triethylammonium tetra[4-((4,4-dimethyl)-4,5-dihydrooxazolyl)phenyl]borate | 1292307-49-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triethylammonium tetra[4-((4,4-dimethyl)-4,5-dihydrooxazolyl)phenyl]borate
• 英文别名: tetrakis[4-(4,4-dimethyl-5H-1,3-oxazol-2-yl)phenyl]boranuide;triethylazanium
• CAS: 1292307-49-3
• 化学式: C₆H₁₅N*C₄₄H₄₈BN₄O₄*H
• 分子量: 809.9
• InChiKey: QBEIQGYQVYGOTE-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  5.22
• 重原子数：
  60
• 可旋转键数：
  11
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  90.8
• 氢给体数：
  1
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  sodium;tetrakis[4-(4,4-dimethyl-5H-1,3-oxazol-2-yl)phenyl]boranuide 、 三乙胺 以 甲醇 、 水 为溶剂， 以3.64 g的产率得到triethylammonium tetra[4-((4,4-dimethyl)-4,5-dihydrooxazolyl)phenyl]borate
  参考文献：
  名称：

  Preparation of Triethylammonium Tetra-Arylborates (TEATABs): Coupling Partners for the Suzuki Reaction

  摘要：

  [image omitted] Six triethylammonium tetra-arylborates (TEATABs) were synthesized via a convenient reproducible procedure and characterized by spectroscopic methods (1H, 13C, 11B NMR and electrospray ionization-high-resolution mass spectrometry). The compounds could be stored at ambient temperature and were useful as reactants in the Suzuki reaction in aqueous conditions when using commercially available catalysts.

  DOI：

  10.1080/00397911003718086

文献信息

• Preparation of Triethylammonium Tetra-Arylborates (TEATABs): Coupling Partners for the Suzuki Reaction
  作者：Noora M. Kuuloja、Tuula M. Kylmälä、Jan E. Tois、Rainer E. Sjöholm、Robert G. Franzén

  DOI：10.1080/00397911003718086

  日期：2011.3.3

  [image omitted] Six triethylammonium tetra-arylborates (TEATABs) were synthesized via a convenient reproducible procedure and characterized by spectroscopic methods (1H, 13C, 11B NMR and electrospray ionization-high-resolution mass spectrometry). The compounds could be stored at ambient temperature and were useful as reactants in the Suzuki reaction in aqueous conditions when using commercially available catalysts.