2-氯苯脒酸乙酯 | 46004-52-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-氯苯脒酸乙酯
• 英文名称: 2-chloro-benzimidic acid ethyl ester
• 英文别名: 2-Chlor-benziminoaethylaether；2-Chlor-benzimidsaeure-aethylester；Ethyl 2-chlorobenzimidate；ethyl o-chlorobenzimidate；o-chlorobenzimidic acid ethyl ester；ethyl 2-chlorobenzenecarboximidate
• CAS: 46004-52-8
• 化学式: C₉H₁₀ClNO
• 分子量: 183.637
• InChiKey: YDXVOCXVQXQYPX-UHFFFAOYSA-N

物化性质

• 沸点：
  231.3±42.0 °C(Predicted)
• 密度：
  1.14±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  33.1
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2925290090

反应信息

• 作为反应物：
  描述：

  2-氯苯脒酸乙酯 、 乙酰氯 在 碳酸氢钠 、 三乙胺 作用下， 以 二氯甲烷 、 水 为溶剂， 生成 ethyl N-acetyl-o-chlorobenzimidate
  参考文献：
  名称：

  Heterocyclic compounds

  摘要：

  本发明涉及公式##STR1##中的新型三唑衍生物，其中R.sup.1是可选择取代的苯基，R.sup.2表示取代的苯基，如描述中更精确定义的那样，R.sup.3是卤素、甲基或卤代甲基，以及它们的酸盐，其制备方法，含有这些化合物作为活性物质的杀虫剂组合物，以及利用这些化合物或组合物控制害虫的方法。

  公开号：

  US04871757A1
• 作为产物：
  描述：

  碘乙烷 、 2-氯苯甲酰胺 在 乙醚 、 silver(l) oxide 作用下， 生成 2-氯苯脒酸乙酯
  参考文献：
  名称：

  Lander; Jewson, Journal of the Chemical Society, 1903, vol. 83, p. 770

  摘要：

  DOI：

文献信息

• Triazole derivatives, insecticide, acaricide and methods thereof
  申请人：Ihara Chemical Industry Co. Ltd.

  公开号：US05616594A1

  公开（公告）日：1997-04-01

  The invention provides a triazole derivative represented by a general formula ##STR1## (wherein R.sup.1 is an alkyl group, X is a hydrogen atom, a halogen atom or an alkyl group, n is an integer of 1-5, Y is a halogen atom, a nitro group or an alkyl group, and m is an integer of 2-5) as well as insecticide and acaricide containing the same as an active ingredient. The triazole derivatives according to the invention exhibit an excellent effectiveness against harmful pests, particularly aphids and mites.

  该发明提供了一种由通式表示的三唑衍生物##STR1##（其中R.sup.1是烷基，X是氢原子、卤素原子或烷基，n是1-5的整数，Y是卤素原子、硝基或烷基，m是2-5的整数），以及含有该三唑衍生物作为活性成分的杀虫剂和杀螨剂。根据该发明的三唑衍生物对有害害虫，特别是蚜虫和螨虫，表现出极好的效果。
• Triazole derivatives pest controlling agent and pest control method
  申请人：Kumiai Chemical Industry Co., Ltd.

  公开号：US05466705A1

  公开（公告）日：1995-11-14

  There are provided triazole derivatives represented by a general formula ##STR1## (wherein R.sup.1 is an alkyl group having a carbon number of 1-4, R.sup.2 is a phenyl group substitutable with a halogen atom, an alkyl group having a carbon number of 1-4 or the like, R.sup.3 is an alkenyl group having a carbon number of 3 or more substitutable with 1-4 halogen atoms, a phenyl group substituted with 1 or more halogen atoms or the like), a method producing the same, and a pest controlling agent containing the same as an active ingredient. The triazole derivatives according to the invention have an excellent insecticidal action against harmful pests such as hemipteran insects, lepidopteran insects, dipteran insects, mites and the like and also have an excellent ovicidal action against eggs of these pests. Furthermore, they have a preventively controlling effect on serious diseases such as sheath blight, blast and the like without badly affecting crops.

  本发明提供了一种由一般式##STR1##（其中R.sup.1是具有1-4个碳原子数的烷基，R.sup.2是可被卤原子、具有1-4个碳原子数的烷基或类似物取代的苯基，R.sup.3是可被1-4个卤原子取代的具有3个或更多碳原子数的烯基，取代有1个或更多卤原子的苯基或类似物），以及制备该类化合物的方法和含有其作为活性成分的杀虫剂。本发明所述的三唑类衍生物对半翅目昆虫、鳞翅目昆虫、双翅目昆虫、螨和类似害虫具有优异的杀虫作用，对这些害虫的卵也具有优异的卵杀作用。此外，它们对严重病害如纹枯病、稻瘟病等具有预防控制作用，而不会对作物造成严重影响。
• 1,2,4-Triazole compounds
  申请人：Hoffmann-La Roche Inc.

  公开号：US04788210A1

  公开（公告）日：1988-11-29

  The invention is concerned with novel heterocyclic compounds of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are as hereinafter set forth, and their acid addition salts, processes for the preparation of these compounds, pest control compositions which contain these compounds as the active substance, as well as the methods of use of such compounds or compositions for the control of pests.

  本发明涉及一种新型杂环化合物，其化学式为##STR1##其中R.sup.1，R.sup.2和R.sup.3如下所述，以及它们的酸加成盐，制备这些化合物的过程，含有这些化合物作为活性成分的杀虫剂组合物，以及使用这些化合物或组合物控制害虫的方法。
• Pesticidal phenylcarbamoylbenzimidates
  申请人：The Upjohn Company

  公开号：US04357347A1

  公开（公告）日：1982-11-02

  Phenylcarbamoylbenzimidates of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of methyl, trifluoromethyl, chlorine, fluorine and bromine; X.sub.2 is selected from the group consisting of hydrogen, methyl, trifluoromethyl, chlorine, fluorine and bromine; R is alkyl of from 1 to 5 carbon atoms; X.sub.3 and X.sub.4 can be the same or different and are selected from the group consisting of hydrogen, chlorine and bromine; X.sub.5 is selected from the group consisting of hydrogen, chlorine, bromine and trifluoromethyl; and X.sub.6 is selected from the group consisting of cyano and nitro; with the proviso that when X.sub.1 and X.sub.2 are chlorine or when X.sub.1 is fluorine and X.sub.2 is hydrogen then R, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are respectively not 1-methylethyl, chlorine, hydrogen, chlorine and nitro; with the further proviso that when X.sub.1 is fluorine and X.sub.2 is hydrogen then R, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are respectively not 1-methylethyl, chlorine, hydrogen, hydrogen and nitro; and with the further proviso that when X.sub. 1 is florine or methyl and X.sub.2 is hydrogen then R, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are respectively not ethyl, hydrogen, hydrogen, hydrogen and nitro; and with the proviso that when X.sub.1 and X.sub.2 are florine, then R, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are respectively not ethyl, chlorine, hydrogen, chlorine and nitro.

  该文本描述的是一种公式为 ##STR1## 的苯基氨甲酰基苯并咪唑，其中X1选择自甲基、三氟甲基、氯、氟和溴的组；X2选择自氢、甲基、三氟甲基、氯、氟和溴的组；R为1至5个碳原子的烷基；X3和X4可以相同也可以不同，选择自氢、氯和溴的组；X5选择自氢、氯、溴和三氟甲基的组；X6选择自氰基和硝基的组。但需注意，当X1和X2为氯时，或者当X1为氟且X2为氢时，则R、X3、X4、X5和X6分别不是1-甲基乙基、氯、氢、氯和硝基；另外，当X1为氟且X2为氢时，则R、X3、X4、X5和X6分别不是1-甲基乙基、氯、氢、氢和硝基；还需注意，当X1为氟或甲基且X2为氢时，则R、X3、X4、X5和X6分别不是乙基、氢、氢、氢和硝基；最后，当X1和X2均为氟时，则R、X3、X4、X5和X6分别不是乙基、氯、氢、氯和硝基。
• TRIAZOLE DERIVATIVE, INSECTICIDAL/ACARICIDAL AGENT, AND PROCESS FOR PRODUCING THE SAME
  申请人：KUMIAI CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0648752A1

  公开（公告）日：1995-04-19

  A triazole derivative represented by general formula (I) and an insecticidal/acaricidal agent containing the same as the active ingredient, wherein R¹ represents alkyl; X represents hydrogen, halogen or alkyl; n represents an integer of 1 to 5; Y represents halogen, nitro or alkyl; and m represents an integer of 2 to 5. This derivative has an excellent drug action on various detrimental insects, in particular, aphids and spider mites.

  一种由通式（I）代表的三唑衍生物和一种以其为活性成分的杀虫/杀螨剂，其中 R¹ 代表烷基；X 代表氢、卤素或烷基；n 代表 1 至 5 的整数；Y 代表卤素、硝基或烷基；m 代表 2 至 5 的整数。这种衍生物对各种有害昆虫，特别是蚜虫和蜘蛛螨具有很好的药物作用。