3-Ethylthio-1-cyclopentene | 91737-96-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3-Ethylthio-1-cyclopentene
• 英文别名: 3-Ethylsulfanylcyclopentene
• CAS: 91737-96-1
• 化学式: C₇H₁₂S
• 分子量: 128.238
• InChiKey: IFZDCFNXLRVIBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-Chloro-1-ethylthiocyclopentane 、 sodium methylate 以48%的产率得到
  参考文献：
  名称：

  GRITSENKO, E. I.;BUTENKO, G. G.;PLEMENKOV, V. V., ZH. ORGAN. XIMII, 1984, 20, N 4, 741-746

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING CYCLOPENTYL ALKYL ETHER COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20170217862A1

  公开（公告）日：2017-08-03

  The present invention is a method for producing a cyclopentyl alkyl ether compound comprising reacting substituted or unsubstituted cyclopentene with an alcohol compound represented by a formula (2): R 1 OH in the presence of an acidic zeolite, the cyclopentyl alkyl ether compound being represented by a formula (1): R 1 —O—R 2 , wherein R 1 represents a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 8 carbon atoms, and R 2 represents a substituted or unsubstituted cyclopentyl group. The present invention provides a method that can produce a cyclopentyl alkyl ether with high reaction efficiency through a liquid-phase reaction even when the raw material feed rate (amount) is increased.

  本发明涉及一种制备环戊基烷基醚化合物的方法，包括在酸性沸石的存在下，将取代或未取代的环戊烯与式（2）表示的醇化合物（R1OH）反应，所述环戊基烷基醚化合物由式（1）表示：R1-O-R2，其中R1表示具有1到10个碳原子的取代或未取代的烷基或具有3到8个碳原子的取代或未取代的环烷基，R2表示取代或未取代的环戊基。本发明提供了一种方法，即使原料进料速率（量）增加，也可以通过液相反应高效地生产环戊基烷基醚。
• METHOD FOR PRODUCING CYCLOALKYL ALKYL ETHER COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20160052848A1

  公开（公告）日：2016-02-25

  The present invention is a method for producing a cycloalkyl alkyl ether compound comprising reacting substituted or unsubstituted cyclopentene or substituted or unsubstituted cyclohexene with an alcohol compound represented by a formula (2): R 1 OH (wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 8 carbon atoms) in a gaseous state in presence of an acidic ion-exchange resin to produce a cycloalkyl alkyl ether compound represented by a formula (1): R 1 —O—R 2 (wherein R 1 is the same as defined above, and R 2 is a substituted or unsubstituted cyclopentyl group or a substituted or unsubstituted cyclohexyl group), the acidic ion-exchange resin having a specific surface area of 20 to 50 m 2 /g, an average pore size of 20 to 70 nm, and a total exchange capacity of 4.8 to 6.0 eq/L-R wet resin.

  本发明是一种生产环烷基烷基醚化合物的方法，包括将取代或未取代的环戊烯或取代或未取代的环己烯与公式（2）所表示的醇化合物反应：R1OH（其中R1是具有1至10个碳原子的取代或未取代的烷基或具有3至8个碳原子的取代或未取代的环烷基），在酸性离子交换树脂的存在下，在气态下生产环烷基烷基醚化合物，该化合物的化学式为（1）：R1—O—R2（其中R1与上述定义相同，R2是取代或未取代的环戊基或取代或未取代的环己基），酸性离子交换树脂具有20至50 m2/g的比表面积，20至70 nm的平均孔径和4.8至6.0 eq/L-R湿树脂的总交换容量。
• Gritsenko, E. I.; Butenko, G. G.; Plemenkov, V. V., Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, p. 673 - 678
  作者：Gritsenko, E. I.、Butenko, G. G.、Plemenkov, V. V.

  DOI：——

  日期：——
• US9586882B2
  申请人：——

  公开号：US9586882B2

  公开（公告）日：2017-03-07