chemicals, textile fibers, paper produces, personal care products, agricultural chemicals and cosmetics.

  提供了一种适合用作增稠剂的新型组合物，该组合物包含一种阴离子含羟基聚合物，该聚合物部分或全部被一个或多个磺酸基团取代，这些磺酸基团来自乙烯基不饱和单体。无论是单独使用，还是与阳离子聚合物结合并分布在溶剂中，该组合物都能产生更高的粘度。这种组合物适用于食品、炸药、油田化学品、纺织纤维、造纸、个人护理产品、农用化学品和化妆品。
• Alkylation of Rhodium Porphyrins Using Ammonium and Quinolinium Salts
  作者：Samuel J. Thompson、Guangbin Dong

  DOI：10.1021/om500438s

  日期：2014.7.28

  Alkylation of rhodium(III) porphyrins [Rh-II(por)] was achieved under relatively mild conditions in up to 98% yields, where readily available ammonium and quinolinium salts were utilized as the alkylating agents. This transformation tolerates air and water, thus serving as a convenient method to prepare a variety of alkyl- and benzyl-Rh-III(por) complexes. Preliminary mechanistic studies support an S(N)2-like reaction pathway involving a Rh-I(por) anion intermediate.
• DERIVATIZED GUAR GUM COMPOSITION INCLUDING NONIONIC AND CATIONIC GROUPS WHICH DEMONSTRATE EXCELLENT SOLUTION CLARITY PROPERTIES FOR DETERGENT APPLICATIONS
  申请人：RHODIA INC.

  公开号：EP0934343A1

  公开（公告）日：1999-08-11