4'-(10-Bromo-9-anthrylethynyl)-2,2':6',2''-terpyridine | 189497-39-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4'-(10-Bromo-9-anthrylethynyl)-2,2':6',2''-terpyridine
• 英文别名: 4-[2-(10-bromoanthracen-9-yl)ethynyl]-2,6-dipyridin-2-ylpyridine
• CAS: 189497-39-0
• 化学式: C₃₁H₁₈BrN₃
• 分子量: 512.408
• InChiKey: BCVMSXVQRPKXTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-乙炔基-2-吡啶-2-基吡啶 、 4'-(10-Bromo-9-anthrylethynyl)-2,2':6',2''-terpyridine 在 四(三苯基膦)钯 正丙胺 作用下， 反应 48.0h， 以98%的产率得到2,6-Dipyridin-2-yl-4-[2-[10-[2-(6-pyridin-2-ylpyridin-3-yl)ethynyl]anthracen-9-yl]ethynyl]pyridine
  参考文献：
  名称：

  Construction of Novel Ditopic Ligands Bearing Fused Polyaromatic and Alkyne Spacers

  摘要：

  We report the preparation of multi-component molecules based on ethynyl-substituted 2,2'-bipyridine and 2,2':6',6 ''-terpyridine derivatives and para substituted phenyl, naphtalene and anthracene moieties. The triple bonds play the role of a wire while the polyaromatic systems behave as an energy relay subunit. (C) 1997 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00412-7
• 作为产物：
  描述：

  9,10-二溴蒽 、 4'-ethynyl-2,2':6',6-terpyridine 在 四(三苯基膦)钯 正丙胺 作用下， 反应 48.0h， 以50%的产率得到4'-(10-Bromo-9-anthrylethynyl)-2,2':6',2''-terpyridine
  参考文献：
  名称：

  Construction of Novel Ditopic Ligands Bearing Fused Polyaromatic and Alkyne Spacers

  摘要：

  We report the preparation of multi-component molecules based on ethynyl-substituted 2,2'-bipyridine and 2,2':6',6 ''-terpyridine derivatives and para substituted phenyl, naphtalene and anthracene moieties. The triple bonds play the role of a wire while the polyaromatic systems behave as an energy relay subunit. (C) 1997 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00412-7

文献信息

• Construction of Novel Ditopic Ligands Bearing Fused Polyaromatic and Alkyne Spacers
  作者：Abdelkrim El-Ghayoury、Raymond Ziessel*

  DOI：10.1016/s0040-4039(97)00412-7

  日期：1997.4

  We report the preparation of multi-component molecules based on ethynyl-substituted 2,2'-bipyridine and 2,2':6',6 ''-terpyridine derivatives and para substituted phenyl, naphtalene and anthracene moieties. The triple bonds play the role of a wire while the polyaromatic systems behave as an energy relay subunit. (C) 1997 Published by Elsevier Science Ltd.