trichloro(9H-fluoren-9-yl)germane | 159759-72-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: trichloro(9H-fluoren-9-yl)germane
• CAS: 159759-72-5
• 化学式: C₁₃H₉Cl₃Ge
• 分子量: 344.163
• InChiKey: DLYPEVABHIRRGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.99
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trichloro(9H-fluoren-9-yl)germane 、 sodium cyclopentadienide 以 乙醚 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  The synthesis, characterization and polymerization behavior of ansa cyclopentadienyl fluorenyl complexes; the X-ray structures of the complexes [(C13H8)SiR2(C5H4)]ZrCl2 (RMe or Ph)

  摘要：

  The preparation and characterization of the ansa metallocene complexes [(C13H8)ER(2)(C5H4)]ZrCl2, [(2,7-(t)Bu(2)C(13)H(5))-SiR(2)(C5H4)ZrCl2 and [(2,7-(t)Bu(2)C(13)H(6))SiR(2)(C13H8)]ZrCl2 (E=Si or Ge; R=Me or Ph) are reported. The crystal structures of [(C(13)H(8)SiR(2)(C5H4)]ZrCl2 (R=Me, or Ph) have been determined and are discussed. The complexes are compared in respect to the polymerization behavior of propylene.

  DOI：

  10.1016/0022-328x(95)05788-q
• 作为产物：
  描述：

  芴 、 四氯化锗 在 正丁基锂 作用下， 以 正戊烷 为溶剂， 以85%的产率得到trichloro(9H-fluoren-9-yl)germane
  参考文献：
  名称：

  The synthesis, characterization and polymerization behavior of ansa cyclopentadienyl fluorenyl complexes; the X-ray structures of the complexes [(C13H8)SiR2(C5H4)]ZrCl2 (RMe or Ph)

  摘要：

  The preparation and characterization of the ansa metallocene complexes [(C13H8)ER(2)(C5H4)]ZrCl2, [(2,7-(t)Bu(2)C(13)H(5))-SiR(2)(C5H4)ZrCl2 and [(2,7-(t)Bu(2)C(13)H(6))SiR(2)(C13H8)]ZrCl2 (E=Si or Ge; R=Me or Ph) are reported. The crystal structures of [(C(13)H(8)SiR(2)(C5H4)]ZrCl2 (R=Me, or Ph) have been determined and are discussed. The complexes are compared in respect to the polymerization behavior of propylene.

  DOI：

  10.1016/0022-328x(95)05788-q

文献信息

• The synthesis, characterization and polymerization behavior of ansa cyclopentadienyl fluorenyl complexes; the X-ray structures of the complexes [(C13H8)SiR2(C5H4)]ZrCl2 (RMe or Ph)
  作者：Konstantinos Patsidis、Helmut G Alt、Wolfgang Milius、Syriac J Palackal

  DOI：10.1016/0022-328x(95)05788-q

  日期：1996.2

  The preparation and characterization of the ansa metallocene complexes [(C13H8)ER(2)(C5H4)]ZrCl2, [(2,7-(t)Bu(2)C(13)H(5))-SiR(2)(C5H4)ZrCl2 and [(2,7-(t)Bu(2)C(13)H(6))SiR(2)(C13H8)]ZrCl2 (E=Si or Ge; R=Me or Ph) are reported. The crystal structures of [(C(13)H(8)SiR(2)(C5H4)]ZrCl2 (R=Me, or Ph) have been determined and are discussed. The complexes are compared in respect to the polymerization behavior of propylene.