Mn2(CO)6(Ph2SbCH2SbPh2)2 | 251465-49-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Mn2(CO)6(Ph2SbCH2SbPh2)2
• 英文别名: Carbon monoxide;diphenylstibanylmethyl(diphenyl)stibane;manganese
• CAS: 251465-49-3
• 化学式: C₅₆H₄₄Mn₂O₆Sb₄
• 分子量: 1409.84
• InChiKey: YWRKWXIRWWGVBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.06
• 重原子数：
  68
• 可旋转键数：
  12
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  羰基镁 、 bis(diphenylstibino)methane 以 甲苯 为溶剂， 以10%的产率得到Mn2(CO)6(Ph2SbCH2SbPh2)2
  参考文献：
  名称：

  Complexes of distibinomethane ligands

  摘要：

  Photolysis of Mn-2(CO)(10) with the distibinomethanes Ph2SbCH2SbPh2 (dpsm) and Me2SbCH2SbMe2 (dmsm) yields [Mn-2(CO)(6)(dpsm)(2)] and [Mn-2(CO)(8)(dmsm)], respectively, which have been characterised by IR, H-1, C-13{H-1} NMR spectroscopies and fast atom bombardment (FAB) mass spectrometry. Similar photolysis of the ligands with Re-2(CO)(10) yields axially substituted [Re-2(CO)(9)(eta(1) -distibinomethane)]. The X-ray crystal structure of [Mn-2(CO)(6)(dpsm)(2)] reveals two dpsm ligands, each bonding to the two metal centres [Mn-Mn 3.098(2), Mn-Sb 2.487(2)-2.500(2) Angstrom]. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00168-0

文献信息

• Complexes of distibinomethane ligands
  作者：Anthony R.J Genge、Nicholas J Holmes、William Levason、Michael Webster

  DOI：10.1016/s0277-5387(99)00168-0

  日期：1999.8

  Photolysis of Mn-2(CO)(10) with the distibinomethanes Ph2SbCH2SbPh2 (dpsm) and Me2SbCH2SbMe2 (dmsm) yields [Mn-2(CO)(6)(dpsm)(2)] and [Mn-2(CO)(8)(dmsm)], respectively, which have been characterised by IR, H-1, C-13H-1} NMR spectroscopies and fast atom bombardment (FAB) mass spectrometry. Similar photolysis of the ligands with Re-2(CO)(10) yields axially substituted [Re-2(CO)(9)(eta(1) -distibinomethane)]. The X-ray crystal structure of [Mn-2(CO)(6)(dpsm)(2)] reveals two dpsm ligands, each bonding to the two metal centres [Mn-Mn 3.098(2), Mn-Sb 2.487(2)-2.500(2) Angstrom]. (C) 1999 Elsevier Science Ltd. All rights reserved.