6-N(1-propylamino)-(6H)-dibenz[c,e][1,2]-oxaphosphorin | 1048955-57-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 6-N(1-propylamino)-(6H)-dibenz[c,e][1,2]-oxaphosphorin
• 英文别名: 6-(N-(1-propyl)amino)-(6H)-dibenzo[c,e][1,2]-oxaphosphorin；N-propylbenzo[c][2,1]benzoxaphosphinin-6-amine
• CAS: 1048955-57-2
• 化学式: C₁₅H₁₆NOP
• 分子量: 257.272
• InChiKey: YWDSMPSYQFTBIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  21.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-N(1-propylamino)-(6H)-dibenz[c,e][1,2]-oxaphosphorin 、 1,3,5-三(2-羟乙基)氰尿酸 120.0~150.0 ℃ 、200.0 Pa 条件下， 反应 24.0h， 生成 1,3,5-Tris(2-benzo[c][2,1]benzoxaphosphinin-6-yloxyethyl)-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  METHOD FOR THE PRODUCTION OF BRIDGED DIBENZ[c,e] [1,2]-OXAPHOSPHORIN-6-OXIDES

  摘要：

  本发明涉及一种改进的方法，用于合成二苯并[c,e][1,2]-氧磷杂环戊烷-6-氧化物的单体和聚合物氮桥衍生物。这些物质可以用作聚酯，聚酰胺，聚碳酸酯，环氧树脂等聚合物的阻燃剂。

  公开号：

  US20100168423A1
• 作为产物：
  描述：

  正丙胺 、 1-propylammonium (2-hydroxy-biphenyl-2-yl)-phosphinate 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 以 正庚烷 为溶剂， 反应 0.75h， 以45%的产率得到6-N(1-propylamino)-(6H)-dibenz[c,e][1,2]-oxaphosphorin
  参考文献：
  名称：

  METHOD FOR THE PRODUCTION OF DIBENZ[C,E] [1,2]-OXAPHOSPHORIN DERIVATIVES, AMINO-DIBENZ[C,E] [1,2]-OXAPHOSPHORIN AND ALSO USE THEREOF

  摘要：

  该发明涉及一般合成（6H）-二苯[c,e][1,2]-氧代磷杂环戊烷，其在磷原子上取代氮化合物，并包括商业可获得的6H-二苯[c,e][1,2]-氧代磷杂环戊烷-6-氧化物。这些含氮（6H）-二苯[c,e][1,2]-氧代磷杂环戊烷可用作进一步合成的反应起始物质，或用作阻燃剂或稳定剂。

  公开号：

  US20100069657A1

文献信息

• Flameproof expandable polymerizates
  申请人：Eberstaller Roman

  公开号：US20120184635A1

  公开（公告）日：2012-07-19

  The invention relates to flameproof expandable polymers containing at least one blowing agent, wherein at least one phosphorus compound is contained as a flame retardant. Novel 9,10-dihydro-9-oxa-10-phosphaphenanthrene derivatives, namely 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione ammonium salt, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-ei-hydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione melaminium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione guanidinium salt, bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthrene-10-yl)sulfide, 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-ylthio)-9-oxa-10-phosphaphenanthrene-10-one, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)sulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)disulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)tetrasulfide, di(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)ether and/or 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yloxy)-9-oxa-10-phosphaphenanthrene-10-one, or ring-opened hydrolyzates thereof, are provided as flame retardants.

  本发明涉及至少含有一种发泡剂的阻燃膨胀聚合物，其中至少含有一种磷化合物作为阻燃剂。提供了新型的9,10-二氢-9-氧-10-磷杂菲衍生物，包括9,10-二氢-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮铵盐，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三聚氰胺盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮胍盐，双(9,10-二氢-9-氧-10-氧-10-磷杂菲-10-基)硫化物，9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基硫基)-9-氧-10-磷杂菲-10-酮，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)二硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)四硫化物，二(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)醚和/或9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-氧基)-9-氧-10-磷杂菲-10-酮及其开环水解物作为阻燃剂。
• FLAMMGESCHÜTZTE EXPANDIERBARE POLYMERISATE
  申请人：Sunpor Kunststoff GmbH

  公开号：EP2449018A1

  公开（公告）日：2012-05-09
• NEUE DERIVATE VON 9,10-DIHYDRO-9-OXA-10-PHOSPHAPHENANTHREN-10-ON
  申请人：Krems Chemie Chemical Services AG

  公开号：EP2449019A1

  公开（公告）日：2012-05-09
• US7973191B2
  申请人：——

  公开号：US7973191B2

  公开（公告）日：2011-07-05
• [DE] FLAMMGESCHÜTZTE EXPANDIERBARE POLYMERISATE<br/>[EN] FLAME-RETARDANT EXPANDABLE POLYMERS<br/>[FR] POLYMÉRISATS EXPANSIBLES, RETARDATEURS DE FLAMME
  申请人：SUNPOR KUNSTSTOFF GMBH

  公开号：WO2011000018A1

  公开（公告）日：2011-01-06

  Die Erfindung betrifft flammgeschützte, zumindest ein Treibmittel enthaltende, expandierbare Polymerisate, wobei als Flammschutzmittel zumindest eine Phosphorverbindung enthalten ist. Als Flammschutzmittel sind neue 9,10 Dihydro-9-oxa-10-phosphaphenanthren-Derivate, nämlich 9,10-Dihydro-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-ammoniumsalz, 9,10-Dihydro-10-mercapto-9-oxa-10-phosphaphenanthren-10-thion, 9,10 Dihydro-10-mercapto-9-oxa-10-phosphaphenanthren-10-thion-triethylammoniumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-triethylammoniumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-melaminiumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-guanidiniumsalz, Bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthren-10-yl)sulfid, 9,10-Dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-ylthio)-9-oxa-10-phosphaphenanthren-10-on, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)sulfid, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)disulfid, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)tetrasulfid, Di(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)ether und/oder 9,10-Dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yloxy)-9-oxa-10-phosphaphenanthren-10-on, oder ringgeöffnete Hydrolysate davon vorgesehen.