3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoic acid 2-(2-ethoxyethoxy)ethyl ester | 1591653-32-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoic acid 2-(2-ethoxyethoxy)ethyl ester
• 英文别名: 2-(2-Ethoxyethoxy)ethyl 3-bis(2,4,6-trimethylbenzoyl)phosphorylpropanoate；2-(2-ethoxyethoxy)ethyl 3-bis(2,4,6-trimethylbenzoyl)phosphorylpropanoate
• CAS: 1591653-32-5
• 化学式: C₂₉H₃₉O₇P
• 分子量: 530.598
• InChiKey: TZCGPRNIGYBVSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  37
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  96
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  膦,二(2,4,6-三甲基苯甲酰)- 在 盐酸 、 双氧水 、 三乙胺 作用下， 以 乙二醇二甲醚 、 乙醚 、 水 、 甲苯 为溶剂， 反应 18.75h， 生成 3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoic acid 2-(2-ethoxyethoxy)ethyl ester
  参考文献：
  名称：

  [EN] A PROCESS FOR THE PREPARATION OF ACYLPHOSPHANES
  [FR] PROCÉDÉ POUR LA PRÉPARATION D'ACYLPHOSPHANES

  摘要：

  本发明涉及一种多功能、高效的过程，用于制备单酰基和双酰基膦化合物，以及它们对应的氧化物或硫化物。该发明还涉及通过该过程获得的新型光引发剂。

  公开号：

  WO2014053455A1

文献信息

• NOVEL CROSS-LINKER FOR THE PREPARATION OF A NEW FAMILY OF SINGLE ION CONDUCTION POLYMERS FOR ELECTROCHEMICAL DEVICES AND SUCH POLYMERS
  申请人：Belenos Clean Power Holding AG

  公开号：US20160168086A1

  公开（公告）日：2016-06-16

  A specific cross-linker, an alkaline metal bis(styrenesulfonyl)imide monomer, is used in the synthesis of single ionic conductive copolymers that are non-fluorinated and non-PEO based. Such copolymers meet the security and costs requirements to be used as solid polymers electrolytes (SPE). They are promising alternatives to standard liquid electrolytes in alkaline metal-ion batteries because of their improved security and inflammability properties. The copolymers described are either polyvinylsulfonates or acrylate vinylsulfonate block-copolymers. Preferred acrylate monomers are methacrylates and preferred vinylsulfonates are styrene sulfonates. The copolymer is prepared by radical polymerization of the vinyl sulfonate and the cross-linker and optionally the acrylate, in particular radical photopolymerization using a functionalized bis(acyl)phosphane oxide (BAPO) as photoinitiator. Also described is the use of such copolymer as solid polymer electrolyte in a lithium ion battery.

  一种特定的交联剂，一种碱金属双(苯乙烯磺酰)亚胺单体，用于合成非氟化和非PEO基础的单离子导电共聚物。这种共聚物符合作为固体聚合物电解质(SPE)使用的安全性和成本要求。由于其改善的安全性和不易燃性能，这些共聚物是碱金属离子电池中标准液态电解质的有希望的替代品。所描述的共聚物可以是聚乙烯磺酸盐或丙烯酸乙烯磺酸盐嵌段共聚物。优选的丙烯酸酯单体是甲基丙烯酸酯，优选的乙烯磺酸盐是苯乙烯磺酸盐。该共聚物通过乙烯磺酸盐和交联剂以及可选的丙烯酸酯的自由基聚合制备，特别是使用功能化的双(酰基)膦氧化物(BAPO)作为光引发剂的自由基光聚合。还描述了将这种共聚物用作锂离子电池中的固体聚合物电解质。
• A PROCESS FOR THE PREPARATION OF ACYLPHOSPHANES
  申请人：ETH ZÜRICH

  公开号：US20150299231A1

  公开（公告）日：2015-10-22

  The present invention provides a process for the preparation of mono- and bisacylphosphanes based on formula (I): as well as for their corresponding oxides or sulfides. The present invention further relates to photoinitiators obtainable by said process.

  本发明提供了一种基于公式(I)的单酰基和双酰基膦的制备方法，以及它们相应的氧化物或硫化物的制备方法。本发明还涉及通过该方法获得的光引发剂。
• Process for the preparation of acylphosphanes
  申请人：ETH ZUERICH

  公开号：US10273258B2

  公开（公告）日：2019-04-30

  The present invention provides a process for the preparation of mono- and bisacylphosphanes based on formula (I): as well as for their corresponding oxides or sulfides. The present invention further relates to photoinitiators obtainable by said process.

  本发明提供了一种基于式（I）的单膦酸和双膦酸的制备方法： 及其相应氧化物或硫化物的工艺。本发明还涉及可通过上述工艺获得的光引发剂。
• PROCESS FOR THE PREPARATION OF ACYLPHOSPHANES
  申请人：ETH ZUERICH

  公开号：US20180002357A1

  公开（公告）日：2018-01-04

  The present invention provides a process for the preparation of mono- and bisacylphosphanes based on formula (I): as well as for their corresponding oxides or sulfides. The present invention further relates to photoinitiators obtainable by said process.
• US9701700B2
  申请人：——

  公开号：US9701700B2

  公开（公告）日：2017-07-11