2,6-Bis(1,2,2-triphenylethenyl)pyridine | 1394025-13-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,6-Bis(1,2,2-triphenylethenyl)pyridine
• 英文别名: 2,6-bis(1,2,2-triphenylethenyl)pyridine
• CAS: 1394025-13-8
• 化学式: C₄₅H₃₃N
• 分子量: 587.764
• InChiKey: XCBMHCFNCJIQPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  46
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三苯乙烯 在 bis-triphenylphosphine-palladium(II) chloride 、 potassium phenolate 、 溴 、 甲基三辛基氯化铵 、 potassium carbonate 、 三苯基膦 作用下， 以 氯仿 、 水 、 甲苯 为溶剂， 反应 28.5h， 生成 2,6-Bis(1,2,2-triphenylethenyl)pyridine
  参考文献：
  名称：

  Pyridine-cored V-shaped π-conjugated oligomers: synthesis and optical properties

  摘要：

  A new series of V-shaped pyridine-cored pi-conjugated oligomers are synthesized utilizing two-fold Heck/Suzuki coupling reactions. Optical properties of these compounds (lambda(max)=390-449 nm, phi(eta)=79-5%, in solutions) are discussed. They are shown to be thermally stable and soluble in common organic solvents. Stilbenoid oligomers exhibited much higher fluorescence quantum yields than tri- and tetra-phenylethylene substituted oligomers in solutions. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.06.096

文献信息

• Isolation and structural characterization of a titanacyclopropane as key intermediate in the double aryl Grignard addition to 2-(arylethynyl)pyridine derivatives
  作者：Francesco Foschi、Torsten Roth、Markus Enders、Hubert Wadepohl、Eric Clot、Lutz H. Gade

  DOI：10.1039/c8cc00478a

  日期：——

  A titanacyclopropane species, which is a key reaction intermediate in the Ti(OiPr)4-mediated double aryl Grignard addition to 1,2-di(pyridin-2-yl)ethyne and related alkynes, was isolated and fully characterized. Based on this observation a one-pot synthesis of diarylated 1,2-di(pyridin-2-yl)ethanes and 2-(1,2,2-triarylvinyl)-pyridines was developed, including the tetraarylation of V-shaped 2,6-bis

  分离并充分表征了钛环丙烷物种，该物种是Ti（OiPr）4介导的双芳基格利雅（Grignard）除1,2-二（吡啶-2-基）乙炔和相关炔烃中的关键反应中间体。基于该观察结果，开发了一锅合成的二芳基化1,2-二（吡啶-2-基）乙烷和2-（1,2,2-三芳基乙烯基）-吡啶，包括V型2的四芳基化。 6-双（芳基乙炔基）吡啶。
• Luminogens for Aggregation‐Induced Emission via Titanium‐Mediated Double Nucleophilic Addition to 2,5‐Dialkynylpyridines: Formation and Transformation of the Emitting Aggregates
  作者：Francesco Foschi、Kevin Synnatschke、Sebastian Grieger、Wen‐Shan Zhang、Hubert Wadepohl、Rasmus R. Schröder、Claudia Backes、Lutz H. Gade

  DOI：10.1002/chem.201905611

  日期：2020.4

  New luminogens for aggregation-induced emission (AIE), which are characterized by a branched cross-conjugated 2,6-bis(1,2,2-triarylvinyl)pyridine motif, have been synthesized exploiting the one-pot Ti-mediated tetraarylation of 2,6-bis(arylethynyl)pyridines. Thin layer solid-state emitters were prepared by spin-coating of the luminogens, while AIE-colloidal dispersions were investigated in terms of

  利用一锅钛介导的四芳基化反应合成了用于聚集诱导发射（AIE）的新型发光剂，其特征在于分支的交叉共轭的2,6-双（1,2,2-三芳基乙烯基）吡啶基序。 2,6-双（芳基乙炔基）吡啶。薄层固态发射体是通过旋涂发光剂制备的，而AIE-胶体分散体的光密度和散射特性则得到了研究。这提供了对粒度分布，聚集体的时间演化以及不同功能化模式对分子聚集体发光的影响的深入了解。特别地，消光光谱法和动态光散射的组合被提出作为研究AIE型胶体中动态聚集过程的有力方法。
• Pyridine-cored V-shaped π-conjugated oligomers: synthesis and optical properties
  作者：Debabrata Jana、Binay K. Ghorai

  DOI：10.1016/j.tet.2012.06.096

  日期：2012.9

  A new series of V-shaped pyridine-cored pi-conjugated oligomers are synthesized utilizing two-fold Heck/Suzuki coupling reactions. Optical properties of these compounds (lambda(max)=390-449 nm, phi(eta)=79-5%, in solutions) are discussed. They are shown to be thermally stable and soluble in common organic solvents. Stilbenoid oligomers exhibited much higher fluorescence quantum yields than tri- and tetra-phenylethylene substituted oligomers in solutions. (C) 2012 Elsevier Ltd. All rights reserved.