bis[di(2-phenylethyl)selenophosphoryl]selenide | 1227311-56-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis[di(2-phenylethyl)selenophosphoryl]selenide
• 英文别名: bis[di(2-phenethyl)selenophosphoryl]selenide；bis[di(phenethyl)selenophosphoryl]selenide；bis(2-phenylethyl)phosphinoselenoylselanyl-bis(2-phenylethyl)-selanylidene-λ5-phosphane
• CAS: 1227311-56-9
• 化学式: C₃₂H₃₆P₂Se₃
• 分子量: 719.465
• InChiKey: UXXCQMYVKVOMQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.69
• 重原子数：
  37
• 可旋转键数：
  14
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  bis(2-phenethyl)phosphine 在 selenium 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以92%的产率得到bis[di(2-phenylethyl)selenophosphoryl]selenide
  参考文献：
  名称：

  A novel simple synthesis of bis(diorganoselenophosphoryl)selenides (R2PSe)2Se from secondary phosphines and elemental selenium

  摘要：

  Secondary phosphines R2PH [R = Ph(CH2)(2), 4-t-BuC6H4(CH2)(2), 4-MeOC6H4(CH2)(2), 2-Naphth(CH2)(2)] react with two equivalents of elemental selenium under mild conditions (85 C, 3 h, toluene) to afford bis(diorganoselenophosphoryl)selenides (R2PSe)(2)Se in high yields (75-92%). (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.02.068

文献信息

• Reaction of secondary phosphine selenides with elemental selenium: Synthesis of bis(diorganoselenophosphoryl)selenides
  作者：A. V. Artem’ev、N. K. Gusarova、S. F. Malysheva、I. A. Ushakov、B. A. Trofimov

  DOI：10.1134/s1070363210100312

  日期：2010.10
• Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine
  作者：Alexander V. Artem’ev、Svetlana F. Malysheva、Boris G. Sukhov、Nataliya A. Belogorlova、Yurii V. Gatilov、Victor I. Mamatyuk、Nina K. Gusarova

  DOI：10.1016/j.mencom.2012.01.006

  日期：2012.1

  Redox reaction between alkali metal diselenophosphinates R2P(Se)SeM (M = Na, K) and elemental iodine in a 2:1 molar ratio (1,4-dioxane, room temperature, 2 min) gives bis(diorganylselenophosphoryl)selenides [R2P(Se)](2)Se and bis(diorganylselenophosphoryl)triselenides [R2P(Se)](2)Se-3 in 87-90% total yields.
• A novel simple synthesis of bis(diorganoselenophosphoryl)selenides (R2PSe)2Se from secondary phosphines and elemental selenium
  作者：Alexander V. Artem’ev、Nina K. Gusarova、Svetlana F. Malysheva、Igor A. Ushakov、Boris A. Trofimov

  DOI：10.1016/j.tetlet.2010.02.068

  日期：2010.4

  Secondary phosphines R2PH [R = Ph(CH2)(2), 4-t-BuC6H4(CH2)(2), 4-MeOC6H4(CH2)(2), 2-Naphth(CH2)(2)] react with two equivalents of elemental selenium under mild conditions (85 C, 3 h, toluene) to afford bis(diorganoselenophosphoryl)selenides (R2PSe)(2)Se in high yields (75-92%). (c) 2010 Elsevier Ltd. All rights reserved.