[EN] AMINOSILANE-FUNCTIONALIZED DIENES FOR USE IN FUNCTIONALIZATION OF ELASTOMERIC POLYMERS<br/>[FR] DIÈNES À FONCTIONNALITÉ AMINOSILANE DESTINÉS À ÊTRE UTILISÉS DANS LA FONCTIONNALISATION DE POLYMÈRES ÉLASTOMÈRES
申请人:TRINSEO EUROPE GMBH
公开号:WO2017067877A1
公开(公告)日:2017-04-27
The present invention relates to novel aminosiIane-functionalized diene compounds of the following Formula 1; wherein each R' is independently selected from C1-C12 alkyl, C6-C18 aryl, C7-C18 alkylaryl, tri(C1-C6, alkyl, C6-C12 aryl or C7-C18 alkylaryl)silyl and allyl, wherein two R' groups may be connected to form a ring and the ring may contain, further to the Si-bonded nitrogen atom, one or more of an oxygen atom, a nitrogen atom, an >N(C1-C6 alkyl or C7-C18 alkylaryl) group and a sulfur atom: each R" is independently selected from C1-C6 hydrocarbyl; Ra, Rb Rc, Rd and Re are independently selected from hydrogen, methyl and ethyl; x is an integer selected from 0, 1 and 2, y is an integer selected from 1, 2 and 3 and x + y = 3. The diene compounds are useful as modifying monomers in the polymerization of conjugated diene monomers, optionally together with aromatic vinyl monomers, thus producing polymers, specifically elastomeric polymers, which can favorably be used in rubber articles such as tires. The present invention further relates to a process for preparing said diene compounds, a process for preparing an elastomeric polymer, involving the use of said diene compounds, the thus-obtainable elastomeric polymer, a non-cured or cured (vulcanized ) polymer composition including said elastomeric polymer, a method of making the vulcanized polymer composition, and an article comprising a component formed from the vulcanized polymer composition.
本发明涉及以下式子1的新型氨基硅烷官能化二烯化合物;其中每个R'独立选择自C1-C12烷基,C6-C18芳基,C7-C18烷基芳基,三(C1-C6烷基,C6-C12芳基或C7-C18烷基芳基)硅基和烯丙基,其中两个R'基团可以连接形成环,并且该环可能包含除了硅键合氮原子外的一个或多个氧原子,氮原子,>N(C1-C6烷基或C7-C18烷基芳基)基团和硫原子:每个R"独立选择自C1-C6烃基;Ra,Rb,Rc,Rd和Re独立选择自氢,甲基和乙基;x是选择自0、1和2的整数,y是选择自1、2和3的整数,并且x+y=3。该二烯化合物在共轭二烯单体的聚合中作为改性单体有用,可选与芳香族乙烯单体一起使用,从而产生聚合物,特别是弹性聚合物,可有利地用于橡胶制品,如轮胎。本发明还涉及制备所述二烯化合物的方法,涉及使用所述二烯化合物的弹性聚合物的制备方法,涉及得到的弹性聚合物,包括所述弹性聚合物的未固化或固化(硫化)聚合物组合物,制备硫化聚合物组合物的方法,以及包括从硫化聚合物组合物形成的组件的物品。