(5-Ethyl-2-nonyl-1,3-dioxan-5-YL)methanol | 116651-92-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: (5-Ethyl-2-nonyl-1,3-dioxan-5-YL)methanol
• 英文别名: (5-ethyl-2-nonyl-1,3-dioxan-5-yl)methanol
• CAS: 116651-92-4
• 化学式: C₁₆H₃₂O₃
• 分子量: 272.428
• InChiKey: PSQZTZBHTKCBJJ-UHFFFAOYSA-N

物化性质

• 沸点：
  363.6±17.0 °C(Predicted)
• 密度：
  0.919±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (5-Ethyl-2-nonyl-1,3-dioxan-5-YL)methanol 在 亚碘酰苯 、 三乙胺 作用下， 以 乙醚 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  Synthesis of ethriolophospholipids of acetal type

  摘要：

  New analogues of acetal-type phospholipids were obtained on the basis of ethriol (2-hydroxymethyl-2-ethyl-1,3-propanediol). The starting triol originally was condensed with decanal or dodecanal to form acetals, which were then phosphorylated with tetraethyidiamidophosphorous acid chloride. The amidophosphites were further oxidized with iodosobenzene or sulfurized to the corresponding acetal-type phospholipids and their thio analogues.

  DOI：

  10.1134/s1068162006050153
• 作为产物：
  描述：

  癸醛 、 三羟甲基丙烷 在 对甲苯磺酸 作用下， 以 苯 为溶剂， 生成 (5-Ethyl-2-nonyl-1,3-dioxan-5-YL)methanol
  参考文献：
  名称：

  Synthesis of ethriolophospholipids of acetal type

  摘要：

  New analogues of acetal-type phospholipids were obtained on the basis of ethriol (2-hydroxymethyl-2-ethyl-1,3-propanediol). The starting triol originally was condensed with decanal or dodecanal to form acetals, which were then phosphorylated with tetraethyidiamidophosphorous acid chloride. The amidophosphites were further oxidized with iodosobenzene or sulfurized to the corresponding acetal-type phospholipids and their thio analogues.

  DOI：

  10.1134/s1068162006050153

文献信息

• Synthesis of ethriolophospholipids of acetal type
  作者：G. A. Savin

  DOI：10.1134/s1068162006050153

  日期：2006.9

  New analogues of acetal-type phospholipids were obtained on the basis of ethriol (2-hydroxymethyl-2-ethyl-1,3-propanediol). The starting triol originally was condensed with decanal or dodecanal to form acetals, which were then phosphorylated with tetraethyidiamidophosphorous acid chloride. The amidophosphites were further oxidized with iodosobenzene or sulfurized to the corresponding acetal-type phospholipids and their thio analogues.