ortho-tolyltrichloro germane | 155728-49-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ortho-tolyltrichloro germane
• 英文别名: Trichloro-(2-methylphenyl)germane；trichloro-(2-methylphenyl)germane
• CAS: 155728-49-7
• 化学式: C₇H₇Cl₃Ge
• 分子量: 270.082
• InChiKey: SCFGQGVAQRGGCJ-UHFFFAOYSA-N

物化性质

• 沸点：
  255.9±19.0 °C(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.86
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  四氯化锗 、 甲苯 在 三氯化铝 作用下， 以 neat (no solvent) 为溶剂， 以25%的产率得到(4-甲基苯基)三氯锗烷
  参考文献：
  名称：

  Microwave-Assisted Lewis Acid Catalysis: Application to the Synthesis of Alkyl- or Arylhalogermanes

  摘要：

  Under microwave irradiation, alkyl- or arylhalogermanes RnGeX4, (R = Et, Bu, Ph; X = Cl, Br) are obtained by redistribution reactions of R4Ge with GeX4. These experimental conditions permit the synthesis of such compounds in good yield in a few minutes at atmospheric pressure. The direct Friedel-Crafts germylation of benzene and toluene by germanium tetrachloride also has been performed, but yields were low.

  DOI：

  10.1021/om00018a050

文献信息

• Microwave-Assisted Lewis Acid Catalysis: Application to the Synthesis of Alkyl- or Arylhalogermanes
  作者：Regis Laurent、Andre Laporterie、Jacques Dubac、Jacques Berlan

  DOI：10.1021/om00018a050

  日期：1994.6

  Under microwave irradiation, alkyl- or arylhalogermanes RnGeX4, (R = Et, Bu, Ph; X = Cl, Br) are obtained by redistribution reactions of R4Ge with GeX4. These experimental conditions permit the synthesis of such compounds in good yield in a few minutes at atmospheric pressure. The direct Friedel-Crafts germylation of benzene and toluene by germanium tetrachloride also has been performed, but yields were low.