2,4,6-trichloro-2,4,6-tri(phenoxy)-1,3,5-triaza-2,4,6-triphosphorine | 1176-43-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-trichloro-2,4,6-tri(phenoxy)-1,3,5-triaza-2,4,6-triphosphorine
• 英文别名: 2,4,6-Trichlor-2,4,6-triphenoxy-cyclotriphosphazatrien；2,4,6-Trichlorotriphenoxycyclotriphosphazene；Trichlor-tris-phenoxy-cyclotriphosphonitril；Trichlorotriphenoxycyclotriphosphazene；2,4,6-trichloro-2,4,6-triphenoxy-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 1176-43-8
• 化学式: C₁₈H₁₅Cl₃N₃O₃P₃
• 分子量: 520.616
• InChiKey: NNHKDHFEUKGYSB-UHFFFAOYSA-N

物化性质

• 密度：
  1.57±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  64.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,4,6-trichloro-2,4,6-tri(phenoxy)-1,3,5-triaza-2,4,6-triphosphorine 在 sodium azide 、 四丁基溴化铵 作用下， 以 甲苯 、 丁酮 为溶剂， 反应 18.0h， 生成
  参考文献：
  名称：

  Synthesis and Reactivity of Alkoxy, Aryloxy, and Dialkylamino Phosphazene Azides

  摘要：

  DOI：

  10.1021/ja983424q
• 作为产物：
  描述：

  六氯环三磷腈 、 sodium phenoxide 以to produce an intermediate (trischlorotrisphenoxycyclotriphosphazene), 19 which的产率得到2,4,6-trichloro-2,4,6-tri(phenoxy)-1,3,5-triaza-2,4,6-triphosphorine
  参考文献：
  名称：

  Fire and heat resistant laminating resins based on maleimido substituted

  摘要：

  4-氨基苯氧基环三磷氮化物与马来酸酐反应，产生马来酰胺酸，再转化为马来酰亚胺。马来酰亚胺被聚合。通过选择起始材料（例如六胺或三氨基苯氧基三苯氧基环三磷氮化物）、选择反应物的摩尔比例、使用酸酐混合物和使用二酸酐作为桥接基团，可以生产各种马来酰亚胺和聚合物。这些聚合物具有高氧指数、高炭化收率和其他有用的耐热和防火性能，因此可用作织物浸渍剂等用途。

  公开号：

  US04634759A1

文献信息

• Aminophenoxycyclotriphosphazene cured epoxy resins and the composites,
  申请人：The United States of America as represented by the Administrator of the

  公开号：US04668589A1

  公开（公告）日：1987-05-26

  Aminophenoxycyclotriphosphazenes such as hexakis(4-aminophenoxy)cyclotriphosphazene and tris(4-aminophenoxy)-tris phenoxyclyclotriphosphazene are used as curing agents for epoxy resins. These 1,2-epoxy resins are selected from di- or polyepoxide-containing organic moieties of the formula (CH.sub.2 --CHO--CH.sub.2).sub.m --W--R--W--(CH.sub.2 CH--CH.sub.2 O).sub.m where R is diphenyldimethylmethane, diphenylmethane, bis(dibromophenyl)dimethylmethane, or ##STR1## W is a nitrogen or oxygen atom; and m is 1 when W is oxygen and 2 when W is nitrogen. The resins are cured thermally in stages at between about 110.degree. to 135.degree. C. for between about 1 and 10 min, then at between about 175.degree. to 185.degree. C. for between about 0.5 to 10 hr and post-cured at between about 215.degree. and 235.degree. C. for between abut 0.1 and 2 hr. These resins are useful for making fire-resistant elevated temperature stable composites, laminates (e.g. graphite fiber or fiberglass), molded parts, and adhesives and structures, usually for aircraft secondary structures and for spacecraft construction.

  Aminophenoxycyclotriphosphazenes，例如六(4-氨基苯氧基)环三磷氮和三(4-氨基苯氧基)-三苯氧环三磷氮，用作环氧树脂的固化剂。这些1,2-环氧树脂从具有以下式子的二元或多元环氧基有机基团中选择：(CH.sub.2 --CHO--CH.sub.2).sub.m --W--R--W--(CH.sub.2 CH--CH.sub.2 O).sub.m，其中R是二苯基二甲基甲烷，二苯甲烷，双(二溴苯基)二甲基甲烷，或##STR1##W是氮或氧原子;当W为氧时，m为1，当W为氮时，m为2。这些树脂在110℃至135℃之间的阶段性热固化，时间为1至10分钟，然后在175℃至185℃之间的温度下热固化0.5至10小时，并在215℃至235℃之间进行后固化，时间为0.1至2小时。这些树脂适用于制造耐火高温稳定的复合材料、层压板（例如石墨纤维或玻璃纤维）、成型件、粘合剂和结构件，通常用于飞机次要结构和航天器建造。
• Aromatic cyclotriphosphazenes
  申请人：The United States of America as represented by the administrator of the

  公开号：US04748263A1

  公开（公告）日：1988-05-31

  4-Aminophenoxy cyclotriphosphazenes are reacted with maleic anhydride to produce maleamic acids which are converted to the maleimides. The maleimides are polymerized. By selection of starting materials (e.g. hexakis amino or trisaminophenoxy-trisphenoxy-cyclotriphosphazenes), selection of molar proportions of reactants, use of mixtures of anhydrides and use of dianhydrides as bridging groups a variety of maleimides and polymers are produced. The polymers have high limiting oxygen indices, high char yields and other useful heat and fire resistant properties making them useful as, for example, impregnants of fabrics.

  4-氨基苯氧基环三磷氮化物与马来酸酐反应生成马来酰胺酸，然后转化为马来酰亚胺。马来酰亚胺进行聚合反应。通过选择起始物质（例如六胺或三氨基苯氧基三苯氧基环三磷氮化物）、选择摩尔比例的反应物、使用酸酐混合物和使用二酸酐作为桥连基团，可以生产各种马来酰亚胺和聚合物。这些聚合物具有高限氧指数、高炭化收率和其他有用的耐热和防火性能，因此可以用作织物的浸渍剂等。
• Maleimido substituted aromatic cyclotriphosphazenes
  申请人：The United States of America as represented by the Administrator of the

  公开号：US04550177A1

  公开（公告）日：1985-10-29

  4-Aminophenoxy cyclotriphosphazenes are reacted with maleic anhydride to produce maleamic acids which are converted to the maleimides. The maleimides are polymerized. By selection of starting materials (e.g. hexakis amino or trisaminophenoxy-trisphenoxy-cyclotriphosphazenes), selection of molar proportions of reactants, use of mixtures of anhydrides and use of dianhydrides as bridging groups a variety of maleimides and polymers are produced. The polymers have high limiting oxygen indices, high char yields and other useful heat and fire resistant properties making them useful as, for example, impregnants of fabrics.

  4-氨基苯氧基环三磷氮化物与马来酸酐反应生成马来酰胺酸，然后转化为马来酰亚胺。马来酰亚胺被聚合。通过选择起始材料（例如六胺或三氨基苯氧基三苯氧基环三磷氮化物），选择反应物的摩尔比例，使用酸酐混合物以及使用双酸酐作为桥接基团，可以生产出各种马来酰亚胺和聚合物。这些聚合物具有高限氧指数、高炭化收率和其他有用的耐热和耐火性能，例如可用作织物的浸渍剂。
• Phosphazene Compound, Lubricant and Magentic Recording Medium Having Such Compound, Method of Preparation, and Method of Lubrication
  申请人：Xu Jianwei

  公开号：US20090291325A1

  公开（公告）日：2009-11-26

  A compound of the formula: (I) is provided, where R is selected from CF 3 , F, and H, and m is an integer from 1 to 22. The compound may be prepared by reacting a first reactant with a second reactant in a solution, where the first reactant is a 2,4-dichloro-2,4,6,6-tetra(aryloxy)-1,3,5-triaza-2,4,6-triphosphorine, and the second reactant is a perfluoropolyether of the formula CF 3 CF 2 CF 2 O(CF 2 CF 2 CF 2 O) m CF 2 CF 2 CH 2 OH. The aryloxy is selected from 4-(trifluoromethyl)phenoxy (p-CF 3 —C 6 H 4 O), 4-fluorophenoxy (p-F—C 6 H 4 O), and phenoxy (C 6 H 5 O). The first reactant may be prepared by reacting 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine with a phenoxide. The compound may be used in a lubricant for lubricating a surface. The lubricant may be applied to a recording surface in a magnetic recording device including a recording medium.

  提供了公式（I）的化合物，其中R从CF3，F和H中选择，m是1至22的整数。可以通过在溶液中反应第一反应物和第二反应物来制备化合物，其中第一反应物是2,4-二氯-2,4,6,6-四（芳氧基）-1,3,5-三氮杂-2,4,6-三磷环，第二反应物是公式 CF2CF2O（CF2CF2CF2O）mCF2CF2CH2OH的全氟聚醚。芳氧基从4-（三氟甲基）苯氧基（p- —C6H4O），4-氟苯氧基（p-F— ）和苯氧基（C6H5O）中选择。第一反应物可以通过将2,2,4,4,6,6-六氯-1,3,5-三氮杂-2,4,6-三磷环与苯氧基反应来制备。该化合物可以用作润滑剂，润滑表面。润滑剂可以涂覆在包括记录介质的磁记录装置中的记录表面上。
• METHOD FOR PRODUCING MODIFIED POLYDIENES (VARIANTS)
  申请人：Public Joint Stock Company "Sibur Holding" (PJSC "Sibur Holding")

  公开号：EP4098666A1

  公开（公告）日：2022-12-07

  The invention relates to the production of synthetic polymers used in the manufacture of tires and tire parts, golf balls and other industrial rubber goods. In particular, the present invention relates to methods for producing a modified polydiene by catalytic polymerization of a conjugated diene in an organic solvent, wherein the catalytic system used includes a lanthanide compound, an organoaluminum compound, a conjugated diene, and a halogen-containing component, followed by post-polymerization modification with at least one phosphorus-nitrogen compound the chemical structure of which is based on repeating (-P=N-)n units, where n is an integer from 3 to 24. The technical result of the invention is the obtaining a modified stereoregular polydiene characterized by a narrow molecular weight distribution, good processability in the composition of rubber compounds, a low rolling resistance, and a low wearability.

  本发明涉及用于制造轮胎和轮胎部件、高尔夫球和其他工业橡胶制品的合成聚合物的生产。特别是，本发明涉及通过共轭二烯在有机溶剂中的催化聚合生产改性聚二 烯的方法，其中使用的催化体系包括镧系化合物、有机铝化合物、共轭二烯和含卤 成分，然后用至少一种磷氮化合物进行聚合后改性，该磷氮化合物的化学结构基于 重复的 (-P=N-)n 单元，其中 n 为 3 至 24 的整数。本发明的技术成果是获得了一种改性立体扁平聚二烯烃，其特点是分子量分布窄、在橡胶复合物成分中具有良好的加工性、低滚动阻力和低磨损性。