Phenyl-bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)phosphane | 872051-40-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)phosphane
• 英文别名: phenyl-bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)phosphane
• CAS: 872051-40-6
• 化学式: C₂₄H₁₇F₂₆P
• 分子量: 830.331
• InChiKey: ORUBBYCYPVAOAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  51
• 可旋转键数：
  17
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  Phenyl-bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)phosphane 在 sodium hydroxide 作用下， 以 水 、 异丙醇 为溶剂， 反应 28.0h， 生成 9-[Bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)phosphoryl]-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononane
  参考文献：
  名称：

  Synthesis of fluorous trialkyl phosphines with the complete exclusion of PH3

  摘要：

  A novel synthetic protocol has been developed for the synthesis of fluorous tertiary phosphines excluding the use Of hazardous PH3 and with control over the number of methylene spacers and the length of fluorous ponytails. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.09.166
• 作为产物：
  描述：

  3-(perfluorohexyl)prop-1-ene 、 苯基膦 在 偶氮二异丁腈 作用下， 反应 15.0h， 以90%的产率得到Phenyl-bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)phosphane
  参考文献：
  名称：

  Synthesis of fluorous trialkyl phosphines with the complete exclusion of PH3

  摘要：

  A novel synthetic protocol has been developed for the synthesis of fluorous tertiary phosphines excluding the use Of hazardous PH3 and with control over the number of methylene spacers and the length of fluorous ponytails. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.09.166

文献信息

• Synthesis of fluorous trialkyl phosphines with the complete exclusion of PH3
  作者：Gábor Vlád、Frank U. Richter、István T. Horváth

  DOI：10.1016/j.tetlet.2005.09.166

  日期：2005.12

  A novel synthetic protocol has been developed for the synthesis of fluorous tertiary phosphines excluding the use Of hazardous PH3 and with control over the number of methylene spacers and the length of fluorous ponytails. (c) 2005 Elsevier Ltd. All rights reserved.