6-benzyl-6H-dibenzo[c,e][1,2λ⁵]oxaphosphinine 6-oxide | 113504-81-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6-benzyl-6H-dibenzo[c,e][1,2λ⁵]oxaphosphinine 6-oxide
• 英文别名: 10-benzyl-9-hydro-9-oxa-10-phosphaphenanthrene-10-oxide；6H-Dibenz[c,e][1,2]oxaphosphorin, 6-(phenylmethyl)-, 6-oxide；6-benzylbenzo[c][2,1]benzoxaphosphinine 6-oxide
• CAS: 113504-81-7
• 化学式: C₁₉H₁₅O₂P
• 分子量: 306.301
• InChiKey: JRCVADPCCJEFEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  氯化苄 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 苄基三乙基氯化铵 potassium carbonate 作用下， 以 1,4-二氧六环 为溶剂， 反应 514.0h， 以70%的产率得到6-benzyl-6H-dibenzo[c,e][1,2λ⁵]oxaphosphinine 6-oxide
  参考文献：
  名称：

  Arylation of 6H-dibenzo[c,e][1,2λ5]oxaphosphinine 6-oxide

  摘要：

  在磷原子上成功实现了6H-二苯并[c,e][1,2λ5]氧磷烯-6-氧化物的芳基化和烷基化。通过将6-三甲基硅氧基-6H-二苯并[c,e][1,2]氧磷烯与五氟吡啶反应，引入了四氟-4-吡啶基片段。使用铂或镍络合物催化，成功进行了该化合物与包含电子受体和电子给体取代基的芳基碘化物的芳基化反应。

  DOI：

  10.1007/s11178-005-0099-9

文献信息

• USE OF PHOSPHOROUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS AND/OR AS STABILIZERS FOR PLASTICS, FLAME-RETARDANT AND/OR STABILIZED PLASTIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF, MOULDED PART, PAINT AND COATINGS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20170260366A1

  公开（公告）日：2017-09-14

  The present invention relates to the use of phosphorous-containing organic oxyimides according to the general formula (I) as flame retardant for plastic materials, as radical generators in plastic materials and/or stabilisers for plastics. In addition, the present invention relates to a flame-retardant plastic material moulding compound in which the previously described phosphorous-containing organic oxyimides are integrated, and also to a method for the production of the previously mentioned plastic material composition. Furthermore, the present invention relates to a moulded article, a paint or a coating from the previously mentioned flame-retardant plastic material composition.

  本发明涉及根据一般式(I)的含磷有机氧亚胺化合物作为塑料材料的阻燃剂，作为塑料材料中的自由基发生剂和/或塑料的稳定剂。此外，本发明涉及一种阻燃塑料材料成型复合物，其中集成了前述的含磷有机氧亚胺化合物，并且涉及一种用于制备前述塑料材料组合物的方法。此外，本发明涉及一种从前述阻燃塑料材料组合物制成的成型制品、涂料或涂层。
• AZINE METAL PHOSPHATES AS FLAME-RETARDANT MATERIALS
  申请人：WEHNER Wolfgang

  公开号：US20150252065A1

  公开（公告）日：2015-09-10

  The present invention relates to azine metal phosphates, compositions containing the same, a process for preparing the same and their use as flame retardants. Typical representatives are (A-H) +) [MtPO 4 ] (+) .2 H 2 O and (Mel-H) (+) [AlP 2 O 7 ] (+) (where A=melamine or guanidine, Mel=melamine and Mt=Mg or Zn).

  本发明涉及偶氮金属磷酸盐，含有该物质的组合物，制备该物质的方法以及它们作为阻燃剂的用途。典型代表有(A-H)+)[MtPO4](+).2H2O和(Mel-H)(+)[AlP2O7](+)（其中A=三聚氰胺或胍，Mel=三聚氰胺，Mt=镁或锌）。
• [EN] AMINOGUANIDINEPHENYLPHOSPHINATE FLAME RETARDANT COMPOSITIONS<br/>[FR] COMPOSITIONS IGNIFUGES À BASE D'AMINOGUANIDINEPHÉNYLPHOSPHINATE
  申请人：BASF SE

  公开号：WO2011138410A1

  公开（公告）日：2011-11-10

  The present invention relates to flame retardant polymer compositions which comprise aminoguanidine phenylphosphinates and mixtures with additional flame retardants. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及含有氨基胍苯基膦酸盐和其他阻燃剂混合物的阻燃聚合物组合物。该组合物特别适用于制造基于多官能团环氧树脂或聚酯、聚酰胺和聚碳酸酯的阻燃化合物。
• Immunoassay method
  申请人：Ohzeki Katsuhisa

  公开号：US20080145869A1

  公开（公告）日：2008-06-19

  The present invention provides a method for immunoassaying an object to be analyzed including: causing to act, on a specimen or a sample including the specimen, a first protein (Y), which can specifically recognize the object to be analyzed in the specimen and is modified by a labeling substance, so as to form a complex including the object to be analyzed and Y; and measuring the labeling substance contained in the complex or the labeling substance contained in the free protein (Y), wherein the measurement of the labeling substance is performed by a chemiluminescent method which includes sensing the light generated by chemiluminescence using a photothermographic material including at least an organic silver salt, a reducing agent for silver ions and a photosensitive silver halide to form a latent image, and making the latent image visible by thermal development. An easy, quick, and highly precise immunoassay method is provided.

  本发明提供了一种免疫分析待分析物的方法，包括：在含有待分析物的样本或标本上作用第一蛋白（Y），该蛋白可以特异性地识别标本中的待分析物并被标记物质改性，以形成包括待分析物和Y的复合物；并测量复合物中包含的标记物质或自由蛋白（Y）中包含的标记物质。其中，标记物质的测量是通过化学发光法进行的，该法包括使用至少含有有机银盐、银离子还原剂和感光银卤化物的光热材料来感应化学发光所产生的光，并通过热发展使潜像可见。提供了一种简单、快速、高精度的免疫分析方法。
• MELAMINE PHENYLPHOSPHONATE FLAME RETARDANT COMPOSITIONS
  申请人：Fuchs Sabine

  公开号：US20110266507A1

  公开（公告）日：2011-11-03

  The present invention relates to flame retardant polymer compositions which comprise melamine phenylphosphonates and mixtures with dihydro-oxa-phosphaphenanthrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及阻燃聚合物组合物，其包括三聚氰胺苯基膦酸盐和与二氢氧磷菲衍生物混合物。该组合物特别适用于基于多功能环氧化合物或聚酯，聚酰胺和聚碳酸酯的阻燃化合物的制造。