acenaphthenquinone monophenylhydrazone | 13152-81-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: acenaphthenquinone monophenylhydrazone
• 英文别名: acenaphthene-1,2-dione-mono-phenylhydrazone；Acenaphthen-1,2-dion-mono-phenylhydrazon；Acenaphthenchinon-mono-phenylhydrazon；Acenaphthenchinon-monophenylhydrazon；1-Oxo-2-phenylhydrazono-acenaphthen；Acenaphthenchinonmonophenylhydrazon；2-(2-Phenylhydrazinylidene)acenaphthylen-1(2h)-one；2-(phenylhydrazinylidene)acenaphthylen-1-one
• CAS: 13152-81-3
• 化学式: C₁₈H₁₂N₂O
• 分子量: 272.306
• InChiKey: HCOFEPAPGOGFNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  acenaphthenquinone monophenylhydrazone 在 盐酸 、 铁粉 、 溶剂黄146 作用下， 生成 1-苊酮
  参考文献：
  名称：

  368. ena和and

  摘要：

  DOI：

  10.1039/jr9370001761
• 作为产物：
  描述：

  苊 在 sodium dichromate 、 乙醇 、 溶剂黄146 作用下， 生成 acenaphthenquinone monophenylhydrazone
  参考文献：
  名称：

  Graebe; Gfeller, Justus Liebigs Annalen der Chemie, 1893, vol. 276, p. 15

  摘要：

  DOI：

文献信息

• Chemistry of Phosphorus Ylides, 13¹Reactions with Phosphacumulenes. VII: Novel Synthesis of Pyridazinones and Pyridazinethiones from the Reaction of Cumulated Phosphorus Ylides with Monohydrazones of<i>α</i>-Diketones, Acenaphthenequinone, and Indantrione
  作者：Fouad M. Soliman、El-Sayed M. Yakout、Medhat M. Said

  DOI：10.1246/bcsj.67.2162

  日期：1994.8

  monohydrazone 8 and indantrione monohydrazone 16 has been studied. In some cases the resulted phosphoranes directly cyclize by an intramolecular Wittig reaction with the formation of pyridazinones 4a, 6, 9, 12, and 17 and pyridazinethione 4b. Structure of the new products were assigned according to consistent analytical and spectroscopic data.

  已经研究了活性磷枯草烯 2a、b 对不同 α-二酮单腙1、5、11 和13、苊醌单腙8 和阴丹三酮单腙16 的行为。在某些情况下，生成的正膦通过分子内 Wittig 反应直接环化，形成哒嗪酮 4a、6、9、12 和 17 和哒嗪硫酮 4b。根据一致的分析和光谱数据分配新产品的结构。
• Mono(arylhydrazino)acenaphthenones as a platform for the design of NIR chromophores based on Pd(<scp>ii</scp>)-BIAN complexes
  作者：I. V. Bakaev、N. F. Romashev、V. I. Komlyagina、D. G. Samsonenko、A. L. Gushchin

  DOI：10.1039/d3nj03832g

  日期：——

  synthetic procedure for mono(arylhydrazino)acenaphthenones Ph-mhan (1) and 2-tol-mhan (2), based on the reaction of acenaphthenequinone with an arylhydrazonium salt, has been developed. These compounds were used further to obtain a series of heteroleptic cationic palladium(II) complexes containing bis(arylimino)acenaphthene (Ar-bian) and mono(arylhydrazino)acenaphthenone (Ar-mhan) ligands: [Pd(tmp-bian)(Ph-mhan)](CF3SO3)2

  基于苊醌与芳基腙盐的反应，开发了一种新的单（芳基肼基）苊酮 Ph-mhan ( 1 ) 和 2-tol-mhan ( 2 ) 合成方法。这些化合物进一步用于获得一系列含有双(芳基亚氨基)苊(Ar-bian)和单(芳基肼基)苊酮(Ar-mhan)配体的杂配阳离子钯( II )配合物：[Pd(tmp-bian)(Ph -mhan)](CF 3 SO 3 ) 2 ( 3 )、[Pd(tmp-bian)(2-tol-mhan)](CF 3 SO 3 ) 2、( 4 ) 和 [Pd(dpp-bian) (Ph-mhan)](CF 3 SO 3）2（5）。通过 X 射线衍射分析、1 H NMR、红外和紫外光谱、循环伏安法和量子化学计算对所得化合物进行了表征。所有配合物均在 Ar-bian 配体上在 -0.31 至 -0.41 V（相对于Ag/AgCl）处表现出可逆还原，随后在 Ar-bian 配体上在
• Have the Oldest Old Adults Ever Been Frail in the Past? A Hypothesis That Explains Modern Trends in Survival
  作者：A. I. Yashin、S. V. Ukraintseva、G. De Benedictis、V. N. Anisimov、A. A. Butov、K. Arbeev、D. A. Jdanov、S. I. Boiko、A. S. Begun、M. Bonafe、C. Franceschi

  DOI：10.1093/gerona/56.10.b432

  日期：2001.10.1

  Three important results concerning the shape and the trends of the human mortality rate were discussed recently in demographic and epidemiological literature. These are the deceleration of the mortality rate at old ages, the tendency to rectangularization of the survival curve, and the decline of the old age mortality observed in the second part of the 20th century. In this paper we show that all these results can be explained by using a model with a new type of heterogeneity associated with individual differences in adaptive capacity. We first illustrate the idea of such a model by considering survival in a mixture of two subpopulations of individuals (called "labile" and "stable"). These subpopulations are characterized by different Gompertz mortality patterns, such that their mortality rates cross over. The survival chances of individuals in these subpopulations have different sensitivities to changes in environmental conditions. Then we develop a more comprehensive model in which the mortality rate is related to the adaptive capacity of an organism. We show that the trends in survival patterns experienced by a mixture of such individuals resemble those obtained in an analysis of empirical data on survival in developed countries. Lastly, we present evidence of the existence of subpopulations of phenotypes in both humans and experimental organisms, which were used as prototypes in our models. The existence of such phenotypes provides the possibility that at least part of today's centenarians originated from an initially frail part of the cohort.
• Ghigi, Chemische Berichte, 1940, vol. 73, p. 677,686
  作者：Ghigi

  DOI：——

  日期：——
• Cruto, Gazzetta Chimica Italiana, 1915, vol. 45 II, p. 334
  作者：Cruto

  DOI：——

  日期：——