4,4'-Divinyloxy-biphenyl | 93022-01-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-Divinyloxy-biphenyl
• 英文别名: 1-Ethenoxy-4-(4-ethenoxyphenyl)benzene
• CAS: 93022-01-6
• 化学式: C₁₆H₁₄O₂
• 分子量: 238.286
• InChiKey: KDMKNYRMJYZBBQ-UHFFFAOYSA-N

物化性质

• 沸点：
  346.3±35.0 °C(Predicted)
• 密度：
  1.054±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙酸乙烯酯 、 4,4'-二羟基联苯 在 bis(1,5-cyclooctadiene)diiridium(I) dichloride 、 sodium carbonate 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以80%的产率得到4,4'-Divinyloxy-biphenyl
  参考文献：
  名称：

  IRIDIUM-CATALYZED SYNTHESIS OF VINYL ETHERS FROM ALCOHOLS AND VINYL ACETATE

  摘要：

  DOI：

  10.15227/orgsyn.082.0055

文献信息

• RESIST POLYMER, RESIST COMPOSITION, PROCESS FOR PATTERN FORMATION, AND STARTING COMPOUNDS FOR PRODUCTION OF THE RESIST POLYMER
  申请人：Momose Hikaru

  公开号：US20090198065A1

  公开（公告）日：2009-08-06

  To provide a resist polymer comprising, as a structural unit, an acid-decomposable unit having a structure represented by formula (1) or (2) which exhibits a small line edge roughness and produces little defects in DUV excimer laser lithography or the like. In formulas (1) and (2), n represents an integer of 2 to 24; J represents a single bond or a divalent hydrocarbon group which may have a substituent/heteroatom when n=2, or represents an n-valent hydrocarbon group which may have a substituent/heteroatom when n≧3; E represents a residue of a polymerization terminator, a chain transfer agent or a polymerization initiator; K 1 and K 2 each represent at least one selected from alkylene, cycloalkylene, oxyalkylene, arylene, a divalent thiazoline ring, a divalent oxazoline ring and a divalent imidazoline ring; L 1 and L 2 each represent at least one selected from —C(O)O—, —C(O)— and —OC(O)—; M 1 , M 2 and M 3 each represent at least one selected from alkylene, cycloalkylene, oxyalkylene and arylene; Y, Y 1 and Y 2 each represent an acid-decomposable linkage; k1, k2, l1, l2, m1, m2, and m3 each represent 0 or 1; and R 1 represents H or a methyl group.

  提供一种抗蚀聚合物，其由一个具有结构式（1）或（2）所表示的酸分解单元作为结构单元，能够在DUV准分子激光微影或类似工艺中表现出小的线边粗糙度并产生少量缺陷。在式（1）和（2）中，n表示2至24的整数；J表示单键或二价碳氢基团，当n=2时可以具有取代基/杂原子，或者当n≥3时可以表示n价碳氢基团，可以具有取代基/杂原子；E表示聚合终止剂、链转移剂或聚合引发剂的残基；K1和K2分别表示至少选择自烷基、环烷基、氧烷基、芳烃、二价噻唑环、二价噁唑环和二价咪唑环中的至少一种；L1和L2分别表示至少选择自—C（O）O—、—C（O）—和—OC（O）—中的至少一种；M1、M2和M3分别表示至少选择自烷基、环烷基、氧烷基和芳烃中的至少一种；Y、Y1和Y2分别表示酸分解键；k1、k2、l1、l2、m1、m2和m3分别表示0或1；R1表示H或甲基基团。
• CURABLE COMPOSITION, CURED PRODUCT, AND COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20220177641A1

  公开（公告）日：2022-06-09

  a curable composition that gives a cured product exhibiting a high refractive index and a surface without defects such as roughness or cracks, a cured product of the composition, and a compound that may be blended to the composition. In a curable composition including a triazine compound having three aromatic-ring-containing groups each bonded to the triazine ring via an amino group, an aromatic-ring-containing group having a specific structure having a radically polymerizable group-containing group or a cationically polymerizable group-containing group is used as at least one of the three aromatic-ring-containing groups bonded to the triazine ring in the triazine compound mentioned above.

  一种可治愈的组合物，可产生具有高折射率和表面无缺陷（如粗糙或裂纹）的固化产品，该组合物的固化产品以及可混合到该组合物中的化合物。在包括三嗪化合物的可固化组合物中，每个含有芳香环的基团均通过氨基与三嗪环结合，具有特定结构的含芳香环基团具有具有自由基聚合基团或阴离子聚合基团的群组，至少用作上述三嗪化合物中与三嗪环结合的三个芳香环含基团之一。
• Curable composition, adhesive, method of producing fiber-reinforced composite material, and fiber-reinforced composite material
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP2930200A1

  公开（公告）日：2015-10-14

  A curable composition is obtained by blending a polymerizable compound (A) having predetermined kinds of polymerizable functional groups, a reactive compound (B) having predetermined kinds of reactive functional groups, a compound (C) which is an imidazolyl group-containing compound having a predetermined structure, and a compound (D) which is an oxime compound or an oxime ester compound having a predetermined structure.

  将具有预定种类可聚合官能团的可聚合化合物 (A)、具有预定种类活性官能团的活性化合物 (B)、具有预定结构的含咪唑基化合物 (C) 和具有预定结构的肟化合物或肟酯化合物 (D) 混合在一起，可得到一种可固化组合物。
• Curable composition, cured product of the curable composition, and method of producing a cured product using the curable composition
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US10479879B2

  公开（公告）日：2019-11-19

  A cationically polymerizable curable composition comprising a compound having a vinyloxy group bonded to an aromatic group which is easily cured upon light exposure and/or heating, a cured product of the curable composition, and a method of producing a cured product using the curable composition. In a cationically polymerizable curable composition that includes a compound having a vinyloxy group bonded to an aromatic group, a sulfonium salt having a specific structure is used as a curing agent. A cured product is produced by shaping the curable composition into a predetermined shape, and subjecting the shaped curable composition to light exposure and/or heating.

  一种阳离子可聚合固化组合物，其中包含一种具有与芳香基键合的乙烯氧基的化合物，该化合物在光照和/或加热时容易固化；一种固化组合物的固化产品；以及一种使用该固化组合物生产固化产品的方法。在阳离子可聚合固化组合物中，包括一种具有与芳香基键合的乙烯氧基的化合物，具有特定结构的锍盐被用作固化剂。通过将固化组合物塑造成预定形状，并将塑造好的固化组合物进行光照和/或加热，即可制成固化产品。
• Curable composition, cured film, display panel, and method for producing cured product
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US10640607B2

  公开（公告）日：2020-05-05

  A curable composition having satisfactory curability, capable of forming a cured product having satisfactory heat resistance and adhesion to a base material, a cured film made of a cured product of the curable composition, a display panel provided with the cured film, and a method for producing a cured product using the above-mentioned curable composition. The curable composition includes a curable compound and a thermal cationic polymerization initiator, the curable compound contains a cationic polymerizable compound containing, as a main skeleton, a fused ring in which three or more rings including an aromatic ring are fused, and the thermal cationic polymerization initiator contains a quaternary ammonium salt-type compound having a specific structure.

  一种固化组合物，具有令人满意的固化性，能够形成具有令人满意的耐热性和与基底材料的粘附性的固化物，由该固化组合物的固化物制成的固化膜，具有该固化膜的显示面板，以及使用上述固化组合物生产固化物的方法。可固化组合物包括一种可固化化合物和一种热阳离子聚合引发剂，可固化化合物含有一种阳离子可聚合化合物，其主骨架含有一个融合环，其中包括一个芳香环在内的三个或三个以上的环被融合，热阳离子聚合引发剂含有一种具有特定结构的季铵盐型化合物。