[2,4-bis(3-aminophenoxy)phenyl]diphenylphosphine oxide | 393570-77-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [2,4-bis(3-aminophenoxy)phenyl]diphenylphosphine oxide
• 英文别名: 3-[3-(3-aminophenoxy)-4-diphenylphosphorylphenoxy]aniline
• CAS: 393570-77-9
• 化学式: C₃₀H₂₅N₂O₃P
• 分子量: 492.514
• InChiKey: JQGSAYZEEVEWNT-UHFFFAOYSA-N

物化性质

• 沸点：
  697.9±55.0 °C(Predicted)
• 密度：
  1.32±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  36
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.6
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1-溴-2,4-二氟苯 在 potassium carbonate 、 magnesium 作用下， 以 四氢呋喃 、 N-甲基吡咯烷酮 、 甲苯 为溶剂， 反应 18.0h， 生成 [2,4-bis(3-aminophenoxy)phenyl]diphenylphosphine oxide
  参考文献：
  名称：

  [2,4-双（3-氨基苯氧基）苯基]二苯基膦氧化物衍生的空间环境稳定聚酰亚胺和共聚酰亚胺

  摘要：

  聚酰亚胺具有以下特性的组合：薄膜中的低太阳吸收率（α），抗原子氧（AO）和抗紫外线（UV），以酰亚胺形式在有机溶剂中的溶解度，较高的玻璃化转变（T g）温度和已经制备并表征了高热稳定性。通过在极性非质子溶剂中使新型芳族二胺[2,4-双（3-氨基苯氧基）苯基]二苯基膦氧化物（2）与芳族二酐反应来制备聚合物。由市售起始原料在两步反应中以相对高的收率制备二胺。共聚（酰胺酸）和共聚酰亚胺的制备使用2与其他市售的芳族二胺结合使用。将讨论聚合物和薄膜的化学以及物理和机械性能。

  DOI：

  10.1021/ma0201779

文献信息

• Space environmentally durable polyimides and copolyimides
  申请人：——

  公开号：US20030045670A1

  公开（公告）日：2003-03-06

  Polyimides displaying low color in thin films, atomic oxygen resistance, vacuum ultraviolet radiation resistance, solubility in organic solvents in the imide form, high glass transistion (T g ) temperatures, and high thermal stability are provided. The poly(amide acid)s, copoly(amide acid)s, polyimides and copolyimides are prepared by the reaction of stoichiometric ratios of an aromatic dianhydride with diamines which contain phenylphosphine oxide groups in polar aprotic solvents. Controlled molecular weight oligomeric (amide acid)s and imides can be prepared by offsetting the stoichiometry according to the Carothers equation using excess diamine and endcapping with aromatic anhydrides The polyimide materials can be processed into various material forms such as thin films, fibers, foams, threads, adhesive film, coatings, dry powders, and fiber coated prepreg, and uses include thin film membranes on antennas, second-surface mirrors, thermal optical coatings, and multi-layer thermal insulation (MLI) blanket materials.

  提供低颜色的聚酰亚胺薄膜，抗原子氧、真空紫外辐射、有机溶剂溶解性的聚酰亚胺，具有高玻璃转变温度（Tg）和高热稳定性。通过在极性非质子溶剂中的芳香族二酐和含有苯基膦氧基团的二胺的摩尔比反应制备聚酰亚胺和共聚酰亚胺。可以通过根据卡罗瑟方程调整摩尔比，使用过量二胺并用芳香族酐进行端基处理，制备控制分子量寡聚物（酰亚胺）和亚酰亚胺。聚酰亚胺材料可加工成各种形式的材料，如薄膜、纤维、泡沫、线、胶粘膜、涂料、干粉和涂覆纤维的预浸料，用途包括天线上的薄膜膜、第二表面镜、热光学涂层和多层热隔热毯材料。
• Fire retardant materials and devices including same
  申请人：THE BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION on behalf of THE UNIVERSITY OF NEVADA, LAS VEGAS

  公开号：US10240090B2

  公开（公告）日：2019-03-26

  This disclosure provides fire retardant materials, including polymers that include at least one pyridinium salt moiety and at least one phosphine oxide moiety. In some cases, fire retardant polymers provided herein have the following structure:

  本公开提供的阻燃材料包括包含至少一个吡啶鎓盐分子和至少一个氧化膦分子的聚合物。在某些情况下，本文提供的阻燃聚合物具有以下结构：
• Electrically conductive, optically transparent polymer/carbon nanotube composites and process for preparation thereof
  申请人：——

  公开号：US20030158323A1

  公开（公告）日：2003-08-21

  The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (T g ) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.

  本发明旨在将碳纳米管（CNT）有效分散到聚合物基质中。使用聚合物基质制备的纳米复合材料表现出独特的性能组合，最显著的是在可见光范围（即 400-800 纳米）内保持较高的光学透明度、导电性和高热稳定性。通过适当选择基体树脂，还可获得其他特性，如抗真空紫外线辐射、抗原子氧、高玻璃化转变（T g ) 温度和优异的韧性。由此产生的纳米复合材料可用于制造或配制各种物品，如各种基材、薄膜、泡沫、纤维、线、粘合剂和纤维涂层预浸料上的涂层。纳米复合材料的性能可通过选择聚合物基体和碳纳米管进行调整，从而制造出具有高光学透明度和抗静电性能的产品。
• Electrically Conductive, Optically Transparent Polymer/Carbon Nanotube Composites
  申请人：Connell John W.

  公开号：US20100084618A1

  公开（公告）日：2010-04-08

  The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (T g ) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
• Electrically Conductive, Optically Transparent Polymer/Carbon Nanotube Composites And Process For Preparation Thereof
  申请人：Connell John W.

  公开号：US20100078600A1

  公开（公告）日：2010-04-01

  The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (T g ) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.