N,N,N',N'-tetramethyl-9,10-bis(aminomethyl)anthracene | 166821-89-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N,N,N',N'-tetramethyl-9,10-bis(aminomethyl)anthracene
• 英文别名: 9,10-bis-diisopropylphosphanyl-anthracene；DND-192 dye；1-[10-[(dimethylamino)methyl]anthracen-9-yl]-N,N-dimethylmethanamine
• CAS: 166821-89-2
• 化学式: C₂₀H₂₄N₂
• 分子量: 292.424
• InChiKey: ADZLKYIUIDQSBV-UHFFFAOYSA-N

物化性质

• 熔点：
  >250°C
• 沸点：
  418.0±25.0 °C(Predicted)
• 密度：
  1.079±0.06 g/cm3(Predicted)
• 溶解度：
  不溶于水；溶于二甲基亚砜
• 最大波长(λmax)：
  374nm

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N,N',N'-tetramethyl-9,10-bis(aminomethyl)anthracene 、 碘甲烷 以 二氯甲烷 为溶剂， 反应 4.0h， 以76.4%的产率得到
  参考文献：
  名称：

  The synthesis of anthracene, and dipyridine salts as cations for DMIT complexes

  摘要：

  The synthesis of a series of cations for the preparation of [Ni(dmit)(2)](2) complexes is described. These cations are a series of 9,10-disubstituted anthracene derivatives with phosphane or alkylamine sustituents. Metal catalysed coupling reactions were used to prepare the 9,10-ethynylanthracene derivatives, one of which was subsequently methylated, using iodomethane as methylating reagent, to form cations for [Ni(dmit)(2)](2) salts. A range of salts were prepared using ferrocene and anthracene-based cations with [Ni(dmit)(2)](2) as the dianion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.11.007
• 作为产物：
  描述：

  蒽 在 正丁基锂 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 二氯甲烷 为溶剂， 反应 24.0h， 生成 N,N,N',N'-tetramethyl-9,10-bis(aminomethyl)anthracene
  参考文献：
  名称：

  The synthesis of anthracene, and dipyridine salts as cations for DMIT complexes

  摘要：

  The synthesis of a series of cations for the preparation of [Ni(dmit)(2)](2) complexes is described. These cations are a series of 9,10-disubstituted anthracene derivatives with phosphane or alkylamine sustituents. Metal catalysed coupling reactions were used to prepare the 9,10-ethynylanthracene derivatives, one of which was subsequently methylated, using iodomethane as methylating reagent, to form cations for [Ni(dmit)(2)](2) salts. A range of salts were prepared using ferrocene and anthracene-based cations with [Ni(dmit)(2)](2) as the dianion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.11.007

文献信息

• NORBORNENE-TYPE POLYMERS HAVING QUATERNARY AMMONIUM FUNCTIONALITY
  申请人：Bell Andrew

  公开号：US20110143260A1

  公开（公告）日：2011-06-16

  Embodiments of the present disclosure encompass vinyl addition and ROMP polymers having at least one type of repeating unit that encompasses a comprise N + (CH 3 ) 3 OH − moiety. Other embodiments in accordance with the disclosure include alkali anion-exchange membranes (AAEMs) made from one of such polymers, anion fuel cells (AFCs) that encompass such AAEMs and components of such AFCs, other than the AAEM, that encompass one of such polymers.

  本公开的实施例涵盖具有至少一种重复单元的乙烯加成和ROMP聚合物，该重复单元包括一个包含N+（CH3）3OH−基团的组分。根据本公开的其他实施例，还包括由此类聚合物之一制成的碱性阴离子交换膜（AAEMs），包括这样的AAEM的阴离子燃料电池（AFCs）以及包括这样的聚合物之一的AFC的组件，除了AAEM。
• Aminoborohydrides. 10. The Synthesis of Tertiary Amine−Boranes from Various Benzyl Halides and Lithium <i>N,N</i>-Dialkylaminoborohydrides
  作者：Christopher J. Collins、Marc Lanz、Christian T. Goralski、Bakthan Singaram

  DOI：10.1021/jo982176d

  日期：1999.4.1
• DEVICE FOR THE QUALIFICATION OF COOKING OILS, AND METHODS
  申请人：3M Innovative Properties Company

  公开号：EP2104854A1

  公开（公告）日：2009-09-30
• US8765893B2
  申请人：——

  公开号：US8765893B2

  公开（公告）日：2014-07-01
• US8765894B2
  申请人：——

  公开号：US8765894B2

  公开（公告）日：2014-07-01