(E)-3-(5-(10-butyl-10H-phenothiazin-3-yl)furan-2-yl)-2-cyanoacrylic acid | 1340541-64-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: (E)-3-(5-(10-butyl-10H-phenothiazin-3-yl)furan-2-yl)-2-cyanoacrylic acid
• 英文别名: (E)-3-[5-(10-butylphenothiazin-3-yl)furan-2-yl]-2-cyanoprop-2-enoic acid
• CAS: 1340541-64-1
• 化学式: C₂₄H₂₀N₂O₃S
• 分子量: 416.5
• InChiKey: GKFYAPARZGTGNJ-GHRIWEEISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  103
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-bromo-10-butyl-10H-phenothiazine 在 哌啶 、 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 、 乙腈 为溶剂， 反应 8.0h， 生成 (E)-3-(5-(10-butyl-10H-phenothiazin-3-yl)furan-2-yl)-2-cyanoacrylic acid
  参考文献：
  名称：

  Effect of Five-Membered Heteroaromatic Linkers to the Performance of Phenothiazine-Based Dye-Sensitized Solar Cells

  摘要：

  Phenothiazine derivatives with various conjugated linkers (furan, thiophene, and 3,4-ethylenedioxythiophene) were synthesized and used in dye-sensitized solar cells to study the effect of conjugated linkers on device performance. Among them, one with furan as a conjugated linker showed a solar energy-to-electricity conversion efficiency (eta) of 6.58%, an improvement of over 24% compared with the T2-1 reference cells' 5.29% under AM 1.5 G irradiation.

  DOI：

  10.1021/ol2023517

文献信息

• Effect of Five-Membered Heteroaromatic Linkers to the Performance of Phenothiazine-Based Dye-Sensitized Solar Cells
  作者：Se Hun Kim、Hyun Woo Kim、Chun Sakong、Jinwoong Namgoong、Se Woong Park、Min Jae Ko、Choong Hyuk Lee、Wan In Lee、Jae Pil Kim

  DOI：10.1021/ol2023517

  日期：2011.11.4

  Phenothiazine derivatives with various conjugated linkers (furan, thiophene, and 3,4-ethylenedioxythiophene) were synthesized and used in dye-sensitized solar cells to study the effect of conjugated linkers on device performance. Among them, one with furan as a conjugated linker showed a solar energy-to-electricity conversion efficiency (eta) of 6.58%, an improvement of over 24% compared with the T2-1 reference cells' 5.29% under AM 1.5 G irradiation.