1-Buta-1,3-diynyl-2-nitrobenzene | 125600-38-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Buta-1,3-diynyl-2-nitrobenzene
• CAS: 125600-38-6
• 化学式: C₁₀H₅NO₂
• 分子量: 171.155
• InChiKey: ZFRWYTZXIYMIQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-乙炔基-2-硝基苯 在 异丙胺 、 copper(l) chloride 、 potassium hydroxide 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 1-Buta-1,3-diynyl-2-nitrobenzene
  参考文献：
  名称：

  Solid-State Polymerization of Monophenylbutadiyne Derivatives

  摘要：

  Solid-state polymerization of phenylbutadiyne derivatives with o-nitro, m-nitro or p-nitro group was investigated. All monomers in bulk crystals could be thermally polymerized to become black suggesting formation of extended p-conjugation system. However, no regular polydiacetylene structures were confirmed by the structural analysis. Nanocrystals of the m-nitro derivative were prepared, and the different polymerization behavior compared with in the bulk crystals was observed.

  DOI：

  10.1080/15421400902950030

文献信息

• MATSUDA, XIROO;OKADA, SYUDZI;NAKANISI, XATIRO;KATO, MASAO;XORAJ, SIGEHRU;+
  作者：MATSUDA, XIROO、OKADA, SYUDZI、NAKANISI, XATIRO、KATO, MASAO、XORAJ, SIGEHRU、+

  DOI：——

  日期：——
• JPH01233263A
  申请人：——

  公开号：JPH01233263A

  公开（公告）日：1989-09-19
• Solid-State Polymerization of Monophenylbutadiyne Derivatives
  作者：Jun-ichi Watanabe、Harumi Yokoyama、Shuji Okada、Shigeru Takaragi、Hiro Matsuda、Hachiro Nakanishi

  DOI：10.1080/15421400902950030

  日期：2009.6.18

  Solid-state polymerization of phenylbutadiyne derivatives with o-nitro, m-nitro or p-nitro group was investigated. All monomers in bulk crystals could be thermally polymerized to become black suggesting formation of extended p-conjugation system. However, no regular polydiacetylene structures were confirmed by the structural analysis. Nanocrystals of the m-nitro derivative were prepared, and the different polymerization behavior compared with in the bulk crystals was observed.