4-(1,1,3,3-tetramethylbutyl)-2-nitrophenol | 46912-02-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-(1,1,3,3-tetramethylbutyl)-2-nitrophenol
• 英文别名: Phenol, 4-tert.-octyl-2-nitro；2-nitro-4-(2,4,4-trimethylpentan-2-yl)phenol
• CAS: 46912-02-1
• 化学式: C₁₄H₂₁NO₃
• 分子量: 251.326
• InChiKey: BHSFQPGUTBZBDA-UHFFFAOYSA-N

物化性质

• 沸点：
  319.6±22.0 °C(Predicted)
• 密度：
  1.081±0.06 g/cm3(Predicted)
• 保留指数：
  1730

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  66
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(1,1,3,3-tetramethylbutyl)-2-nitrophenol 在 溶剂黄146 、 锌 作用下， 生成 2-氨基-4-(1,1,3,3-四甲基丁基)苯酚
  参考文献：
  名称：

  Reactions of 3,4,6-Trialkylphenols. III. Oxidation Studies

  摘要：

  DOI：

  10.1021/ja01648a068
• 作为产物：
  描述：

  异辛烯 在 硫酸 、 硝酸 、 溶剂黄146 作用下， 生成 4-(1,1,3,3-tetramethylbutyl)-2-nitrophenol
  参考文献：
  名称：

  二叔丁基苯酚的合成-结构-性能-衍生物

  摘要：

  DOI：

  10.1021/ie50347a014

文献信息

• A Sandwich‐Shaped Hexanuclear Silver Complex with a Giant Cavity Constructed from a Macrocycle with Inward Chelating Units
  作者：Takashi Nakamura、Rui Yun Feng、Tatsuya Nabeshima

  DOI：10.1002/ejic.202000882

  日期：2021.1.26

  The formation of a macrocyclic hexanuclear silver complex with a giant cavity (diameter ∼16.5 Å) is reported. Six silver centers are sandwiched by two molecules of a macrocyclic ligand possessing six pap (2‐[(pyridin‐2‐ylmethylene)amino]phenol) chelating units, and the metals are arranged on the wall of the internal cavity. Various analytical techniques revealed that each pap binds to the silver as

  据报道形成了具有大空腔（直径〜16.5Å）的大环六核银配合物。六个银中心被两个具有六个pap（2-[（吡啶-2--2-亚甲基）氨基]苯酚螯合单元的大环配体分子夹在中间，金属排列在内部腔壁上。各种分析技术表明，每个pap均以NN双齿配体的形式与银结合。
• Preparation of o,o'-dihydroxyazobenzenes from o-nitrophenols
  申请人：Phillips Petroleum Company

  公开号：US04055567A1

  公开（公告）日：1977-10-25

  Compounds having the formula ##STR1## are prepared from a corresponding o-nitrophenol by blocking the hydroxyl groups via acetal formation, followed by reductive coupling and acid hydrolysis.

  具有##STR1##式的化合物是通过从相应的邻硝基苯酚开始，通过缩醛形成阻断羟基，然后进行还原偶联和酸水解制备的。
• Preparation of high-dye yield couplers and intermediates useful therein
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1016653A1

  公开（公告）日：2000-07-05

  Disclosed is a carbamyl chloride of an aminoarylcarbonyl compound having the structural formula I: wherein R is an alkyl, alkenyl, or aryl group; A is an aryl (including heteroaryl) ring group; each R' is independently an alkyl group which may form a ring with Z or Z'; p is 0, 1, 2, or 3; each Z, Z', and Y is independently hydrogen or a substituent; and n is 0, 1, or 2.

  本发明公开了一种氨基芳基羰基化合物的氨基甲酰氯，其结构式为 I： 其中 R 是烷基、烯基或芳基； A 是芳基（包括杂芳基）环基团 每个 R'独立地是一个烷基，可与 Z 或 Z'形成一个环； p 为 0、1、2 或 3； 每个 Z、Z' 和 Y 独立地是氢或取代基；以及 n 是 0、1 或 2。
• Photographic element containing high dye-yield couplers
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1016916A1

  公开（公告）日：2000-07-05

  Disclosed is a photographic element containing a light sensitive silver halide emulsion layer having associated therewith a coupler represented by Formula I: wherein COUP is a coupler parent group capable of reacting with an oxidized developer to form a first dye and is bonded at a coupling position to the group wherein X is O or NSO2R; R is an alkyl or aryl group; and DYE is a releasable second dye that is after release the same color as the first dye and is linked to OC=X by a moiety of the DYE having Formula (IA): wherein R2 is a substituent; provided there is contained in the coupler of Formula I at least one group of Formula IB: wherein L is a divalent linking group and m is 0 or 1; and Sol is a group containing an acidic hydrogen selected from the group consisting of -ArOH, -NHSO2R1 and -SO2NHR1, in which Ar is an aromatic group and each R1 is a substituent; provided further that the pKa of an acidic hydrogen of Sol is less than 8.8.

  本发明公开了一种照相元件，该元件含有感光卤化银乳剂层，并与式 I 所表示的耦合剂相关联： 其中 COUP是耦合剂母基，能与氧化显影剂反应形成第一染料，并在耦合位置与基团键合 其中 X 是 O 或 NSO2R；R 是烷基或芳基；DYE 是可释放的第二染料，释放后颜色与第一染料相同，并通过具有式 (IA) 的 DYE 分子与 OC=X 连接： 其中 R2 是取代基； 只要式 I 的耦合剂中含有至少一个式 IB 的基团： 其中 L 是二价连接基团，m 是 0 或 1；Sol 是含有酸性氢的基团，该基团选自由-ArOH、-NHSO2R1 和-SO2NHR1 组成的组，其中 Ar 是芳香基团，每个 R1 是取代基； 此外，Sol 的酸性氢的 pKa 小于 8.8。
• Synthesis and electrode properties of 16-membered azo- and azoxycrown ethers. Structure of tribenzo-16-azocrown-6
  作者：Elżbieta Luboch、Jan F. Biernat、Yurii A. Simonov、A.A. Dvorkin

  DOI：10.1016/s0040-4020(98)00203-8

  日期：1998.5

  16-Membered benzoazo- and benzoazoxycrown ethers have been synthesized by reductive macrocyclization of respective bis(nitrophenoxy)oxaalkanes. The isomers of azocrown ethers were separated and E and Z structures were ascribed. Behavior of the compounds as ionophores in ion-selective membrane electrodes has been studied. Structure of Z isomer of 16-membered tribenzoazocrown ether has been determined. (C) 1998 Elsevier Science Ltd. All rights reserved.