1-phenyl-1-(2-propenyloxy)ethene | 40815-73-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-1-(2-propenyloxy)ethene
• 英文别名: 1-phenyl-1-(prop-2-enoxy)ethene；1-phenyl-1-(3-propenoxy)ethene；allyl-(1-phenyl-vinyl)-ether；Allyl-(1-phenyl-vinyl)-aether；α-Allyloxy-styrol；Allyl-α-phenylvinylether；Benzene, [1-(2-propenyloxy)ethenyl]-；1-prop-2-enoxyethenylbenzene
• CAS: 40815-73-4
• 化学式: C₁₁H₁₂O
• 分子量: 160.216
• InChiKey: MZONMYOSAYHGAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-phenyl-1-(2-propenyloxy)ethene 生成 1-苯基-4-戊烯-1-酮
  参考文献：
  名称：

  The Rearrangement of Vinyl Allyl Ethers

  摘要：

  DOI：

  10.1021/ja01275a051
• 作为产物：
  描述：

  allyl 2-bromo-1-phenylethyl ether 生成 1-phenyl-1-(2-propenyloxy)ethene
  参考文献：
  名称：

  The Rearrangement of Vinyl Allyl Ethers

  摘要：

  DOI：

  10.1021/ja01275a051

文献信息

• Convenient One‐Pot Synthesis of Vinyl Ethers from Phenyl 2‐Hydroxyalkyl Selenides
  作者：Shou‐Ri Sheng、Hai‐Rong Luo、Wu‐Kang Sun、Xiao‐Ling Liu、Qin Xin、Qiu‐Ying Wang

  DOI：10.1080/00397910500296901

  日期：2005.11

  Abstract Vinyl ethers were prepared with good yields in a one‐pot, two‐step transformation by O‐alkylation reaction of phenyl 2‐hydroxyalkyl selenides with primary or secondary organic halides followed by oxidation elimination with 30% hydrogen peroxide.

  摘要 通过苯基 2-羟烷基硒化物与伯或仲有机卤化物的 O-烷基化反应，然后用 30% 的过氧化氢氧化消除，在一锅两步转化中以良好的收率制备了乙烯基醚。
• Highly efficient nitrogen chelated ruthenium carbene metathesis catalysts
  作者：Yulian Duan、Tao Wang、Qingxiao Xie、Xiaobo Yu、Weijie Guo、Jianhui Wang、Guiyan Liu

  DOI：10.1039/c6dt03899a

  日期：——

  metathesis catalysts containing an N-heterocyclic carbene (NHC) and a carbonyl group have been developed and their catalytic activities for olefin metathesis reactions were investigated. The X-ray structure of the [(H2IMes)(Cl)2Ru]C(H)CH2[p-F(C6H3)NC(CF3)(C(O)OCH2CH3)] complex shows that the carbonyl oxygen of the ester and the imine nitrogen are both coordinated to the Ru metal to give an octahedral

  已开发出一系列含有N-杂环卡宾（NHC）和羰基的氮螯合钌卡宾复分解催化剂，并研究了它们对烯烃复分解反应的催化活性。[（H 2 IMes）（Cl）2 Ru] C（H）CH 2 [ p -F（C 6 H 3）NC（CF 3）（C（O）OCH 2 CH 3）]配合物表明，酯的羰基氧和亚胺氮都与Ru金属配位，得到八面体结构。测试了这些钌卡宾配合物对烯烃复分解反应的催化活性。一些带有吸电子基团的配合物具有较高的引发速率。这些复合物对于闭环复分解和交叉复分解均显示出优异的性能。
• Carbonyl methylenation using a titanium-aluminum (Tebbe) complex
  作者：Stanley H. Pine、Robert J. Pettit、Gregory D. Geib、Susana G. Cruz、Claudio H. Gallego、Tomas Tijerina、Randall D. Pine

  DOI：10.1021/jo00208a013

  日期：1985.4
• CONTROL OF MOLECULAR WEIGHT AND END GROUP FUNCTIONALITY OF POLYMERS
  申请人：COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION

  公开号：EP0333758B1

  公开（公告）日：1995-11-02
• Preparation, characterization and nonlinear optical properties of colloidal gallium arsenide nanocrystals
  作者：Z LIU、C LIU、Q LI、Z CHEN、Q GONG

  DOI：10.1016/s1001-0521(06)60026-0

  日期：2006.4

  GaAs nanocrystals were prepared via a simple mechanical ball milling technique. The prepared GaAs nanocrystals have high purity and could form colloidal ethanol suspension without any surfactant additives. The colloidal GaAs nanocrystal suspension displayed excellent two-photon absorption property over the visible and near-infrared region from 490 nm to 1064 run, which enables it to become a promising broadband optical limiting material.