1-phenyl-7-tributylstannyl-1,6-heptadiyne | 1222989-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-7-tributylstannyl-1,6-heptadiyne
• 英文别名: Tributyl(7-phenylhepta-1,6-diynyl)stannane；tributyl(7-phenylhepta-1,6-diynyl)stannane
• CAS: 1222989-84-5
• 化学式: C₂₅H₃₈Sn
• 分子量: 457.287
• InChiKey: WBWYEINCMLJECX-UHFFFAOYSA-N

物化性质

• 沸点：
  483.5±47.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.28
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-phenyl-7-tributylstannyl-1,6-heptadiyne 在 titanium(IV) isopropylate 、 copper(l) iodide 、 四(三苯基膦)钯 、 碘 、 异丙基氯化镁 作用下， 以 乙醚 、 二氯甲烷 、 甲苯 为溶剂， 反应 38.5h， 生成
  参考文献：
  名称：

  Phosphole‐ and Benzodithiophene‐Based Copolymers: Synthesis and Application in Organic Photovoltaics

  摘要：

  AbstractTwo kinds of phosphole‐ and benzodithiophene‐based copolymers bearing PV=O or PV=NSO2C8H17 functions were prepared by Pd–CuI‐promoted Stille coupling reactions, and their optical and electrochemical properties were investigated. Bulk heterojunction organic photovoltaic devices comprised of the new P,S‐bridged copolymers and (6,6)‐phenyl‐C71‐butyric acid methyl ester (PC71BM) exhibited power conversion efficiencies of up to 0.65 % under AM1.5 irradiation at 100 mW cm–2.

  DOI：

  10.1002/ejic.201301132

文献信息

• Phosphole‐ and Benzodithiophene‐Based Copolymers: Synthesis and Application in Organic Photovoltaics
  作者：Yoshihiro Matano、Hiroshi Ohkubo、Tetsushi Miyata、Yusuke Watanabe、Yukiko Hayashi、Tomokazu Umeyama、Hiroshi Imahori

  DOI：10.1002/ejic.201301132

  日期：2014.4

  AbstractTwo kinds of phosphole‐ and benzodithiophene‐based copolymers bearing PV=O or PV=NSO2C8H17 functions were prepared by Pd–CuI‐promoted Stille coupling reactions, and their optical and electrochemical properties were investigated. Bulk heterojunction organic photovoltaic devices comprised of the new P,S‐bridged copolymers and (6,6)‐phenyl‐C71‐butyric acid methyl ester (PC71BM) exhibited power conversion efficiencies of up to 0.65 % under AM1.5 irradiation at 100 mW cm–2.