1.4-Dichlor-hexan | 140238-72-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1.4-Dichlor-hexan
• 英文别名: 1,4-dichlorohexane
• CAS: 140238-72-8
• 化学式: C₆H₁₂Cl₂
• mdl: MFCD17012618
• 分子量: 155.067
• InChiKey: QUBRHRAWRVZUFZ-UHFFFAOYSA-N

物化性质

• 沸点：
  177.4±8.0 °C(Predicted)
• 密度：
  1.028±0.06 g/cm3(Predicted)
• 保留指数：
  1058;1058

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三甲胺 、 1.4-Dichlor-hexan 生成 4-Chlorohexyl(trimethyl)azanium;chloride
  参考文献：
  名称：

  TANNER, D. D.;ARHART, R.;MEINTZER, CH. P., TETRAHEDRON, 1985, 41, N 19, 4261-4277

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-己烷二醇 在 吡啶 、 氯化亚砜 作用下， 生成 1.4-Dichlor-hexan
  参考文献：
  名称：

  Asinger,F. et al., Chemische Berichte, 1963, vol. 96, p. 2831 - 2840

  摘要：

  DOI：

文献信息

• Polar radicals XVIII. On the mechanism of chlorination by N-Chloroamines: Intermolecular and intramolecular abstraction
  作者：Dennis D. Tanner、Richard Arhart、Christian P. Meintzer

  DOI：10.1016/s0040-4020(01)97198-4

  日期：1985.1

  pronounced in the more polar protic solvent. The reagent, N-chlorodimethylamine, generated the dimethylamminium radical, whose reaction showed a polar sensitivity toward hydrogen abstraction similar to that of the chlorine atom, but exhibiting a much greater secondary/primary selectivity. Comparison of the isomer distributions obtained from the self photochlorination reactions of N-chloro--hexylmethylamine

  使用六氯丙酮中的分子氯或15％CD 3 CO 2 D / 85％H 2 SO 4对-丁基，-戊基和-己基三甲基氯化铵进行光氯化描述了在酸性溶剂中使用N-氯二甲基胺或使用N-氯二甲基胺。铵基团对取代位点具有很强的极性导向作用。发现在极性更强的质子溶剂中这种作用更为明显。N-氯二甲基胺试剂生成了二甲基铵基团，其反应显示出对吸氢的极性敏感性与氯原子相似，但具有更高的仲/伯选择性。从N-氯代-己基甲胺和N-氯代-己胺的自光氯化反应获得的异构体分布的比较酸溶剂中的-戊基甲胺具有通过N-氯二甲基胺氯化铵盐而获得的分布模式，这表明N-氯胺的自氯化反应是通过先前提出的分子内氢提取机理进行的。
• New free-radical halogenations of alkanes, catalysed by N-hydroxyphthalimide. Polar and enthalpic effects on the chemo- and regioselectivity
  作者：Francesco Minisci、Ombretta Porta、Francesco Recupero、Cristian Gambarotti、Roberto Paganelli、Gian Franco Pedulli、Francesca Fontana

  DOI：10.1016/j.tetlet.2003.12.130

  日期：2004.2

  Reactions of alkanes with different halogenating systems are compared in order to explore the reactivity of phthalimido-N-oxyl radical in hydrogen abstraction; the importance of polar effects is emphasised.

  比较了烷烃与不同卤代体系的反应，以探索邻苯二甲酰亚胺-N-氧基在氢提取中的反应性。强调了极性效应的重要性。
• Optical functional film, production method thereof, and polarizing plate and image display device using the same
  申请人：Muramatsu Yuuzou

  公开号：US20060233972A1

  公开（公告）日：2006-10-19

  An optical functional film comprises: a transparent support comprising a cellulose acylate film and having a thickness of less than 80 μm; and at least one coating layer on at least one surface of the transparent support, wherein said at least one coating layer has a total thickness of 5 μm or less.

  一种光学功能薄膜包括：一个透明支撑层，包括一个纤维素酰化薄膜，其厚度小于80μm;以及至少一层涂层在透明支撑层的至少一个表面上，其中所述至少一层涂层的总厚度小于5μm。
• Synthetic polymeric adsorbents and ion exchange resins, their production and processes using them
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0007792A1

  公开（公告）日：1980-02-06

  Synthetic polymeric adsorbents are produced from lightly crosslinked macroreticular aromatic copolymer beads by post crosslinking the copolymer beads while in a swollen state, the crosslinks resulting from the post-crosslinking comprising the residue of external crosslinker selected from polyfunctional alkylating agent, polyfunctional acylating agent and sulfur halide. A Friedel-Crafts catalyst may be used for the post-crosslinking. The adsorbents may be functionalized to produce ion exchange resins. The adsorbents are generally useful in processes for removing components from fluids by adsorption, particularly in adsorbing organic components from liquid or gas streams. The ion exchange resins are useful not only in ion exchange processes in general but may also be useful as catalysts.

  合成聚合物吸附剂是由轻度交联的大网状芳香族共聚物珠子在溶胀状态下通过后交联制成的，后交联产生的交联包括外部交联剂的残留物，外部交联剂选自多官能团烷基化剂、多官能团酰化剂和卤化硫。后交联可使用 Friedel-Crafts 催化剂。可对吸附剂进行官能化处理，以生产离子交换树脂。这些吸附剂通常可用于通过吸附从流体中去除成分的工艺，特别是用于吸附液流或气流中的有机成分。离子交换树脂不仅可用于一般的离子交换工艺，还可用作催化剂。
• Polyurethane biasable transfer members having improved moisture stability
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0690359A2

  公开（公告）日：1996-01-03

  The invention provides rolls, belts and other biasable members having at least one layer or coating of an elastomeric resilient polyurethane formed by reacting: (a) a polyisocyanate prepolymer comprising the reaction product of: (i) a saturated aliphatic polyisocyanate, a saturated cycloaliphatic polyisocyanate, or an aromatic polyisocyanate; and (ii) a polyol free of aliphatic unsaturation; and (b) a hardening mixture comprising: (i) a polyol of (a) (ii) or a diamine free of aliphatic unsaturation, or a mixture thereof; and, (ii)as a conductivity control agent for controlling the resistivity of the elastomeric polyurethane, from 0.001 to 5.0 weight percent, based on the total weight of the polyurethane, of an ammonium tetrahaloferrate salt having the formula:    wherein R, R¹, R and R³ are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, alkoxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, alkoxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; or wherein any two or more of R, R¹, R, or R³ can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, and X, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine. The biasable members find use in the transfer of electrostatographic toner images from a photoconductor to a final support sheet where the member electrically cooperates with a photoconductor to establish a directional force field therebetween.

  本发明提供的辊子、传送带和其他可偏置部件至少有一层或一层通过反应形成的弹性回弹聚氨酯涂层： (a) 多异氰酸酯预聚物，包括以下物质的反应产物 (i) 饱和脂肪族多异氰酸酯、饱和环脂族多异氰酸酯或芳香族多异 氰酸酯；和 (ii) 不含脂肪族不饱和度的多元醇；以及 (b) 一种硬化混合物，包括 (i) (a)(ii)的多元醇或不含脂肪族不饱和物的二胺，或它们的混合物；以及 (ii) 作为控制弹性聚氨酯电阻率的传导性控制剂，以聚氨酯总重量为基准，加入 0.001 至 5.0 重量百分数的四卤铁酸铵盐，其式如下 其中 R、R¹、R 和 R³ 相同或不同，且独立选自氢；具有 1 至 24 个碳原子的未取代烷基；具有 1 至 24 个碳原子的被一个或多个羟基、烷氧基、硝基、氰基、酮基或卤基取代的取代烷基；具有 3 至 7 个碳原子的环烷基； 具有 6 至 14 个碳原子的未取代芳基； 具有 6 至 14 个碳原子的被一个或多个羟基、烷氧基、氨基、硝基、氰基、酮基或卤素基取代的取代芳基；在烷基中具有 1 至 20 个碳原子、在芳基中具有 6 至 14 个碳原子的烷芳基； 在烷基中具有 1 至 4 个碳原子、在芳基中具有 6 至 14 个碳原子的芳烷基； 或其中任意两个或多个 R、R¹、R 或 R³ 可相互连接，形成 5 至 14 个成员的饱和或不饱和环系统，且 X（可以相同或不同）选自氟、氯、溴或碘。 这种可偏置构件可用于将电致发光调色剂图像从感光导体转移到最终支持片材上，在此过程中，构件与感光导体电性配合，在两者之间建立定向力场。