N-(2-Cyan-phenyl)-diphenylphosphinsaeureamid | 23021-55-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2-Cyan-phenyl)-diphenylphosphinsaeureamid
• 英文别名: 2-(Diphenylphosphorylamino)benzonitrile
• CAS: 23021-55-8
• 化学式: C₁₉H₁₅N₂OP
• 分子量: 318.315
• InChiKey: GFSYTZGYOZETHF-UHFFFAOYSA-N

物化性质

• 沸点：
  496.3±47.0 °C(Predicted)
• 密度：
  1.25±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.9
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  diphenyltrichlorophosphorane 在 水 作用下， 生成 N-(2-Cyan-phenyl)-diphenylphosphinsaeureamid
  参考文献：
  名称：

  Schmidpeter,A.; Schindler,N., Chemische Berichte, 1969, vol. 102, # 7, p. 2201 - 2206

  摘要：

  DOI：

文献信息

• On the Reactivity of the Iminodiphosphane C ₆ H ₄ ( <i>o</i> ‐CN)N=PPh ₂ −PPh ₂ : Fragmentation Versus Isomerisation
  作者：Zhaofu Fei、Rosario Scopelliti、Paul J. Dyson

  DOI：10.1002/ejic.200300529

  日期：2004.2

  AbstractThe reactivity of the iminodiphosphane C6H4(o‐CN)N=PPh2−PPh2, which contains an N=P−P unit, has been investigated. Reaction with small molecules, [viz. H2O/O2, H2O2, CH3OH, C6H4(o‐CN)NH2] and elemental sulfur result in cleavage of the P−P bond to give aminophosphane‐derivatised compounds. The products from these reactions have been characterized spectroscopically, including two by single‐crystal X‐ray diffraction. The reactivity of the iminodiphosphane towards the transition metal complexes [M(cod)Cl2] (M = Pd or Pt) has also been investigated. In the reactions, the iminodiphosphane rearranges to form the more common diphosphonylamine (P−N−P) unit which chelates to the metal centres. Three different compounds were isolated from these reactions and they have all been fully characterised by spectroscopy and single‐crystal X‐ray diffraction. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
• Schmidpeter,A.; Schindler,N., Chemische Berichte, 1969, vol. 102, # 7, p. 2201 - 2206
  作者：Schmidpeter,A.、Schindler,N.

  DOI：——

  日期：——