1,3-di-n-amyl-2-imidazolidinethione | 144332-31-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 1,3-di-n-amyl-2-imidazolidinethione
• 英文别名: 1,3-diamyl-2-imidazolidinethione；1,3-Dipentylimidazolidine-2-thione；1,3-dipentylimidazolidine-2-thione
• CAS: 144332-31-0
• 化学式: C₁₃H₂₆N₂S
• 分子量: 242.429
• InChiKey: YJKRFLUUVPFGSG-UHFFFAOYSA-N

物化性质

• 沸点：
  386.9±9.0 °C(Predicted)
• 密度：
  0.99±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  38.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  potassium aquo pentachlororhodate(III) 、 1,3-di-n-amyl-2-imidazolidinethione 以 盐酸 为溶剂， 生成 mer-[RhCl3(H2O)(1,3-diamyl-2-imidazolidinethione)2]
  参考文献：
  名称：

  Extraction of rhodium(III) by 1,3-diamyl-2-imidazolidinethione from hydrochloric acid solutions

  摘要：

  The extraction of rhodium(III) with 1,3-diamyl-2-imidazolidinethione from hydrochloric acid solutions was studied. Optimum conditions for rhodium(III) extraction were determined. It was found that rhodium(III) was extracted from a 0.5 M solution of HCl at a phase contact time of 3 h by a coordination mechanism. The composition of the extracted compound was determined using electronic, (1)H and (13)C NMR, and IR spectroscopy and elemental analysis. It was demonstrated that the extracting agent coordinated to the rhodium(III) ion through the sulfur atom.

  DOI：

  10.1134/s0036023610010249
• 作为产物：
  描述：

  亚乙基硫脲 、 1-溴戊烷 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 反应 15.0h， 以37.2%的产率得到1,3-di-n-amyl-2-imidazolidinethione
  参考文献：
  名称：

  Krivonogov, V. P.; Dronov, V. I.; Khisamutdinov, R. A., Journal of applied chemistry of the USSR, 1992, vol. 65, # 12.2, p. 2293 - 2299

  摘要：

  DOI：

文献信息

• Krivonogov, V. P.; Dronov, V. I.; Khisamutdinov, R. A., Journal of applied chemistry of the USSR, 1992, vol. 65, # 12.2, p. 2293 - 2299
  作者：Krivonogov, V. P.、Dronov, V. I.、Khisamutdinov, R. A.、Afzaletdinova, N. G.、Murinov, Yu. I.、et al.

  DOI：——

  日期：——
• Extraction of rhodium(III) by 1,3-diamyl-2-imidazolidinethione from hydrochloric acid solutions
  作者：N. G. Afzaletdinova、Yu. I. Murinov、Sh. Yu. Khazhiev、R. R. Muslukhov

  DOI：10.1134/s0036023610010249

  日期：2010.1

  The extraction of rhodium(III) with 1,3-diamyl-2-imidazolidinethione from hydrochloric acid solutions was studied. Optimum conditions for rhodium(III) extraction were determined. It was found that rhodium(III) was extracted from a 0.5 M solution of HCl at a phase contact time of 3 h by a coordination mechanism. The composition of the extracted compound was determined using electronic, (1)H and (13)C NMR, and IR spectroscopy and elemental analysis. It was demonstrated that the extracting agent coordinated to the rhodium(III) ion through the sulfur atom.