1,4-bis(3-formylphenothiazin-10-yl)butane | 1278524-17-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 1,4-bis(3-formylphenothiazin-10-yl)butane
• 英文别名: 10-[4-(3-Formylphenothiazin-10-yl)butyl]phenothiazine-3-carbaldehyde；10-[4-(3-formylphenothiazin-10-yl)butyl]phenothiazine-3-carbaldehyde
• CAS: 1278524-17-6
• 化学式: C₃₀H₂₄N₂O₂S₂
• 分子量: 508.665
• InChiKey: KNBOUSWOTFNUJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  36
• 可旋转键数：
  7
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  91.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,4-bis(3-formylphenothiazin-10-yl)butane 、 氰乙酸 在 哌啶 作用下， 以 氯仿 为溶剂， 反应 8.0h， 以86%的产率得到
  参考文献：
  名称：

  Enhanced Performance of the Dye-Sensitized Solar Cells with Phenothiazine-Based Dyes Containing Double D−A Branches

  摘要：

  Double donor-acceptor (D-A) branched dyes (DBD) with a phenothiazine unit as electron donor and a 2-cyanoacrylic acid unit as electron acceptor were synthesized and used as sensitizers for solar cells (DSSCs). The conversion efficiency of the DSSCs amounts up to 4.22% (2.91% for the single D-A branched dye) under AM 1.5 G irradiation. The results show that the performance of DSSCs can be effectively enhanced by the cooperation of two donor-acceptor containing branches in one molecule of the dyes.

  DOI：

  10.1021/ol2000167
• 作为产物：
  描述：

  1,4-bis(10-phenothiazinyl)butane 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 以 1,1,2-三氯乙烷 为溶剂， 以74%的产率得到1,4-bis(3-formylphenothiazin-10-yl)butane
  参考文献：
  名称：

  Enhanced Performance of the Dye-Sensitized Solar Cells with Phenothiazine-Based Dyes Containing Double D−A Branches

  摘要：

  Double donor-acceptor (D-A) branched dyes (DBD) with a phenothiazine unit as electron donor and a 2-cyanoacrylic acid unit as electron acceptor were synthesized and used as sensitizers for solar cells (DSSCs). The conversion efficiency of the DSSCs amounts up to 4.22% (2.91% for the single D-A branched dye) under AM 1.5 G irradiation. The results show that the performance of DSSCs can be effectively enhanced by the cooperation of two donor-acceptor containing branches in one molecule of the dyes.

  DOI：

  10.1021/ol2000167

文献信息

• Enhanced Performance of the Dye-Sensitized Solar Cells with Phenothiazine-Based Dyes Containing Double D−A Branches
  作者：Derong Cao、Jinan Peng、Yanping Hong、Xiaoming Fang、Lingyun Wang、Herbert Meier

  DOI：10.1021/ol2000167

  日期：2011.4.1

  Double donor-acceptor (D-A) branched dyes (DBD) with a phenothiazine unit as electron donor and a 2-cyanoacrylic acid unit as electron acceptor were synthesized and used as sensitizers for solar cells (DSSCs). The conversion efficiency of the DSSCs amounts up to 4.22% (2.91% for the single D-A branched dye) under AM 1.5 G irradiation. The results show that the performance of DSSCs can be effectively enhanced by the cooperation of two donor-acceptor containing branches in one molecule of the dyes.