4-methyl-5,6-diphenylpyrimidine | 1353577-57-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 4-methyl-5,6-diphenylpyrimidine
• CAS: 1353577-57-7
• 化学式: C₁₇H₁₄N₂
• 分子量: 246.312
• InChiKey: NOKNHFLGSQCVBM-UHFFFAOYSA-N

物化性质

• 沸点：
  358.3±21.0 °C(Predicted)
• 密度：
  1.105±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  5-溴-4-氯-6-甲基嘧啶 、 苯硼酸 在 potassium phosphate 、 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 作用下， 以 1,4-二氧六环 为溶剂， 反应 16.0h， 以78%的产率得到4-methyl-5,6-diphenylpyrimidine
  参考文献：
  名称：

  Suzuki-Miyaura和Negishi方法研究了一系列法医相关的吡啶和嘧啶

  摘要：

  制备了5-芳基-4-甲基嘧啶，4-苄基嘧啶，2，6-苄基吡啶和2，6-二苄基-4-甲基吡啶的苯环取代的衍生物的文库。5-芳基-4-甲基嘧啶的合成是通过芳基硼酸与5-溴-4-甲基嘧啶之间的Suzuki-Miyaura交叉偶联反应完成的。通过用环取代的苄基锌试剂处理4-溴嘧啶和2,6-二溴吡啶衍生物来合成4-苄基嘧啶和2,6-苄基吡啶。 交叉偶联反应-苯丙胺类似物-Leuckart合成-药物-杂环

  DOI：

  10.1055/s-0030-1260224

文献信息

• Organic electroluminescence device
  申请人：UDC Ireland

  公开号：US10454042B2

  公开（公告）日：2019-10-22

  An object of the present invention is to provide an organic electroluminescence device having excellent light emission efficiency and durability, in particular, durability when driving at a high temperature. Provided is an organic electroluminescence device including on a substrate a pair of electrodes, and at least one layer of an organic layer including a light emitting layer containing a light emitting material disposed between the electrodes, wherein the light emitting layer includes at least each one of specific indolocarbazole derivatives and specific condensed ring metal complexes.

  本发明的目的是提供一种有机电致发光器件，该器件具有优异的发光效率和耐用性，特别是在高温驱动时的耐用性。本发明提供了一种有机电致发光器件，包括在基底上的一对电极，以及至少一层有机层，该有机层包括设置在电极之间的包含发光材料的发光层，其中发光层包括特定吲哚咔唑衍生物和特定缩合环金属配合物中的至少一种。
• COMPOUND FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP1956022B1

  公开（公告）日：2012-07-25
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Fukuzaki Eiji

  公开号：US20120153272A1

  公开（公告）日：2012-06-21

  An object of the present invention is to provide an organic electroluminescence device having excellent light emission efficiency and durability, in particular, durability when driving at a high temperature. Provided is an organic electroluminescence device including on a substrate a pair of electrodes, and at least one layer of an organic layer including a light emitting layer containing a light emitting material disposed between the electrodes, wherein the light emitting layer includes at least each one of specific indolocarbazole derivatives and specific condensed ring metal complexes.
• Organic Electroluminescence Device
  申请人：UDC Ireland

  公开号：US20160079545A1

  公开（公告）日：2016-03-17

  An object of the present invention is to provide an organic electroluminescence device having excellent light emission efficiency and durability, in particular, durability when driving at a high temperature. Provided is an organic electroluminescence device including on a substrate a pair of electrodes, and at least one layer of an organic layer including a light emitting layer containing a light emitting material disposed between the electrodes, wherein the light emitting layer includes at least each one of specific indolocarbazole derivatives and specific condensed ring metal complexes.
• US7993760B2
  申请人：——

  公开号：US7993760B2

  公开（公告）日：2011-08-09