2,6,2',6'-tetramethyl-4,4'-oxy-di-aniline | 129936-56-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6,2',6'-tetramethyl-4,4'-oxy-di-aniline
• 英文别名: 4.4'-Diamino-3.5.3'.5'-tetramethyl-diphenylaether；2,6,2',6'-Tetramethyl-4,4'-oxy-di-anilin；Benzenamine, 4,4'-oxybis[2,6-dimethyl-；4-(4-amino-3,5-dimethylphenoxy)-2,6-dimethylaniline
• CAS: 129936-56-7
• 化学式: C₁₆H₂₀N₂O
• 分子量: 256.348
• InChiKey: ZUGMCBYCZBUHIG-UHFFFAOYSA-N

物化性质

• 沸点：
  415.8±45.0 °C(Predicted)
• 密度：
  1.116±0.06 g/cm3 (20 ºC 760 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  61.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,6,2',6'-tetramethyl-4,4'-oxy-di-aniline 、 乙酸酐 生成 bis-(4-acetylamino-3,5-dimethyl-phenyl)-ether
  参考文献：
  名称：

  Bamberger; Rising, Justus Liebigs Annalen der Chemie, 1901, vol. 316, p. 279

  摘要：

  DOI：
• 作为产物：
  描述：

  2,6-二甲基硝基苯 在 乙醇 、 硫酸 、 ammonium chloride 、 锌 作用下， 生成 2,6,2',6'-tetramethyl-4,4'-oxy-di-aniline
  参考文献：
  名称：

  Bamberger; Rising, Justus Liebigs Annalen der Chemie, 1901, vol. 316, p. 279

  摘要：

  DOI：

文献信息

• TRIARYLAMINE DERIVATIVE, ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, AND METHOD FOR PRODUCING ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER
  申请人：KYOCERA Document Solutions Inc.

  公开号：US20170131647A1

  公开（公告）日：2017-05-11

  A triarylamine derivative represented by general formula (1) below. In the general formula (1), R 1 , R 2 , R 4 , R 5 , R 6 , R 7 , R 8 , and R 9 each represent, independently from one another, a hydrogen atom, an optionally substitute alkyl group having a carbon number of at least 1 and no greater than 6, an optionally substituted alkoxy group having a carbon number of at least 1 and no greater than 6, or an optionally substituted aryl group having a carbon number of at least 6 and no greater than 14, R 3 represents an alkyl group having a carbon number of at least 1 and no greater than 4, X represents an alkylene group having a carbon number of at least 1 and no greater than 6 or an oxygen atom, and n represents an integer of 1 to 3.

  下面是通式（1）表示的三芳胺衍生物。在通式（1）中，R1、R2、R4、R5、R6、R7、R8和R9分别独立地表示氢原子、具有至少1个碳原子且不大于6个碳原子的可选取代烷基基团、具有至少1个碳原子且不大于6个碳原子的可选取代烷氧基基团，或具有至少6个碳原子且不大于14个碳原子的可选取代芳基基团，R3表示具有至少1个碳原子且不大于4个碳原子的烷基基团，X表示具有至少1个碳原子且不大于6个碳原子的烷基基团或氧原子，n表示1到3之间的整数。
• POLYIMIDE, DIAMINE COMPOUND AND METHOD FOR PRODUCING THE SAME
  申请人：Yamaguchi Hiroaki

  公开号：US20100041860A1

  公开（公告）日：2010-02-18

  A polyimide obtained by reacting a tetracarboxylic acid component with a diamine component containing a diamine compound represented by the following general formula (1): wherein, A represents a biphenylene group which may be substituted with an alkyl group having up to 4 carbon atoms.

  一种聚酰亚胺，通过将四羧酸组分与含有由以下通式（1）表示的二胺化合物的二胺组分反应获得：其中，A代表一个联苯基团，可以用含有最多4个碳原子的烷基基团进行取代。
• Polyimides, thermosetting resin compositions containing the polyimides, formed articles of the resin compositions, and production process of the polyimides
  申请人：HITACHI CHEMICAL CO., LTD.

  公开号：EP0553612A2

  公开（公告）日：1993-08-04

  A polyimide comprises structural units represented by the following formula: wherein Ar is a group consisting of 10-90 mole % of a first specific structural sub-unit and 90-10 mole % of a second particular structural sub-unit. A process for the production of the polyimide and a thermosetting resin composition comprising the polyimide and a particular polymaleimide are also disclosed.

  聚酰亚胺包括下式所代表的结构单元： 其中 Ar 是由 10-90 摩尔%的第一种特定结构亚单元和 90-10 摩尔%的第二种特定结构亚单元组成的组。本发明还公开了聚酰亚胺的生产工艺以及包含聚酰亚胺和特定聚马来酰亚胺的热固性树脂组合物。
• PASTE COMPOSITION, AND PROTECTIVE FILM AND SEMICONDUCTOR DEVICE BOTH OBTAINED WITH THE SAME
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP1114845A1

  公开（公告）日：2001-07-11

  A paste composition which comprises as essential ingredients (A) a thermoplastic resin, (B) an epoxy resin, (C) a coupling agent, (D) a powdery inorganic filler, (E) a powder having rubber elasticity and (F) an organic solvent and which, when applied and dried, gives a coating film having a void content of 3 % by volume or higher and a water vapor permeability as measured at 40°C and 90 %RH of 500 g/m2·24h or less; a protective film which is formed by applying the paste composition to a surface of a semiconductor part and drying it and has a void content of 3 % by volume or higher and a water vapor permeability as measured at 40°C and 90 %RH of 500 g/m2·24h or less; and a semiconductor device having the protective film.

  一种糊状组合物，其基本成分包括：(A) 热塑性树脂；(B) 环氧树脂；(C) 偶联剂；(D) 粉末状无机填料；(E) 具有橡胶弹性的粉末；(F) 有机溶剂；该糊状组合物在涂抹和干燥后可形成一层涂膜，其空隙率为 3% 或更高，在 40°C 和 90%RH 条件下测得的水蒸气透过率为 500 g/m2-24h 或更低；一种保护膜，它是通过在半导体部件表面涂抹浆糊组合物并将其干燥而形成的，其空隙率为 3% 或更高，在 40°C 和 90%RH 条件下测量的水蒸气渗透率为 500 g/m2-24h 或更低；以及一种具有该保护膜的半导体器件。
• RESIN MATERIAL FOR GAS SEPARATION BASE AND PROCESS FOR PRODUCING THE SAME
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP1213049A1

  公开（公告）日：2002-06-12

  This invention relates to resin material for gas separation base containing a cardo polyimide structure in which the hydrogen atoms in the side-chain benzyl and/or allyl position are halogenated at a rate of modification by halogen of 0.1% or more or resin material for gas separation base containing polymer in which the hydrogen atoms in the side-chain benzyl and/or allyl position are halogenated at a rate of modification by halogen of 34% or more and, additionally, relates to polymer which serves as raw material for the aforementioned resin material for gas separation base containing a cardo polymer structure and a process for producing said polymer; said polymer not only excels in such properties as solvent solubility, ease of conversion to film by a wet process, thermal stability, and chemical stability but also performs well in gas permeability and the process of this invention makes it possible to produce gas separation base, particularly gas separation membrane, whose gas permeability and gas selectivity can be readily controlled.

  本发明涉及用于气体分离基础的树脂材料，该材料含有一种卡多聚酰亚胺结构，其中侧链苄基和/或烯丙基位置上的氢原子被卤化，卤化率为 0.1%或更高，或含有侧链苄基和/或烯丙基位置的氢原子被卤化的比率为 34% 或更高的聚合物的气体分离基树脂材料，此外，还涉及作为上述含有卡道聚合物结构的气体分离基树脂材料原料的聚合物以及生产上述聚合物的工艺；所述聚合物不仅在溶剂溶解性、通过湿法工艺转化为薄膜的难易程度、热稳定性和化学稳定性等性能方面表现出色，而且在气体渗透性方面也有很好的表现，本发明的工艺可以生产出气体渗透性和气体选择性易于控制的气体分离基料，特别是气体分离膜。