2-吡啶羧酸银 | 27876-60-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2-吡啶羧酸银
• 英文名称: silver 2-pyridine-carboxylate
• 英文别名: silver pyridylcarboxylate；silver(II) picolinate；silver picolinate；silver pyridine 2-carboxylate；Ag(I) picolinate；silver 2-pyridinecarboxylate；Silver;pyridine-2-carboxylate
• CAS: 27876-60-4
• 化学式: Ag*C₆H₄NO₂
• 分子量: 229.971
• InChiKey: GJGOWHNOGHVUJK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.56
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-吡啶羧酸银 在 K₂S₂O₈ 作用下， 以 水 为溶剂， 生成 pyridine-2-carboxylic acid, Ag(II) salt
  参考文献：
  名称：

  Cox, E. G.; Wardlaw, W.; Webster, K. C., Journal of the Chemical Society

  摘要：

  DOI：
• 作为产物：
  描述：

  pyridine-2-carboxylic acid, Ag(II) salt 生成 2-吡啶羧酸银
  参考文献：
  名称：

  Silver II complexes as oxidising agents

  摘要：

  DOI：

  10.1016/s0040-4039(00)90961-4
• 作为试剂：
  描述：

  2-(2-Phenylcyclopropyl)glycine 在 2-吡啶羧酸银 作用下， 以 水 为溶剂， 反应 1.0h， 以75%的产率得到trans-2-phenylcyclopropanecarbaldehyde
  参考文献：
  名称：

  Silver(I)/peroxydisulfate-induced oxidative decarboxylation of amino acids. A chemical model for a possible intermediate in the monoamine oxidase-catalyzed oxidation of amines

  摘要：

  DOI：

  10.1021/jo00047a045

文献信息

• Synthesis and characterisation of some ruthenium(II) complexes of α-N heterocyclic carboxylic acids—X-ray structures of cis-[Ru(PPh3)2(L1)2]·2CH3OH and cis-[Ru(PPh3)2(L3H)2] (L1H=pyridine 2-carboxylic acid and L3H2=imidazole 4,5-dicarboxylic acid)
  作者：Parbati Sengupta、Rupam Dinda、Saktiprosad Ghosh、W.S Sheldrick

  DOI：10.1016/s0277-5387(01)00946-9

  日期：2001.12

  Abstract Synthesis and characterisation of ruthenium(II) complexes of several α-N heterocyclic carboxylic acids of the general formula [Ru(PPh3)2(L)2] are reported [LH=pyridine 2-carboxylic acid (L1H), pyrazine 2-carboxylic acid (L2H), imidazole 4,5-dicarboxylic acid (L3H2) and pyrazine 2,3-dicarboxylic acid (L4H2)]. All the acids behaved as bidentate N–O chelating donors, the second carboxyl group

  摘要报道了几种通式为[Ru（PPh3）2（L）2]的α-N杂环羧酸的钌（II）配合物的合成和表征[LH =吡啶2-羧酸（L1H），吡嗪2-羧酸（L 2 H），咪唑4，5-二羧酸（L 3 H 2）和吡嗪2，3-二羧酸（L 4 H 2）]。所有酸均表现为双齿N–O螯合供体，二元羧酸的第二个羧基保持游离状态。通过循环伏安法研究了配合物的电化学行为。两种配合物cis- [Ru（PPh3）2（L1）2]·2CH3OH和cis- [Ru（PPh3）2（L3H）2]的单晶X射线分析导致结构的阐明，结果表明：在这两种复合物中，两个庞大的PPh3基团是彼此顺式的。
• Metal ions and complexes in organic reactions. Part XIII. Oxidative effects of silver(II) complexes of pyridinecarboxylic acids
  作者：J. A. Azoo、R. G. R. Bacon、K. K. Gupta

  DOI：10.1039/j39700001975

  日期：——

  Aldehydes or ketones were produced by reaction of silver(II) picolinate (pyridine-2-carboxylate) in aqueous suspension with some arylalkanes and arylalkanols; the response of substrates differed in certain respects from that reported when the oxidant was silver(II) oxide in phosphoric acid. The silver(II) complexes of pyridine-2-carboxylic, -3-carboxylic, -4-carboxylic, and -2,3-dicarboxylic acids

  通过使吡啶甲酸银（II）（吡啶-2-羧酸吡啶盐）在水性悬浮液中与某些芳基烷烃和芳基烷醇反应生成醛或酮。底物的反应在某些方面与氧化剂在磷酸中为氧化银（II）时报道的反应有所不同。与伯，仲胺和其他有机底物的氧化剂相比，吡啶-2-羧酸，-3-羧酸，-4-羧酸和-2,3-二羧酸的银（II）配合物在效率上仅表现出很小的差异。 。
• Ruthenium(II) and iron(II) complexes of N-pyridyl substituted imidazolin-2-ylidenes
  作者：Oliver Kaufhold、F. Ekkehardt Hahn、Tania Pape、Alexander Hepp

  DOI：10.1016/j.jorganchem.2008.08.013

  日期：2008.10

  The di-μ-bromo bridged derivative [(κ2-2)2Ru(μ-Br)2Ru(κ2-2)2]2+ [3b]2+ was obtained from RuCl3 · xH2O and 1b. The bridging halide ligands can be removed by the reaction with silver or sodium salts of bidentate Lewis acids. Complex [3a]2+ reacts with silver pyridylcarboxylate to give a racemic mixture of the mononuclear complex [4]+. Reaction of [3a]2+ with the sodium salt of l-proline resulted in

  Ñ -mesityl- Ñ ' -吡啶基咪唑鎓氯化物1A和相应的溴化物盐1B已在THF被去质子化用NaH得到游离N-杂环卡宾Ñ -mesityl- ñ “ -吡啶基咪唑啉-2-亚基2在80％的产量（从1a开始）。咪唑鎓盐1A与发生反应的RuCl 3  ·  X ^ h 2 O操作得到的双核二- μ氯桥钌络合物[（κ的外消旋混合物2 - 2）2的Ru（μ-Cl）的2的Ru（κ 2 - 2）2 ] 2+ [ 3a ] 2+。卡宾碳原子以及卤化物彼此以顺式位置排列，而氮原子采用反式构型。将二μ溴桥接衍生物[（κ 2 - 2）2的Ru（μ-溴）2的Ru（κ 2 - 2）2 ] 2+ [图3b ] 2+从的RuCl得到3  ·  X ^ h 2 O和1b。可以通过与二齿路易斯酸的银盐或钠盐反应除去桥联的卤化物配体。配合物[ 3a ] 2+与吡啶基羧酸银反应，得到单核配合物[ 4 ] +的外消旋混合物。[
• IRIDIUM COMPLEX COMPOUND, METHOD FOR PRODUCING SAID COMPOUND, COMPOSITION CONTAINING SAID COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3081571A1

  公开（公告）日：2016-10-19

  The object of the invention is to provide an iridium complex compound which emits red light with a high luminescent quantum yield, a process for producing the compound, an organic electroluminescent element which employs the iridium complex compound and has a high luminescent efficiency, a display device, and an illuminator. The present invention relates to an iridium complex compound represented by the following formula (1), which contains a phenyl(iso)quinoline or phenylquinazoline ligand and a phenylazole ligand:

  本发明的目的是提供一种能发出红光且发光量子产率高的铱络合物、一种生产该化合物的工艺、一种采用该铱络合物且发光效率高的有机电致发光元件、一种显示装置和一种照明器。本发明涉及一种由下式（1）表示的铱络合物，它含有苯基（异）喹啉或苯基喹唑啉配体和苯基唑配体：
• Iridium complex compound, process for producing the compound, composition including the compound, organic electroluminescent element, display device, and illuminator
  申请人：Mitsubishi Chemical Corporation

  公开号：US10600974B2

  公开（公告）日：2020-03-24

  The object of the invention is to provide an iridium complex compound which emits red light with a high luminescent quantum yield, a process for producing the compound, an organic electroluminescent element which employs the iridium complex compound and has a high luminescent efficiency, a display device, and an illuminator. The present invention relates to an iridium complex compound represented by the following formula (1), which contains a phenyl(iso)quinoline or phenylquinazoline ligand and a phenylazole ligand: Ir(L1)m(L2)n(L3)3-m-n  (1)

  本发明的目的是提供一种能发出红光且发光量子产率高的铱络合物、一种生产该化合物的工艺、一种采用该铱络合物且发光效率高的有机电致发光元件、一种显示装置和一种照明器。本发明涉及一种由下式（1）表示的铱络合物，它含有苯基（异）喹啉或苯基喹唑啉配体和苯基唑配体： Ir(L1)m(L2)n(L3)3-m-n (1)