perfluoro-4-isopropylbenzoic | 20017-56-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: perfluoro-4-isopropylbenzoic
• 英文别名: 4-Heptafluorisopropyl-tetrafluor-benzoesaeure；Perfluor-(4-isoproyl)-benzoesaeure；4-(CF3)2CF-C6F4COOH；2,3,5,6-Tetrafluoro-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)benzoic acid；2,3,5,6-tetrafluoro-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)benzoic acid
• CAS: 20017-56-5
• 化学式: C₁₀HF₁₁O₂
• 分子量: 362.099
• InChiKey: LZSQJYLYIHNMKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  terbium(III) hydroxide 、 perfluoro-4-isopropylbenzoic 以 异丙醇 为溶剂， 反应 1.0h， 以0.49 g的产率得到
  参考文献：
  名称：

  Synthesis and photoluminescence of Eu(III) and Tb(III) complex compounds containing anions of 4-CF3C6F4COOH and 4-(CF3)2CFC6F4COOH acids

  摘要：

  Hydrates of Eu(III) and Tb(III) salts with anions (L) 4-CF3C6F4COO- and 4-(CF3)(2)CFC6F4COO-, and also mixed-ligand complexes Ln(phen)(L)(3) were obtained. The compounds show red and green photoluminescence characteristic of Eu3+ and Tb3+ ions, respectively, in the visible region of spectrum. The intensity of the photoluminescence of the complexes containing 1,10-phenanthroline is much higher than that of compounds containing water. It is connected with sensitizing properties of phen in relation to Eu3+ and Tb3+ ions.

  DOI：

  10.1134/s1070363213060194
• 作为产物：
  描述：

  氯五氟苯 在 H₂SO₄ 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 perfluoro-4-isopropylbenzoic
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.9, 7, page 50 - 101

  摘要：

  DOI：

文献信息

• Reactions involving fluoride ion. Part I. The polyfluoroalkylation of fluorinated aromatic systems
  作者：R. D. Chambers、J. A. Jackson、W. K. R. Musgrave、R. A. Storey

  DOI：10.1039/j39680002221

  日期：——

  Highly fluorinated aromatic compounds and their derivatives will react with carbanions produced from fluorinated olefins and fluoride ion, with the formation of polyfluoroalkyl derivatives, in a process which is the nucleophilic equivalent of the Friedel-Crafts reaction in hydrocarbon chemistry. Reaction occurs between hexafluoropropene and pentafluoropyridine, pentafluoronitrobenzene, and other activated

  高度氟化的芳族化合物及其衍生物将与氟化烯烃和氟化物离子产生的碳负离子发生反应，形成多氟烷基衍生物，该过程与烃化学中的Friedel-Crafts反应的亲核当量相同。反应发生在六氟丙烯和五氟吡啶，五氟硝基苯以及其他活化系统（如八氟甲苯，五氟苄腈和五氟苯甲酸甲酯）之间。加成取代反应是通过增加烯烃的压力来实现的，CF 3 CF 2 –是比（CF 3）2 CF –更有效的亲核试剂。。氟化钾或氟化铯可用于引发，并且作为溶剂，四甘醇二甲醚和磺脲比二甲基甲酰胺，二甘醇二甲醚和三甘醇二甲醚更好。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.9, 7, page 50 - 101
  作者：

  DOI：——

  日期：——
• Drayton,C.J. et al., Journal of the Chemical Society. Perkin transactions I, 1975, p. 1035 - 1040
  作者：Drayton,C.J. et al.

  DOI：——

  日期：——
• Synthesis and photoluminescence of Eu(III) and Tb(III) complex compounds containing anions of 4-CF3C6F4COOH and 4-(CF3)2CFC6F4COOH acids
  作者：S. V. Larionov、T. G. Leonova、E. M. Uskov、M. I. Rakhmanova、V. E. Platonov、V. M. Karpov、V. P. Fadeeva

  DOI：10.1134/s1070363213060194

  日期：2013.6

  Hydrates of Eu(III) and Tb(III) salts with anions (L) 4-CF3C6F4COO- and 4-(CF3)(2)CFC6F4COO-, and also mixed-ligand complexes Ln(phen)(L)(3) were obtained. The compounds show red and green photoluminescence characteristic of Eu3+ and Tb3+ ions, respectively, in the visible region of spectrum. The intensity of the photoluminescence of the complexes containing 1,10-phenanthroline is much higher than that of compounds containing water. It is connected with sensitizing properties of phen in relation to Eu3+ and Tb3+ ions.