diphenethyl(15-phenethyl-17-phenyl-15-thioxo-3,6,9,12-tetraoxa-15λ⁵-phosphaheptadecyl)phosphine sulfide | 1411984-53-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenethyl(15-phenethyl-17-phenyl-15-thioxo-3,6,9,12-tetraoxa-15λ⁵-phosphaheptadecyl)phosphine sulfide
• 英文别名: 2-[2-[2-[2-[2-[Bis(2-phenylethyl)phosphinothioyl]ethoxy]ethoxy]ethoxy]ethoxy]ethyl-bis(2-phenylethyl)-sulfanylidene-lambda5-phosphane；2-[2-[2-[2-[2-[bis(2-phenylethyl)phosphinothioyl]ethoxy]ethoxy]ethoxy]ethoxy]ethyl-bis(2-phenylethyl)-sulfanylidene-λ5-phosphane
• CAS: 1411984-53-6
• 化学式: C₄₂H₅₆O₄P₂S₂
• 分子量: 750.984
• InChiKey: ULKITYZDORURGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  50
• 可旋转键数：
  27
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  bis(2-phenethyl)phosphine 在 sulfur 作用下， 以 苯 为溶剂， 反应 1.5h， 生成 diphenethyl(15-phenethyl-17-phenyl-15-thioxo-3,6,9,12-tetraoxa-15λ⁵-phosphaheptadecyl)phosphine sulfide
  参考文献：
  名称：

  Atom-Economic, Metal- and Halogen-Free Synthesis of Podands: α,ω-Diphosphines and Their Chalcogenides Separated by Alkane Diol Spacers

  摘要：

  Secondary phosphines and phosphine chalcogenides add to the divinyl ether of alpha,omega-alkane diols regio- and chemoselectively under free-radical conditions (UV irradiation or AIBN, 2:1 reactants molar ratio) to give anti-Markovnikov diadducts in good to excellent yields (65-98%).

  DOI：

  10.1055/s-0032-1316764

文献信息

• Atom-Economic, Metal- and Halogen-Free Synthesis of Podands: α,ω-Diphosphines and Their Chalcogenides Separated by Alkane Diol Spacers
  作者：Boris Trofimov、Ludmila Oparina、Nina Gusarova、Oksana Vysotskaya、Nikita Kolyvanov、Alexander Artem’ev

  DOI：10.1055/s-0032-1316764

  日期：——

  Secondary phosphines and phosphine chalcogenides add to the divinyl ether of alpha,omega-alkane diols regio- and chemoselectively under free-radical conditions (UV irradiation or AIBN, 2:1 reactants molar ratio) to give anti-Markovnikov diadducts in good to excellent yields (65-98%).