3-docosanoyloxymethyl-2-hydroxy-5-nitrobenzaldehyde | 111340-91-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-docosanoyloxymethyl-2-hydroxy-5-nitrobenzaldehyde
• 英文别名: (3-Formyl-2-hydroxy-5-nitrophenyl)methyl docosanoate
• CAS: 111340-91-1
• 化学式: C₃₀H₄₉NO₆
• 分子量: 519.722
• InChiKey: VHDQVIWUMRRBHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  37
• 可旋转键数：
  24
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  109
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-docosanoyloxymethyl-2-hydroxy-5-nitrobenzaldehyde 以 氯仿 、 丁酮 为溶剂， 反应 5.0h， 生成 1'-(10-piridinodecyl)-3',3'-dimethyl-6-nitro-8-icosylcarbonyloxymethyl-spiropyran bromide
  参考文献：
  名称：

  Photochromic behaviour of surfactant spiro [2H-1-benzopyran-2,2′-[2,3]-dihydroindole]s (spiropyrans) adsorbed into clay interlayers

  摘要：

  Spiro[2H-1 -benzopyran-2,2'-[2,3]-dihydroindolels (abbreviated as spiropyrans) containing long omega-pyridinoalkyl chains have been intercalated into clay interlayers and studied to observe the photochromic characteristics of the resulting molecular assemblies. 1'-Octadecyl-3',3'-dimethyl-6-nitro-8-pyridinomethyl-(SP1801(+)), 1'-(10-pyridinodecyl)-3',3'-dimethyl-6-nitro- (SP10(+)00) and 1'-(10-pyridinodecyl)-3',3'-dimethyl-6-nitro-8-icosylcarbonyloxymethyl-spiropyrans (SP10(+) 22) were all quantitatively intercalated into the clay interlayer and exhibit normal photochromism in aqueous clay dispersions. Their thermal decolourations obey simple first-order kinetics and are about one-tenth as slow in clay dispersions and about one-hundredth as slow in clay films as that in bulk solution witho ut clay at 50 degrees C. However, 1',3',3 '-trimethyl-6-nitro-8-pyridinomethylspiropyran (SP0101(+)), a homologue without a long alkyl chain, exhibits inverse photochromism and its thermal decolouration undergoes two kinds of first-order kinetics in aqueous clay dispersions. These results are explicable in terms of the restricted conformational motions of the intercalated spiropyrans.

  DOI：

  10.1039/p29950001667
• 作为产物：
  描述：

  3-氯甲基-5-硝基水杨醛 、 silver docosanoate 生成 3-docosanoyloxymethyl-2-hydroxy-5-nitrobenzaldehyde
  参考文献：
  名称：

  MIYADZAKI, DZINSEHJ;ANDO, EHJDZI

  摘要：

  DOI：

文献信息

• A method for preparing a photochromic material
  申请人：MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

  公开号：EP0389813A1

  公开（公告）日：1990-10-03

  A method for preparing a photochromic material is provided. The photochromic material is a spiropyran compound with a nitro group at the 5′ position and a long-chain alkyl group at the 1′ position. Since a nitro group is present in the compound obtained by the present method, the colored form of the compound possesses absorption sensitivity in the wavelength region of a semiconductor laser beam. Moreover, the photochromic reactions of the compound are of high stability. Furthermore, since the compound possess a long-chain substituent at the 1′ position, ultrathin films of extremely high uniformity can be formed from the compound by the Langmuir-Blodgett method.

  本发明提供了一种制备光致变色材料的方法。这种光致变色材料是一种螺吡喃化合物，其 5′位上有一个硝基，1′位上有一个长链烷基。由于本方法得到的化合物中含有硝基，因此该化合物的有色形式在半导体激光束的波长区域内具有吸收敏感性。此外，该化合物的光致变色反应具有很高的稳定性。此外，由于该化合物在 1′位置上具有长链取代基，因此可通过 Langmuir-Blodgett 法由该化合物形成均匀度极高的超薄薄膜。
• A photochromic material and an optical storage medium using the same
  申请人：MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

  公开号：EP0483542A1

  公开（公告）日：1992-05-06

  The present invention provides a photochromic material which comprises a spiropyran compound of formula (I):    wherein R¹ and R² are independently alkyl groups each containing 1 to 30 carbon atoms and Y is a halogen. The photochromic material possesses absorption sensitivity at wavelengths in the length region of about 700 nm which is the oscillation range of a semiconductor laser device, and possesses higher stability compared with conventional one when it becomes a colored form.

  本发明提供了一种光致变色材料，它由式（I）的螺吡喃化合物组成：其中 R¹ 和 R² 分别独立地为各含 1 至 30 个碳原子的烷基，Y 为卤素。 该光致变色材料在半导体激光设备的振荡范围约 700 nm 的长度区域内具有吸收灵敏度，与传统光致变色材料相比，它在变为有色形态时具有更高的稳定性。
• Ionic spiropyran compound and photochromic material conjugated it with clay
  申请人：NISSHO IWAI BENTONITE CO.,LTD.

  公开号：EP0738728A2

  公开（公告）日：1996-10-23

  Present invention provides an ionic spiropyran compounds having a long-chain alkyl group or groups at both or either of the 1- and 2-positions of 3',3'-dimethyl-6-nitrospiro[2H-1-benzopyran-2',2'-indol composite material conjugated the said ionic spiropyran compound with clay mineral. Said composite material is capable of forming a transparent thin film photo-interconvertible between the said spiropyran structure and the corresponding merocyanine structure.

  本发明提供了一种离子型螺吡喃化合物，在 3',3'-二甲基-6-硝基螺[2H-1-苯并吡喃-2',2'-吲哚]的 1 位和 2 位上都有一个或多个长链烷基，将上述离子型螺吡喃化合物与粘土矿物共轭的复合材料。 所述复合材料能够在所述螺吡喃结构和相应的美拉罗嗪结构之间形成透明的光电转换薄膜。
• MIYADZAKI, DZINSEHJ;ANDO, EHJDZI
  作者：MIYADZAKI, DZINSEHJ、ANDO, EHJDZI

  DOI：——

  日期：——
• US5360699A
  申请人：——

  公开号：US5360699A

  公开（公告）日：1994-11-01