2-((E)-2-(4-[(E)-2-(2-naphthyl)vinyl]phenyl)vinyl)naphthalene | 16726-74-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2-((E)-2-(4-[(E)-2-(2-naphthyl)vinyl]phenyl)vinyl)naphthalene
• 英文别名: 1,4-bis(2-naphthalen-2-ylethenyl)-benzene；β,β,-Dinaphthyldivinylbenzene (β, β - DNDVB)；trans,trans-1,4-Bis-(2-naphthyl-vinyl)-benzol；2-[(1E)-2-{4-[(1E)-2-(Naphthalen-2-YL)ethenyl]phenyl}ethenyl]naphthalene；2-[(E)-2-[4-[(E)-2-naphthalen-2-ylethenyl]phenyl]ethenyl]naphthalene
• CAS: 16726-74-2
• 化学式: C₃₀H₂₂
• 分子量: 382.505
• InChiKey: FYGRKBKOHBYWNB-WXUKJITCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  对苯二甲醛 、 (naphthalen-2-ylmethyl)zinc(II) bromide 在 bis-triphenylphosphine-palladium(II) chloride 三甲基氯硅烷 作用下， 以 四氢呋喃 为溶剂， 反应 8.0h， 以80%的产率得到2-((E)-2-(4-[(E)-2-(2-naphthyl)vinyl]phenyl)vinyl)naphthalene
  参考文献：
  名称：

  的钯催化立体选择性合成（E） -Stilbenes经由有机锌试剂和羰基化合物

  摘要：

  在催化量的PdCl 2（PPh 3）2和甲硅烷基化剂的存在下，有机锌卤化物与羰基化合物反应，在温和的条件下以良好或优异的收率得到相应的（E）-芪。简要讨论了反应机理。

  DOI：

  10.1002/adsc.200606016

文献信息

• Polymers and oligomers, their synthesis, and electronic devices incorporating same
  申请人：Epstein J. Arthur

  公开号：US20050187375A1

  公开（公告）日：2005-08-25

  The invention relates to polymers and oligomers, methods of their synthesis, and electronic devices comprising them.

  这项发明涉及聚合物和寡聚物，它们的合成方法，以及包含它们的电子设备。
• Design of π-Conjugated Organic Materials for One-Dimensional Energy Transport in Nanochannels
  作者：Juan Carlos Sancho-García、Jean-Luc Brédas、David Beljonne、Jérôme Cornil、Roberto Martínez-Álvarez、Michael Hanack、Lars Poulsen、Johannes Gierschner、Hans-Georg Mack、Hans-Joachim Egelhaaf、Dieter Oelkrug

  DOI：10.1021/jp045364i

  日期：2005.3.1

  Various end-substituted distyrylbenzenes have been synthesized to serve as guest molecules in inclusion compounds to promote efficient energy transport along one-dimensional channels. Their optical and photophysical properties have been characterized at both experimental and theoretical levels. All molecules display a large transition dipole moment between the ground state and lowest excited state and hence a short radiative lifetime (on the order of 1-2 ns). They also exhibit a large spectral overlap between the emission and absorption spectra, which enables efficient energy transport between molecules arranged in a head-to-tail configuration in nanochannels. Hopping rates on the order of 10(12) s(-1) are calculated at a full quantum-chemical level; this is much larger than the radiative lifetimes and opens the way for energy migration over large distances. Changes in the nature of the terminal substituents are found to modulate the optical properties weakly but to impact significantly the energy transfer rates.
• Palladium-Catalyzed Stereoselective Synthesis of (E)-Stilbenes via Organozinc Reagents and Carbonyl Compounds
  作者：Jin-Xian Wang、Kehu Wang、Lianbiao Zhao、Hongxia Li、Ying Fu、Yulai Hu

  DOI：10.1002/adsc.200606016

  日期：——

  In the presence of a catalytic amount of PdCl2(PPh3)2 and a silylating agent, organozinc halides reacted with carbonyl compounds to give the corresponding (E)-stilbenes in good to excellent yields under mild conditions. The reaction mechanism is briefly discussed.

  在催化量的PdCl 2（PPh 3）2和甲硅烷基化剂的存在下，有机锌卤化物与羰基化合物反应，在温和的条件下以良好或优异的收率得到相应的（E）-芪。简要讨论了反应机理。