o-tert.-Butyl perbenzoesaeure-tert.-butylester | 10568-21-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-tert.-Butyl perbenzoesaeure-tert.-butylester
• 英文别名: 2-tert-Butyl-benzenecarboperoxoic acid tert-butyl ester；tert-butyl 2-tert-butylbenzenecarboperoxoate
• CAS: 10568-21-5
• 化学式: C₁₅H₂₂O₃
• 分子量: 250.338
• InChiKey: AILNOOGPPHHVSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  o-tert.-Butyl perbenzoesaeure-tert.-butylester 在 三苯基甲烷 作用下， 生成 1-溴-2-叔丁基苯 、 1-氯-2-(2-甲基-2-丙基)苯
  参考文献：
  名称：

  Giese, Bernd; Stellmach, Joachim, Chemische Berichte, 1980, vol. 113, # 10, p. 3294 - 3302

  摘要：

  DOI：
• 作为产物：
  描述：

  叔丁基过氧化氢 、 2-叔丁基苯甲酰氯 在 sodium hydroxide 、 甲基三辛基氯化铵 作用下， 以 苯 为溶剂， 以91%的产率得到o-tert.-Butyl perbenzoesaeure-tert.-butylester
  参考文献：
  名称：

  Antolini, Luciano; Benassi, Rois; Ghelli, Stefano, Journal of the Chemical Society. Perkin transactions II, 1992, # 11, p. 1907 - 1913

  摘要：

  DOI：

文献信息

• Method for oxidizing hydrocarbons
  申请人：——

  公开号：US20030176733A1

  公开（公告）日：2003-09-18

  The invention relates to a method for oxidizing substrates such as hydrocarbons, waxes or soot. The method involves the use of a compound of formula (I) in which: R1 and R2 represent H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 hydrocarbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 designate identical or different radicals or R1 and R2 can be linked to one another via a covalent bonding; Q1 and Q2 represent C, CH, N, CR5, each being the same or different; X and Z represent C, S, CH2, each being the same or different; Y represents O and OH; k=0, 1, 2; l=0, 1, 2; m=1 to 3, and; R5 represents one of the meanings of R1. Said compound is used as a catalyst in the presence of a radical initiator, whereby the molar ratio of the catalyst to the hydrocarbon is less than 10 mol %. Peroxy compounds or azo compounds can be used as the radical initiator. Preferred substrates are aliphatic or aromatic hydrocarbons.

  该发明涉及一种氧化底物（如烃、蜡或烟尘）的方法。该方法涉及使用式（I）的化合物，其中：R1和R2代表H、脂肪或芳香烷氧基基、羧基、烷氧羰基基或烃基，每个基有1到20个碳氢原子，SO3H、NH2、OH、F、Cl、Br、I和/或NO2，其中R1和R2表示相同或不同的基团，或者R1和R2可以通过共价键相连；Q1和Q2代表C、CH、N、CR5，每个基相同或不同；X和Z代表C、S、CH2，每个基相同或不同；Y代表O和OH；k=0、1、2；l=0、1、2；m=1到3；R5代表R1的一种含义。所述化合物作为催化剂在自由基引发剂存在下使用，其中催化剂与烃的摩尔比小于10mol％。过氧化物或偶氮化合物可用作自由基引发剂。首选底物为脂肪或芳香烃。
• COMPOUNDS CARRYING NITROGEN-CONTAINING BINDING GROUPS
  申请人：Arkema France

  公开号：US20190315695A1

  公开（公告）日：2019-10-17

  The invention relates to a compound of formula (I), wherein: A1 and A 2 represent, independently of one another, a binding group comprising at least one nitrogen atom; Q 1 and Q 2 represent, independently of one another, a linkage group; and x is an integer between 2 and 6, preferably between 3 and 6. The invention also relates to a rubber composition comprising said compound.

  该发明涉及一种式子为（I）的化合物，其中：A1和A2分别代表至少含有一个氮原子的结合基团；Q1和Q2分别代表连接基团；x为2到6之间的整数，最好为3到6之间的整数。该发明还涉及一种包含该化合物的橡胶组合物。
• Method for producing aromatic alcohols, especially phenol
  申请人：——

  公开号：US20030083527A1

  公开（公告）日：2003-05-01

  The invention relates to a process for preparing phenol derivatives by catalytic oxidation of an aromatic hydrocarbon to the hydroperoxide and subsequent cleavage of the hydroperoxide to give the phenol derivative and a ketone, wherein a compound of the formula I 1 where R 1 , R 2 =H, aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, in each case having from 1 to 20 carbon atoms, SO 3 H, NH 2 , OH, F, Cl, Br, I and/or NO 2 , where R 1 and R 2 are identical or different radicals or R 1 and R 2 may be joined to one another via a covalent bond, and X, Z=C, S, CH 2 Y=O, OH k=0, 1, 2 l=0, 1, 2 m=1-3; is used as oxidation catalyst in the presence of a free-radical initiator, where the molar ratio of the catalyst to the aromatic hydrocarbon is less than 10 mol %.

  该发明涉及一种制备苯酚衍生物的过程，通过催化氧化芳香烃制备过氧化氢，随后裂解过氧化氢以得到苯酚衍生物和酮类。其中，化合物I的公式为：R1，R2 = H，脂肪或芳香基烷氧基基团，羧基基团，烷氧羰基基团或烃基，每种基团均含有1至20个碳原子，SO3H，NH2，OH，F，Cl，Br，I和/或NO2，其中R1和R2是相同的或不同的基团，或者R1和R2可以通过共价键连接在一起，同时X，Z = C，S，CH2，Y = O，OH，k = 0，1，2，l = 0，1，2，m = 1-3。该化合物作为氧化催化剂，在自由基引发剂的存在下使用，其中催化剂与芳香烃的摩尔比小于10摩尔％。
• Alkali metal salts of cross-linked polymeric microgels as nucleating agents for polyethylene terephthalate moulding compositions
  申请人：CELANESE CORPORATION

  公开号：EP0112167A1

  公开（公告）日：1984-06-27

  Nucleating agents for polyethylene terephthalate moulding compositions comprise alkali metal salts of carboxylic acid-containing polymeric microgel particles which are prepared by polymerising in aqueous emulsion a monomer mixture containing about 5 to 50 percent by weight of polymerisable carboxylic acid monomers, up to 10 percent of a multifunctional cross-linking monomer and one or more carboxyl-free relatively water-insoluble polymerisable vinyl monomers.

  聚对苯二甲酸乙二醇酯模塑组合物的成核剂包括含羧酸聚合物微凝胶颗粒的碱金属盐，这种微凝胶颗粒是通过在水性乳液中聚合单体混合物制备的，该单体混合物含有约 5%至 50%（重量百分比）的可聚合羧酸单体、不超过 10%的多功能交联单体和一种或多种不含羧基的相对不溶于水的可聚合乙烯基单体。
• Water-swellable cross-linked polymeric microgel particles and aqueous dispersions of organic film-forming resins containing the same
  申请人：CELANESE CORPORATION

  公开号：EP0114478A1

  公开（公告）日：1984-08-01

  Disclosed are carboxylic acid containing polymeric microgel particles which are prepared by polymerising in aqueous emulsion a monomer mixture containing about 10-50% by weight of polymerisable carboxylic acid monomers, up to 5% of a difunctional cross-linking monomer and one or more carboxyl-free relatively water-insoluble polymerisable vinyl monomers. The resulting microgel particles are water-swellable and may be employed as stabilisers for use in the preparation of aqueous dispersions of film-forming resins containing smaller amounts of organic solvents than conventional aqueous dispersions of this type. Such dispersions are useful as coating compositions, yielding coatings having less water-sensitivity and improved adhesion as compared with coatings obtained from conventional aqueous dispersions of film-forming resins.

  本发明公开了一种含羧酸的聚合物微凝胶粒子，其制备方法是在水乳液中聚合一种单体混合物，该单体混合物含有约 10-50%（重量百分比）的可聚合羧酸单体、最多 5%的双官能团交联单体以及一种或多种不含羧基且相对不溶于水的可聚合乙烯基单体。 所得到的微凝胶粒子具有水膨胀性，可用作稳定剂，用于制备成膜树脂的水性分散体，与传统的此类水性分散体相比，其有机溶剂用量更少。 此类分散体可用作涂料组合物，与传统的成膜树脂水性分散体相比，所得到的涂料具有更低的水敏感性和更好的附着力。