1,1,1,3,3,3-hexaphenyldiplumbathiane | 1802-88-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1,1,3,3,3-hexaphenyldiplumbathiane
• 英文别名: Ph3PbSPbPh3；Bis-(triphenylplumbyl)-sulfid；Hexaphenyldiplumbathiane；triphenyl(triphenylplumbylsulfanyl)plumbane
• CAS: 1802-88-6
• 化学式: C₃₆H₃₀Pb₂S
• 分子量: 909.1
• InChiKey: CPMNXSCUILQHHN-UHFFFAOYSA-N

物化性质

• 熔点：
  139-141 °C(Solv: ethanol (64-17-5); hexane (110-54-3))
• 沸点：
  708.9±43.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.05
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三(五氟苯基)氢化锑 以 乙腈 、 苯 为溶剂， 生成 1,1,1,3,3,3-hexaphenyldiplumbathiane
  参考文献：
  名称：

  三（五氟苯基）锑化合物的合成及一些反应

  摘要：

  摘要（C6F5）3Sb已与卤素间和卤代假卤素，IX（X = Cl，Br，N3和NCO），拟卤素（SCN）和元素硫反应生成氧化加成产物（I–VI）。（C6F5）3SbS（VI）也可以通过（C6F5）3SbCl2与H2S反应制备。（C6F5）3SbCl2与适当的金属盐的易位反应生成通式为（C6F5）3SbY2的共价五配位双取代产物（V，VII–XII）（Y = NCS，NCO，-ONCMe2，-ONCMePh -NCO（CH 2） 2 CO和对-NO2C6H4OCO）。用NaN3水溶液处理（C6F5）3SbCl2，得到双核氧桥化合物，[（C6F5）3SbOSb（C6F5）3]（N3）2·（III）和（IV）也可通过取代反应获得（I）或（II）与相应的金属盐。分子量，电导率测量，并获得了新的有机锑（V）衍生物的红外光谱。（C6F5）3SbS与六芳基双联键Ar6Pb2（Ar =苯基，对甲苯基）

  DOI：

  10.1016/s0277-5387(00)84497-6

文献信息

• Bahr, Steven R.; Boudjouk, Philip, Inorganic Chemistry, 1992, vol. 31, # 19, p. 4015 - 4016
  作者：Bahr, Steven R.、Boudjouk, Philip

  DOI：——

  日期：——
• 19F NMR studies of the comparative electronegativity of the Ph3E groups (E=C, Si, Ge, Sn, or Pb) in Ph3E derivatives of tris(4-fluorophenyl)stannanethiol
  作者：D. N. Kravtsov、A. S. Peregudov、A. I. Krylova、Yu. Yu. Gorelikova

  DOI：10.1007/bf02496221

  日期：1997.6

  Compounds (4-FC6H4)(3)SnSEPh3 (E = C, Si, Ge, Sn, or Pb) were synthesized or generated in solution. The data on the comparative electronegativity of the Ph3E groups were obtained from the results of F-19 NMR spectroscopy. It was established that, except for E = C, the electronegativity changes in parallel with the absolute electronegativity of the central atom. Possible reasons for the deviation observed are discussed.
• Structural studies on Ph3MSMPh3 (M=Sn, Pb): Quest for a metal–metal bond
  作者：Neetu Singh、Rajendra Prasad、Subrato Bhattacharya

  DOI：10.1016/j.poly.2008.11.033

  日期：2009.2

  The title compounds Ph3PbSPbPh3 (1) and Ph3SnSSnPh3 (2) were prepared in high yields by a reaction of Na2S, respectively, with Ph3Pb(SOCMe) and Ph3Sn(SOCMe). X-ray crystallographic and density functional Studies were made to Understand the structure and bonding in these molecules. Though the Pb-Pb distance in 1 is only marginally shorter than the sum of the corresponding van der Waals' radii, a smaller Pb-S-Pb angle suggests for a Pb center dot center dot center dot Pb interaction. DFT calculations were performed to analyse the nature of M center dot center dot center dot M interaction in 1 and 2. Strong intramolecular pi-pi interactions subsist between the different phenyl rings of the molecules. (C) 2008 Elsevier Ltd. All rights reserved.
• BHATTACHARYA S. N.; SAXENA A. K., INDIAN J. CHEM., 1979, A 17, NO 3, 307-309
  作者：BHATTACHARYA S. N.、 SAXENA A. K.

  DOI：——

  日期：——
• Synthesis and some reactions of tris (pentafluorophenyl) antimony compounds
  作者：Prem Raj、A.K. Saxena、Kiran Singhal、Ashok Ranjan

  DOI：10.1016/s0277-5387(00)84497-6

  日期：1985.1

  Abstract (C6F5)3Sb has been found to react with interhalogens and halo-pseudohalogens, IX(X = Cl, Br, N3 and NCO), pseudohalogen (SCN), and elemental sulphur to give oxidative addition products (I–VI). (C6F5)3SbS(VI) may also be prepared by the reaction of (C6F5)3SbCl2 with H2S. Metathetical reactions of (C6F5)3SbCl2 with appropriate metallic salts yield covalent pentacoordinate disubstituted products

  摘要（C6F5）3Sb已与卤素间和卤代假卤素，IX（X = Cl，Br，N3和NCO），拟卤素（SCN）和元素硫反应生成氧化加成产物（I–VI）。（C6F5）3SbS（VI）也可以通过（C6F5）3SbCl2与H2S反应制备。（C6F5）3SbCl2与适当的金属盐的易位反应生成通式为（C6F5）3SbY2的共价五配位双取代产物（V，VII–XII）（Y = NCS，NCO，-ONCMe2，-ONCMePh -NCO（CH 2） 2 CO和对-NO2C6H4OCO）。用NaN3水溶液处理（C6F5）3SbCl2，得到双核氧桥化合物，[（C6F5）3SbOSb（C6F5）3]（N3）2·（III）和（IV）也可通过取代反应获得（I）或（II）与相应的金属盐。分子量，电导率测量，并获得了新的有机锑（V）衍生物的红外光谱。（C6F5）3SbS与六芳基双联键Ar6Pb2（Ar =苯基，对甲苯基）