tert-butylphenyl-2-(3-thiophenyl)ethylphosphine oxide | 1445236-19-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert-butylphenyl-2-(3-thiophenyl)ethylphosphine oxide
• 英文别名: t-butyl-2-(3'-thienyl)ethyl-phenyl phosphine oxide；3-[2-[Tert-butyl(phenyl)phosphoryl]ethyl]thiophene；3-[2-[tert-butyl(phenyl)phosphoryl]ethyl]thiophene
• CAS: 1445236-19-0
• 化学式: C₁₆H₂₁OPS
• 分子量: 292.382
• InChiKey: VCZJOVHYGPUEKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  45.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(3-thienyl)ethyl chloride 、 tert-Butylphenylphosphine oxide 在 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 24.0h， 以84.9%的产率得到tert-butylphenyl-2-(3-thiophenyl)ethylphosphine oxide
  参考文献：
  名称：

  Phosphine oxide, a process for the manufacture thereof and application thereof

  摘要：

  公开号：

  EP2639233B1

文献信息

• Phosphine oxide, a process for the manufacture thereof and application thereof
  申请人：Centrum Badan Molekularnych I Makromolekularnych Pan

  公开号：EP2639233B1

  公开（公告）日：2017-01-04
• The Chemo- and Electropolymerization of Thiophene Derivatives Containing at the Third Position of A Substituent with A Stereogenic Phosphorus Atom
  作者：Anna Fenyk、Dorota Krasowska、Paweł Urbaniak、Józef Drabowicz

  DOI：10.1080/10426507.2012.740107

  日期：2013.4.1

  Recently, differently functionalized polythiophenes (PTs) have found a broad application in material chemistry. Now, we are working in our laboratories on the synthesis of such derivatives functionalized at the third postion of a thiophene ring with a substituent containing a stereogenic heteroatom. In this paper, we would like to report our preliminary results devoted to the chemo- and electropolymerizations of monomeric thiophene derivatives. The classical three-electrode system used for electropolymerization carried out on platinum (Pt), glassy carbon (GC), and gold (Au) electrodes in acetonitrile with lithium perchlorate as the supporting electrolyte electrolyte will be presented. The chemical polymerization was based on the oxidative coupling using ferric chloride, leading to high molecular weight products.